• Korean Chemical Engineering Research
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• v.46 no.4
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• pp.727-731
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• 2008

Mesoporous Pt-Au alloy films were successfully fabricated on ITO-coated glass by electrodeposition method using tri-blockcopolymer (P123) as a templating agent. The electrolyte consisted of 10 mM hydrogen hexachloroplatinate ($H_2PtCl_6$), 10 mM hydrogen tetrachloroaurate ($HAuCl_4$), and proper amount of P123. For comparison, control samples were electrodeposited without $HAuCl_4$ and P123. Film composition was determined by EDS(Energy Dispersive X-ray Spectroscopy), and the mesoporous structure was confirmed by TEM(Transmission Electron Microscopy). SEM(Scanning Electron Microscopy) was utilized to examine surface morphology, and it was observed that the addition of P123 affected the particle growth, resulting in the significant change of surface morphology. Methanol oxidation and CO oxidation were carried out to investigate electrocatalytic activities of synthesized samples. It was observed that the catalytic activity was strongly dependent on the film compositions. Compared with nonporous electrode prepared without P123 templating, mesoporous films prepared with P123 templating showed much higher catalytic activities and stability for both methanol oxidation and CO oxidation. These enhanced electrocatalytic activities were due to the high surface area and facilitated charge transfer of mesoporous films.

• Clean Technology
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• v.20 no.1
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• pp.1-6
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• 2014

$CO_2$ is generated by the combustion reaction, when getting the energy from fossil fuel. If the carbon dioxide emissions increases more, the global warming problem will become more serious. CCS (carbon capture storage) needs to be developed for the prevention of this. When liquefied $CO_2$ is transported, BOG (boil-off gas) is generated because of several problems. In the study, by injecting liquefied $CO_2$ in two tanks which contains $40m^3$each, the amount of BOG and its composition were measured during 30 days when generating pressure changes and external heat, loading, unloading. In result, 16,040 kg of BOG was generated and the composition has been found out to be 99.95% $CO_2$ and 0.05 % $N_2$. Also, we conducted simulation process for reliquefaction of generated BOG with vapor compression cycle using the PRO/II with PROVISION version 9.2. As a result, the refrigeration cycle of the total circulation flow rate was 42.07 kg/h and the condenser utility consumption was 48.85 kg/h.

• Journal of the Korean Magnetics Society
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• v.22 no.2
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• pp.37-41
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• 2012

The Ag nanoparticles attached $La_{0.7}Sr_{0.3}Co_{0.3}Fe_{0.7}O_{3-{\delta}}$ (LSCF) perovskites were prepared by plasma method. The Ag nanoparticles with size of several nanometers deposited from the Ag target were coated on the surface of LSCF powders with size range from 0.2 to 3 ${\mu}m$. The agglomeration of Ag particles annealed at $800^{\circ}C$ under inert gas of Ar were rarely observed. The inter-diffusion between surface Ag and core LSCF is effectively strong to prevent aggregation of Ag nanoparticles. The wave number of FT-IR spectra for LSCF were largely shifted as the concentration of Ag on LSCF up to 2.11 wt.%. The ionic states of irons in LSCF were measured by M$\ddot{o}$ssbauer spectroscopy. The small amount of $Fe^{4+}$ ions are converted to $Fe^{3+}$ ions after Ag nanopartcles were coated on LSCF.

• Plant Journal
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• v.13 no.2
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• pp.46-51
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• 2017

In this study, the boiler efficiency and the change of boiler combustion state with the burner operation of the uppermost layer of 870MW opposite fired coal boiler were measured. Test results showed that the boiler efficiency was high in the order of the uppermost layer simultaneous operation of the front and rear burners, the front burner, and the rear burner operation. When the front and rear burners were operated simultaneously, the heat absorption rate of water walls in the boiler furnace was uniform at four side, and the temperature deviation of the left and right steam on the convection front surface decreased. As the heat absorption rate of the boiler improved, the loss of boiler exhaust gas decreased and the coal supply amount decreased by 8 tons/hour compared to the operation of the rear burner. This will contribute not only to the reduction of fuel cost but also to the reduction of greenhouse gas emissions.

• Journal of the Korean Society of Marine Environment & Safety
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• v.25 no.7
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• pp.945-952
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• 2019

The International Maritime Organization (IMO) adopted the International Convention on the Control of Ships' Air Pollutants and Discharge as it became interested in environmental issues such as global warming and air pollution. In addition, a special bill on the improvement of air quality, including in port areas, has recently been enacted in Korea to reduce the amount of fine dust generated. As part of such fine dust reduction measures, feasibility studies have been underway on converting diesel engines into battery electric propulsion systems that do not cause fine dust and emissions. Since the battery electric propulsion system can easily utilize renewable energy sources, and does not generate exhaust gas due to combustion of fuel, small coastal ferries with battery electric propulsion systems that use renewable energy have been operating in Europe and the U.S. for several years. However, they have not been introduced in Korea. Therefore, in this study, we selected small coastal ferries in Korea as target ferries, and performed simulations to study the applicability of electric propulsion with batteries linked to solar power systems. Based on the results, we want to confirm the applicability of battery electric propulsion.

• KOREAN JOURNAL OF CROP SCIENCE
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• v.58 no.1
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• pp.71-77
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• 2013

The world demand of renewable bioenergy as an alternative transportation fuel is greatly increasing. Research for bioethanol production is currently being progressed intensively throughout the world. Therefore it will be necessary to develop bioethanol production with cellulosic materials. In this study, the yield of ethanol production was evaluated by simultaneous saccharification and fermentation (SSF) using sodium hydroxide pretreated sorghum ${\times}$ sudangrass hybrids. Composition analysis of 11 varieties of sorghum ${\times}$ sudangrass hybrids was performed for selection of excellent variety to efficiently produce bioethanol. The content of cellulose, hemicellulose, lignin and ash of these varieties were 32~39%, 19~24%, 17~22% and 6~11%, respectively. Among these varieties, 4 varieties of sorghum ${\times}$ sudangrass hybrids were selected for the evaluation of ethanol yield and those were pretreated with 1 M NaOH solution at $150^{\circ}C$ for 30 min using high temperature explosion system. After pretreatment, samples were neutralized with tap water. It contained 52~57% of cellulose. Simultaneous saccharification and fermentation (SSF) was carried out for 48 h at $33^{\circ}C$ by Saccharomyces cerevisiae CHY1011 using Green star variety. The yield of ethanol was 92.4% and the amount of ethanol production was estimated at 6206 L/ha.

• Proceedings of the KSEEG Conference
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• 2002.10a
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• pp.53-67
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• 2002

As in the past, we are concerned today with the magnitudes of mineral resources and the adequacy of these resources to meet future needs. In looking at global resource issues, we should consider the need for the resource, its supply, and the environmental consequences of using it. The need for a resource can become a resource dependency, specially as the global population expands and each of us becomes Increasingly dependent upon hundreds of natural materials. Therefore, our great mineral consumption makes the human population a true “Geologic Force”, which will be even more significant in the future when the global population is projected to reach alarming proportions. Although our supplies of mineral resources probably will be sufficient for the 21st century, the uneven distribution of minerals in the Earth's crust almost certainly will continue to be a major problem. The most likely result will be major shifts in both prices and sources of supply of many mineral resources. As for energy resources, we must avoid an obsessive dependency on one fuel and expand instead to other energy resources. Finally, because the use of resources affects the environment, we need to focus on resource exploitation and global pollution, particularly in regard to ground water and arable land. We must manage our resources so as to be in balance with our environment. And the accelerated industrialization of South Korean economy over the last three decades has resulted in the mass consumption of mineral commodities. South Korea has around 50 useful mineral commodities for the mineral industry, among 330 kinds of minerals described. The component ratio of the mining industry sector of the gross national production(GNP) in South Korea dropped from 1.2% in 1971 to 0.34% in 1997 due to the rapid growth of other industries in the country. During the period from 1971 to 1997, the average growth rate of mineral consumption in South Korea was 9.13% yearly and that of GMP per capita was 14.97%. The mineral consumptions per capita showed a continual increase during the last 30 years as follows(parenthesis: GW per capita); 0.99 metric tons in 1997($289), 3.83 metric tons in 1989($5, 210), 6.11 metric tons in 1995 ($10, 037), and 6.66 metric tons in 1997($9, 511). The total amount of mineral consumption in South Korea was 33 million tons of 32 mineral commodities in 1971, and 306 million metric tons of 47 mineral commodities in 1997.

• Transactions of the Korean Society of Automotive Engineers
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• v.24 no.1
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• pp.67-73
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• 2016

The application of titanium has been gradually rising because the utilizing ranges for low weight and high strength are rapidly increased by the need for improving the fuel economy in production industries such as the aviation and automotive in recent. The purpose in this study is to investigate the appropriate cutting conditions on the life of flat and round end mills by measuring the maximum cutting temperature relative to the machining time, and calculating the wear rates of cutting tool with the spindle speed and feed rate of vertical machining center as a parameter in the titanium roughing cut machining which is widely used in critical parts of aircraft, cars, etc. When the wetted roughing cut machining of titanium with a soluble cutting oil is conducted by the flat and round end mills, the maximum cutting temperatures for a variety of spindle speed and feed rate are measured at ten-minute intervals during 60 minutes by an infrared thermometer, and the wear rates of cutting tool are calculated by the weight ratios based on tool wear before and after the experiment. It is found that the maximum cutting temperature and the wear rates of cutting tool are raised as the cutting amount per tool edge is increased with the rise of feed rate, in this experimental range, and as the frictional area due to the rise of contacting friction numbers between tool and specimen is increased with the rises of cutting time and spindle speed. In addition, the increasing rate of maximum cutting temperature in the flat and round end mills are the highest for the cutting time from 50 to 60 minutes, and the wear rate of cutting tool in the flat end mill is 1.14 to 1.55 times higher than that in the round end mill for all experimental conditions.

• Analytical Science and Technology
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• v.13 no.4
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• pp.453-465
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• 2000

Polycyclic aromatic hydrocarbons (PAHs) were produced by thermoreaction (incompletely combustion) of organic compounds such as fuel, gasoline, diesel etc, and were known the strong carcinogenic compounds. In our country, a study for health risk assessment of PAHs in air were needed according to rapidly increasing of motor vehicle and progressing to industrial country. In this study, concentrations of PAHs in 263 air samples of fourteen sites-Seoul, Pusan, etc-according to four times sampling for one year are measured by GC/MSD for basic research for health risk assessment. As the result, 14 PAHs are detected in all samples and annual average concentration of total PAHs was $28.72ng/m^3$ and highest average concentration of total PARs was $47.76ng/m^3$ in winter season. The concentrations of total PAHs are proportioned to amount of extracted organic material (EOM). The average concentration of total PAHs in EOM was 0.28%.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.14 no.3
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• pp.211-221
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• 2016

Waste salt generated from a pyro-processing for the recovery of uranium and transuranic elements has high volatility at vitrification temperature and low compatibility in conventional waste glasses. For this reason, KAERI (Korea Atomic Energy Research Institute) suggested a new method to de-chlorinate waste salt by using an inorganic composite named SAP ($SiO_2-Al_2O_3-P_2O_5$). In this study, the de-chlorination behavior of waste salt and the microstructure of consolidated form were examined by adding $B_2O_3$ and $Fe_2O_3$ to the original SAP composition. De-chlorination behavior of metal chloride waste was slightly changed with given compositions, compared with that of original SAP. In the consolidated forms, the phase separation between Si-rich phase and P-rich phase decreases with the amount of $Al_2O_3$ or $B_2O_3$ as a connecting agent between Si and P-rich phase. The results of PCT (Product Consistency Test) indicated that the leach-resistance of consolidated forms out of reference composition was lowered, even though the leach-resistance was higher than that of EA (Environmental Assessment) glass. From these results, it could be inferred that the change in the content of Al or B in U-SAP affected the microstructure and leach-resistance of consolidated form. Further studies related with correlation between composition and characteristics of wasteform are required for a better understanding.