• Bulletin of the Korean Chemical Society
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• 제19권1호
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• pp.68-74
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• 1998

The complexation of ethylammonium ion by alkyl p-tert-butylcalix[6]aryl ester derivatives was studied via measurements of proton and carbon spin-lattice relaxation times $(T_1)$ and chemical shift changes in solution state $(CDCl_3)$. The results indicate that the endo-type complexes are formed and that the overall tumbling rates of these complexes are more rapid than those of the corresponding free hosts. The association constants for these complexes in $THF-d_8$ were determined by $^1H$ NMR titration at several different temperatures to estimate the relevant thermodynamic parameters. The logK's for ethylammonium complexes of methyl, ethyl, and propyl esters at 313 K, for example, were found to be 1.56, 3.41, and 3.08, respectively. The complexes formed may be thought of as being kinetically stable in view of their $^1H$ NMR behavior in 2 : 1 host/guest solution.

• Bulletin of the Korean Chemical Society
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• 제19권10호
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• pp.1054-1059
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• 1998

Fluorescence and dynamic light scattering measurements were applied to the study of formation and structure of aggregated colloidal particles in modified poly(ethylene-co-methylacrylate) ionomers in aqueous solution. Both 8-anillino-l-naphthalene-sulfonic acid (ANS) and pyrene were used as fluorescence probe to obtain the information on the structure of particle surface and inside, respectively. Three different ionomers used in this study started to aggregate at very dilute concentration, 3-8 x 10-6 g/mL. In this study, we demonstrate that the polyethylene ionomers can form stable nanoparticles. The hydrophobic core made of the polyethylene backbone chains is stabilized by the ionic groups on the particle surface. Such a formed stable nanoparticles have a relatively narrow size distribution with an average radius in the range of 27-48 nm, depending on the kind of ionic groups. Once the stable particles are formed, the particle size distributions were nearly constant. This study shows another way to prepare surfactant-free polyethylene nanoparticles.

• 한국건축시공학회지
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• 제20권2호
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• pp.171-181
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• 2020

최근 비정형 건축물이 한 나라의 기술적 우월성을 나타내는 새로운 척도로 부상하기 시작하면서 비정형 건축물을 효율적으로 제작하는 기술이 중요해지고 있다. 하지만 기존의 목재, 철재 거푸집 등을 CNC 기술로 가공하여 비정형 거푸집을 제작하는 방식은 제작시간과 재료 비용 측면에서 한계점이 존재한다. 따라서 본 연구에서는 S-LOM 방식의 3D 프린팅 기술을 통한 비정형 EPS 거푸집 제작 공법을 개발하고 제작 프로세스를 제시하였다. 또한 실물 모형 시험을 통해 기존 CNC 밀링 기술과의 제작시간 및 정밀도에 대한 비교 분석을 실시하였다. 연구결과, S-LOM 방식의 3D 프린팅 기술을 활용할 경우 CNC 밀링 기술 대비 약 57.4%의 제작시간 단축 효과가 있었다. 또한 S-LOM 방식의 3D 프린팅 기술의 경우 설계도면 대비 약 20.5mm의 오차의 최대 절댓값이 발생하였다. 본 연구의 결과는 거푸집 제작시간과 정밀도 측면에서 S-LOM 방식 기술의 현장 적용 가능성을 확인하여, S-LOM 방식 기술의 개선 및 공법 활성화에 기여할 수 있을 것으로 사료된다.

• 대한기계학회논문집A
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• 제21권9호
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• pp.1385-1391
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• 1997

An analysis is presented on the stability of an elastic cantilever column subjected to a concentrated follower force as to the influence of the elastic restraint and a tip mass at the free end. The elastic restraint is formed by the rotatory springs. For this purpose, the governing equations and boundary conditions are derived by using Hamilton's principle, and the critical flutter loads and frequencies are obtained from the numerical evaluation of the eigenvalue functions of the considered system.

• 한국표면공학회지
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• 제17권2호
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• pp.41-58
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• 1984

Zinc was electrodeposited from cyanide solutions at temperature from 20$^{\circ}C\;to\;40^{\circ}C$ in the range of current density from 0.5 to 8A/$dm^2$. The preferred orientation changed from (10.3)+(11.0) to (11.0) texture with increasing cathode overpotential in the additive free solution, while the (11.0) preferred orientation developed at lower overpotentials (800-1270 mV) and the (11.0)+(10.0) preferred orientation was formed at higher overpotential (1300-1400mV) in the solution with brightner. Mossy type of morphology developed mostly in the additive free deposits and the microstructure of the cross section of the above deposits changed from columar structure to granular structure with increasing overpotential. The surface appearance of the deposits with additive having (11.0) texture was the smooth deposit of very small crystallite, while that of the deposits having (11.0)+(10.0) texture was fine crystalline deposit. The microstructure of the cross section of them was the fine field oriented type of structure.

• 한국생물정보학회:학술대회논문집
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• 한국생물정보시스템생물학회 2005년도 BIOINFO 2005
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• pp.35-40
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• 2005

Interaction of twelve erythromycin A analogues with 50S ribosomal subunit were studied employing AutoDock 3.0.5. Results showed that all active macrolides bound at the same binding site with erythromycin A in contrast to the inactive analogues which bound at location slightly different than erythromycin A. The binding site showed consistency with the X-ray data from the perspectives of hydrogen bonding and hydrophobic interactions formed by erythromycins, roxithromycin, azithromycin, cethromycin and telithromycin with the ribosome. The inactive derivatives of erythromycin A anhydride showed higher binding free energy, while 5-desosaminyl erythronolides A and B even though having quiet similar values of binding free energy with the active analogues, docked at binding sites which are quiet different than the active analogues. These results suggest the molecular docking technique can be used in predicting the binding of erythromycin A analogues to their ribosomal target.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2002년도 춘계학술대회 논문집
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• pp.297-300
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• 2002

In this study, the deformation of the free surface motion of a magnetic fluid for the change in electromagnetic force is discussed and carried out theoretically and experimentally on the basis of Rosensweig Ferrohydrodynamic Bernoulli Equation. While applied magnetic fields are induced by 4$\times$4 electromagnet located under the magnetic fluid, the surface of the magnetic fluid is formed the balance of surface force, gravity, pressure difference, magnetic normal pressure and magnetic body farce. In case, magnetic fluid in characteristics of fluid adjusted to the opposite direction of the gravity direction. thus, the device of a magnetic fluid proposed the surface actuator. The device of surface deformation as well comparison between numerical simulation and experiments as will be presented.

• 한국정보통신학회:학술대회논문집
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• 한국해양정보통신학회 2003년도 춘계종합학술대회
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• pp.359-362
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• 2003

Electrophoretic deposition (EPD) of alcohol YBCO suspensions on the Ag wire electrode is studied. Poly(ethylene glycol) was coordinated to a structure formed by the EPD process with YBCO particles. The suspension is characterized in terms of zeta potential and conductivity. The d.c electric fields of 200-300 V/cm are applied for 1-10 min. The optimal condition for the EPD allows modifying the properties and microstructure of the deposited films. Superconducting coatings with nanometer-sized pores and a preferred orientation along the c-axis were prepared from the result with chemically modified precursor solution. In contrast, YBCO coatings of submicrometer-sized pores and randomly orientated grains were prepared from the solution without PEG.

• Journal of Microbiology and Biotechnology
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• 제4권3호
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• pp.191-194
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• 1994

Acetoin and ammonia, the precursors of tetramethylpyrazine (TMP) having "nutty " or "roasted" flavors, were produced by cultivating Lactococcus lactis ssp. lactis biovar. diacetilactis FC1. The effects of the volume concentration ratio (VCR) of cell-free medium on the formation of TMP were investigated using a rotary evaporator at $70^{\circ}C than at 80^{\circ}C$. As the VCR increased, the formation of TMP and the conversion ratio of acetoin to TMP increased. More TMP were formed at $70^{\circ}C than at 80^{\circ}C$. As the VCR increased, the concentration of acetoin decreased implying the formation of TMP from acetoin and ammonia.

• Current Research on Agriculture and Life Sciences
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• 제12권
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• pp.51-55
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• 1994

작약(芍藥)의 약(葯)으로부터 분리된 화분소포자(花粉小胞子)를 생장조절제가 첨가되지 않은 MS 배지에 배양하였을때 직접 배(胚)발생 과정을 거쳐서 소포자 유래의 배(胚)가 형성되었고, 1mg/l의 PAA가 첨가된 배지에서는 화분소포자 유래의 캘러스가 형성 되었으며 이들 캘러스를 생장조절제를 함유하지 않은 배지에 이식하였을 때 배양 7주 후에 배(胚)가 형성되었다.