• Title/Summary/Keyword: Fossil fuels

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Effect of Template Existence on the Textural Properties of Iron-based Catalyst for Fischer Tropsch Reaction

  • Sirikulbodee, Papahtsara;Tungkamani, Sabaithip;Phongksorn, Monrudee;Ratana, Tanakorn;Sornchamni, Thana
    • International Journal of Internet, Broadcasting and Communication
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    • v.7 no.2
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    • pp.96-104
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    • 2015
  • Fischer Tropsch reaction is one of the interesting topic for renewable and clean energy. Polymerization of carbon monoxide or carbon dioxide with hydrogen over metal supported catalyst can produce long chain hydrocarbons. Synthetic liquid hydrocarbons are promising alternative to fossil fuels. This research work has been focused on the synthesis of Fe based catalyst for Fischer Tropsch reaction. Mesoporous silica (MS) support prepared by a precipitation method using two different washing solution, distilled water (DW) and acid in ethanol solution (ET), and different calcination temperature. Then, Fe/MS was prepared by an incipient wetness impregnation method. All of samples were systematically characterized using various physical and chemical techniques. TEM and XRD analysis were used to ensure that the cubic Ia3d mesostructure is stable after calcination. FTIR spectra are useful to ascertain the existence of template in the support. TPR studies were also used to understand the nature of Fe species and their reducibility. The results reveal that washing the support with distilled water and calcination at $550^{\circ}C$ can efficiently remove the triblock copolymer templates. The existence of template in the support affects the textural properties of all catalyst investigated.

Evaluations of Hydrogen Embrittlement Behaviours on Dissimilar Welding Part of SDS Bottles (II) (삼중수소 저장용기 이종용접부의 수소취화 거동 평가 (II))

  • Cho, Kyoungwon;Choi, Jaeha;Jang, Minhyuk;Lee, Youngsang;Hong, Taewhan
    • Journal of Hydrogen and New Energy
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    • v.26 no.2
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    • pp.120-126
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    • 2015
  • Recently, the ever-increasing use of fossil fuels for rapid industrial development and population significantly caused an environment pollution and global warming such as climate change. So research and development of sustainable and eco-friendly energy have been performed. Especially the interest in nuclear fusion fuel was significantly increased from the developed countries. The system of fusion energy production was tritium separation, storage and delivery, and purification. Republic of Korea is in charge of Storage and Delivery System (SDS) in the International Thermonuclear Experimental Reactor (ITER). Welding part of the SDS bottles for storing the tritium is known to be susceptible to hydrogen embrittlement. In this study, conducted a study for the relaxation of the stability and hydrogen embrittlement of the weld area. The hydrogen heat treatment was processed through the Pressure-Composition-Temperature (PCT) device according to the time variation. Also mechanical properties such as impact test and hardness test according to using the alkaline cleaning liquid for hydrogen embrittlement relief and the fracture was observed by scanning electron microscopy (SEM) after the mechanical properties evaluation.

Evaluations of Hydrogen Embrittlement Behaviours on Dissimilar Welding Part of SDS Bottles (I) (삼중수소 저장용기 이종용접부의 수소취화 거동 평가 (I))

  • Cho, Kyoungwon;Choi, Jaeha;Jang, Minhyuk;Lee, Youngsang;Hong, Taewhan
    • Journal of Hydrogen and New Energy
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    • v.26 no.2
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    • pp.114-119
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    • 2015
  • Nowdays, fossil fuels have been used as an important resource in development of industry. But it is limited and caused climate change such as pollution and global warming. So nuclear fusion research is being issued with tritium to develop eco-friendly and sustainable energy. Republic of Korea is in charge of Storage and Delivery System (SDS) in the International Thermonuclear Experimental Reactor (ITER), weld present in the SDS bottles are easily exposed to the hydrogen embrittlement of special characteristics of the hydrogen in hydrogen atmosphere, When the hydrogen embrittlement is rapidly progresses, the cracking is generated in the weld zone. Due to this cracking, the risk of leakage of tritium into the atmosphere occurs. In this study, hydrogen heat treatment was processed through the Pressure-Composition-Temperature (PCT) device according to the time variation. Also mechanical properties such as rupture strength test, three point bend test and hardness test in accordance with the respective time have been conducted and the fracture was observed by scanning electron microscopy(SEM) after the mechanical properties evaluation.

The Effect of $PtCl_4$ Concentration on Dye-Sensitized Solar Cell Efficiency ($PtCl_4$ 농도에 따른 염료감응형 태양전지의 효율 변화)

  • Seo, Hyun-Seung;Park, Mi-Ju;Choi, Eun-Chang;Lee, Sung-Uk;Kim, Hyung-Jin;Hong, Byung-You
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.435-436
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    • 2008
  • Dye-sensitized Solar Cells(DSSCs) which convert incident sun light into electricity were expected to overcome global warming and depletion of fossil fuels. And it is one of study that is lately getting into the spotlight because manufacturing method is more simple and inexpensive than existing silicon solar cells. In this respect, DSSCs are in the limelight as the next generation solar cells. DSSCs are generally composed of a dye-modified $TiO_2$ photoelectrode, a Pt counter electrode, and an electrolytes containing a redox couple$(I^-/I_3^-)$. Among these elements, pt electrode were prepared by applying electric potential to FTO substrate in the $H_2PtCl_6$ solution. In this study, we report the solar cell efficiency depending on $PtCl_4$ concentration change. $PtCl_4$ concentration was 1mM, 5mM, 10mM, and 20mM, and adhered on FTO glass substrate by sintering process. When applied each $PtCl_4$ counter electrode on DSSC, the best efficiency was found at 10mM of $PtCl_4$ concentration. The catalyst promotes the movement of electron from the counter electrode to the electrolyte the higher the molarity, the better the efficiency. However, in case of 20mM, it is estimated that over-deposited $PtCl_4$ tends to restrict the movement of electron due to its bundle formation.

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A Study of Energy Management Guide Using Building Energy Map By BIM -Focusing on Suseonggu Daegu city- (BIM을 이용한 건축물별 에너지 지도 작성 및 에너지 관리방안에 관한 연구 -대구시 수성구를 중심으로-)

  • Kim, Hye-Mi;Hong, Won-Hwa
    • Proceedings of the Korean Association of Geographic Inforamtion Studies Conference
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    • 2010.06a
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    • pp.81-82
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    • 2010
  • Emerging global economic growth and increasing demand for energy supply and demand imbalance and the excessive use of fossil fuels existing the rapidly increasing greenhouse gas emissions and resource depletion of global energy crisis is deepening. Accordingly, improvement of living conditions around and through the natural ecological preservation and the need for a comfortable life for the meeting the importance of energy management and consumption are emerging. Many in the field of architecture for energy-saving measures, and conducting research and verify green building energy ratings and low energy for the initial steps that can be verified from the Energy Performance of BIM(Building Information Model) technology development and commercialization of the building energy to predict the performance objectively, leverages technology in an existing building energy performance analysis and possibilities of BIM-based green building process presented. In this study, using BIM for existing building energy performance analysis of data collected through the objective and efficient management of the energy it consumes Mapping and Management Plan is to research on.

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A Review on Membranes and Catalysts for Anion Exchange Membrane Water Electrolysis Single Cells

  • Cho, Min Kyung;Lim, Ahyoun;Lee, So Young;Kim, Hyoung-Juhn;Yoo, Sung Jong;Sung, Yung-Eun;Park, Hyun S.;Jang, Jong Hyun
    • Journal of Electrochemical Science and Technology
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    • v.8 no.3
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    • pp.183-196
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    • 2017
  • The research efforts directed at advancing water electrolysis technology continue to intensify together with the increasing interest in hydrogen as an alternative source of energy to fossil fuels. Among the various water electrolysis systems reported to date, systems employing a solid polymer electrolyte membrane are known to display both improved safety and efficiency as a result of enhanced separation of products: hydrogen and oxygen. Conducting water electrolysis in an alkaline medium lowers the system cost by allowing non-platinum group metals to be used as catalysts for the complex multi-electron transfer reactions involved in water electrolysis, namely the hydrogen and oxygen evolution reactions (HER and OER, respectively). We briefly review the anion exchange membranes (AEMs) and electrocatalysts developed and applied thus far in alkaline AEM water electrolysis (AEMWE) devices. Testing the developed components in AEMWE cells is a key step in maximizing the device performance since cell performance depends strongly on the structure of the electrodes containing the HER and OER catalysts and the polymer membrane under specific cell operating conditions. In this review, we discuss the properties of reported AEMs that have been used to fabricate membrane-electrode assemblies for AEMWE cells, including membranes based on polysulfone, poly(2,6-dimethyl-p-phylene) oxide, polybenzimidazole, and inorganic composite materials. The activities and stabilities of tertiary metal oxides, metal carbon composites, and ultra-low Pt-loading electrodes toward OER and HER in AEMWE cells are also described.

Calculation of the Absorption Coefficient and Weighting Factor Expressing the Total Emissivity of Flame (화염의 총괄폭사 계수를 나타내는 급수계수 및 가중치의 계산)

  • 하만영;허병기
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.10 no.1
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    • pp.121-130
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    • 1986
  • Using the sbsorption coefficients and the weighting factors of the gray gas, the total emissivities of C $O_{2}$- $H_{2}$O and C $O_{2}$- $H_{2}$O- transient species-soot gas mixtures can be expressed by the following equation, [a numerical formula] Where, $a_{i}$ and $K_{i}$ represent the weighting factor and the absorption coeffient of i-gray gas respectively; L is the pathlength of the gas. This equation is widely used for the analyses of the radiation heat transfer in the combustors of internal combustion engines and in the furnace of external combustion engines. In this work, a simple calculation model of the weighting factor and the absorption coeffient of the above equation was developed. The weighting factors and the absorption coefficients of combustion products were calculated by applying the model to various kinds of fossil fuels such as coal and heavy oil. Then, the computed total emissivities for each fuel and pathlength were compared with measured and calculated values which have been already published in the literatures. The followings were the results obtained through the comparisons between the calculated emissivites and the published values; the developed model for the calculations of the weighting factor and the absorption coefficient of C $O_{2}$- $H_{2}$O and C $O_{2}$- $H_{2}$O- transient species-soot gas mixtures could be applied over the wide ranges of the temperature and the pathlength; the errors between the total emissivities calculted and the values published were maximum 10%, and average 1%, respectively.

Development of Product Management System for Higher-Value-Added Bicycle (고부가가치 자전거 개발을 위한 제품모델 및 관리시스템 개발)

  • Lee, Philippe;Hwang, In-Hyuck;Woo, Jong-Hun;Park, Se-Won;Oh, Dae-Kyun;Lee, Gyu-Bong
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.35 no.5
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    • pp.469-477
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    • 2011
  • Nowadays, environmentally friendly technology is attracting considerable attention because of environmental pollution and the increasing price of raw materials. Korea has a high level of dependence on exports, and therefore it has stressed the development of environmentally friendly technologies. Bicycle manufacturing industry has a bright future because bicycles do not use fossil fuels, and cycling is good for one's health. We develop a management system for the effective development of next-generation environmentally friendly technology for bicycles. The goal is to promote the bicycle industry in Korea while keeping the product in the low to medium price range.

Aerodynamic and Structural Design for Medium Size Horizontal Axis Wind Turbine Rotor Blade with Composite Material (복합재를 이용한 수평축 풍력터빈 회전 날개의 공력 및 구조설계에 관한 연구)

  • 공창덕;방조혁;오동우;김기범;김학봉
    • Journal of the Korean Society of Propulsion Engineers
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    • v.1 no.2
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    • pp.12-21
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    • 1997
  • Nowadays, non-pollution energy sources have been strongly needed because of the exhaustion of fossil fuels and serious environmental problems. Because wind energy can be enormously obtained from natural atmosphere, this type of energy has lots of advantages in a economic and pollution point of view. This study has established the aerodynamic and structural design procedure of the rotor blade with an appropriate aerodynamic performance and structural strength for the 500㎾ medium class wind turbine system. The aerodynamic configuration of the rotor blade was determined by considering the wind condition in the typical local operation region, and based on this configuration aerodynamic performance analysis was performed. The rotor blade has the shell-spar structure based on glass/epoxy composite material and is composed of shank including metal joint parts and blade. Structural design was done by the developed design program in this study and structural analysis, for instance stress analysis, mode analysis and fatigue life estimation, was performed by the finite element method. As a result, a medium scale wind turbine rotor blade with starting characteristics of 4m/s wind speed, rated power of 500㎾ at 12m/s wind speed and over 20 years fatigue life has been designed.

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A Study on High Efficiency Power Conditioning System for Safety Operation of PEMFC_type Fuel Cell Generation System (고분자전해질형 연료전지 발전시스템의 안전운전을 위한 고성능 전력변환기에 관한 연구)

  • Kwak Dong-Kurl
    • Journal of the Microelectronics and Packaging Society
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    • v.13 no.1 s.38
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    • pp.57-61
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    • 2006
  • Fuel cells are direct current (DC) power generators. They generate electricity through an electrochemical process that converts the energy stored in a fuel directly into electricity. Fuel cells have many benefits, which produce no particulate matter, nitrogen or sulfur oxides. And they have few moving parts and produce little or no noise. When fueled by hydrogen, they yield only heat and water as byproducts. Their wide application can reduce our dependence on fossil fuels and foreign sources of petroleum. This paper is studied on a high efficiency power conditioning system (PCS) applied to the proton exchange membrane fuel cell (PEMFC) generation system. This paper is designed to a novel PCS circuit topology of high efficiency. Some experimental results of the proposed PCS is confirmed to the validity of the analytical results.

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