• Title/Summary/Keyword: Forming Pressure

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Drilling Gas Hydrate at Hydrate Ridge, ODP Leg 204

  • Lee Young-Joo;Ryu Byong-Jae;Kim Ji-Hoon;Lee Sang-Il
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.06a
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    • pp.663-666
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    • 2005
  • Gas hydrates are ice-like compounds that form at the low temperature and high pressure conditions common in shallow marine sediments at water depths greater than 300-500 m when concentrations of methane and other hydrocarbon gases exceed saturation. Estimates of the total mass of methane carbon that resides in this reservoir vary widely. While there is general agreement that gas hydrate is a significant component of the global near-surface carbon budget, there is considerable controversy about whether it has the potential to be a major source of fossil fuel in the future and whether periods of global climate change in the past can be attributed to destabilization of this reservoir. Also essentially unknown is the interaction between gas hydrate and the subsurface biosphere. ODP Leg 204 was designed to address these questions by determining the distribution, amount and rate of formation of gas hydrate within an accretionary ridge and adjacent basin and the sources of gas for forming hydrate. Additional objectives included identification of geologic proxies for past gas hydrate occurrence and calibration of remote sensing techniques to quantify the in situ amount of gas hydrate that can be used to improve estimates where no boreholes exist. Leg 204 also provided an opportunity to test several new techniques for sampling, preserving and measuring gas hydrates. During ODP Leg 204, nine sites were drilled and cored on southern Hydrate Ridge, a topographic high in the accretionary complex of the Cascadia subduction zone, located approximately 80km west of Newport, Oregon. Previous studies of southern Hydrate Ridge had documented the presence of seafloor gas vents, outcrops of massive gas hydrate, and a pinnacle' of authigenic carbonate near the summit. Deep-towed sidescan data show an approximately $300\times500m$ area of relatively high acoustic backscatter that indicates the extent of seafloor venting. Elsewhere on southern Hydrate Ridge, the seafloor is covered with low reflectivity sediment, but the presence of a regional bottom-simulating seismic reflection (BSR) suggests that gas hydrate is widespread. The sites that were drilled and cored during ODP Leg 204 can be grouped into three end-member environments basedon the seismic data. Sites 1244 through 1247 characterize the flanks of southern Hydrate Ridge. Sites 1248-1250 characterize the summit in the region of active seafloor venting. Sites 1251 and 1252 characterize the slope basin east of Hydrate Ridge, which is a region of rapid sedimentation, in contrast to the erosional environment of Hydrate Ridge. Site 1252 was located on the flank of a secondary anticline and is the only site where no BSR is observed.

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Characteristics of Low Dielectric Constant SiOF Thin Films with Post Plasma Treatment Time (플라즈마 후처리 시간에 따른 저유전율 SiOF 박막의 특성)

  • Lee, Seok Hyeong;Park, Jong Wan
    • Journal of the Korean Vacuum Society
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    • v.7 no.3
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    • pp.267-267
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    • 1998
  • The fluorine doped silicon oxide (SiOF) intermetal dielectric (IMD) films have been of interest due to their lower dielectric constant and compatibility with existing process tools. However instability issues related to bond and increasing dielectric constant to water absorption when the SiOF films was exposured to atmospheric ambient. Therefore, the purpose of this research is to study the effect of post oxygen plasma treatment on the resistance of moisture absorption and reliability of SiOF film. Improvement of moisture absorption resistance of SiOF film is due to the forming of thin SiO₂layer at the SiOF film surface. It is thought that the main effect of the improvement of moisture absorption resistance was densification of the top layer and reduction in the number of Si-F bonds that tend to associate with OH bonds. However, the dielectric constant was increased when plasma treatment time is above 5 min. In this study, therefore, it is thought that the proper plasma treatment time is 3 min when plasma treatment condition is 700 W of microwave power, 3 mTorr of process pressure and 300℃ of substrate temperature.

Study on the shaping process of turbocharger nozzle slide joint (터보차저 노즐 슬라이드 조인트의 정형공정에 관한 연구)

  • Kim, Bong-Ju;Lee, Seon-Bong
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.1
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    • pp.107-114
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    • 2017
  • A turbocharger is an engine supercharger that is driven by exhaust gas. It improves the output and fuel efficiency by increasing the charging efficiency of the mixture gas, which is achieved by changing the rotatory power of the turbine connected to the exhaust passage. It is important to control the supercharging for this purpose. A nozzle slide joint is one of the core parts. Austenitic stainless steel is currently used as the material for this part, and its excellent mechanical properties include high heat resistance and corrosion resistance. However, because of its poor machinability, there are many difficulties in producing products with complicated shapes. Machining is used in the production of nozzle slide joints for high dimensional accuracy after metal powder injection molding. As design variables in this study, we investigated the sintering temperature, product stress, deformation rate, radius of curvature of the punch, and angle of the chamfer punch, which are related to the strain and shapes. The goal is to suggest a forming process using Nitronic 60 that does not require machining to manufacture a nozzle slide joint for a turbocharger. Accordingly, we determined the best process environment using finite-element analysis, the signal-noise ratio, and the Taguchi method for experiment design. The relative density and hydrostatic pressure of the final product were in accordance with the results of the finite element analysis. Therefore, we conclude that the Taguchi method can be applied to the design process of metal powder injection molding.

Effect of Pressing Process on the High-Temperature Stability of Yttria-Stabilized Zirconia Ceramic Material in Molten Salt of CaCl2-CaF2-CaO (CaCl2-CaF2-CaO 용융염에서 YSZ 세라믹의 고온 안정성에 미치는 성형공정의 영향)

  • Kim, Wan-Bae;Kwon, Suk-Cheol;Cho, Soo-Haeng;Lee, Jong-Hyeon
    • Korean Journal of Materials Research
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    • v.30 no.4
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    • pp.176-183
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    • 2020
  • The high-temperature stability of YSZ specimens fabricated by die pressure and cold isostatic press (CIP) is investigated in CaCl2-CaF2-CaO molten salt at 1,150 ℃. The experimental results are as follows: green density 46.7 % and 50.9 %; sintering density 93.3 % and 99.3 % for die press and CIP, respectively. YSZ foremd by CIP exhibits higher stability than YSZ formed by die press due to denseness dependency after high-temperature stability test. YSZ shows peaks mainly attributed to CaZrO3, with a small t-ZrO2 peak, unlike the high-intensity tetragonal-ZrO2 (t-ZrO2) peak observed for the asreceived specimen. The t-ZrO2 phase of YSZ is likely stabilized by Y2O3, and the leaching of Y2O3 results in phase transformation from t-ZrO2 to m-ZrO2. CaZrO3 likely forms from the reaction between CaO and m-ZrO2. As the exposure time increases, more CaZrO3 is observed in the internal region of YSZ, which could be attributed to the inward diffusion of molten salt and outward diffusion of the stabilizer (Y2O3) through the pores. This results in greater susceptibility to phase transformation and CaZrO3 formation. To use SOM anodes for the electroreduction of various metals, YSZ stability must be improved by adjusting the high-density in the forming process.

Nano-size Study of Surface-modified Ag Anode for OLEDs (표면처리에 의한 유기발광소자(OLED)용 Ag 전극의 Nano-size 효과 연구)

  • Kim, Joo-Young;Kim, Soo-In;Lee, Kyu-Young;Kim, Hyeong-Keun;Jun, Jae-Hyeok;Jeong, Yun-Jong;Kim, Mu-Chan;Lee, Jong-Rim;Lee, Chang-Woo
    • Journal of the Korean Vacuum Society
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    • v.21 no.1
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    • pp.12-16
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    • 2012
  • Although silver is used for T-OLED (Top emitting organic Light-Emitting Diode) as reflective anode, it is not an ideal material due to its low work function. Thus, we study the effect of annealing and atmospheric pressure plasma treatment on Ag film that increases its work function by forming the thin silver oxide layer on its surface. In this study, we deposited silver on glass substrate using RF sputtering. Then we treated the Ag samples annealing at $300^{\circ}C$ for 30 minutes in atmosphere or treating the atmospheric plasma treatment for 30, 60, 90, 120s, respectively. We measured the change of the mechanical properties and the potential value of surface with each one at a different treatment type and time. We used nano-indenter system and KPFM (Kelvin Probe Force Microscopy). KPFM method can be measured the change of surface potential. The nanoindenter results showed that the plasma treatment samples for 30s, 120s had very low elastic modulus, hardness and Weibull modulus. However, annealed sample and plasma treated samples for 60s and 90s had better mechanical properties. Therefore, plasma treatment increases the uniformity thin film and the surface potential that is very effective for the performace of T-OLED.

Preparation and Application of Pore-filled PVDF ion Exchange Membranes (Pore-filled PVDF 이온교환막의 제조 및 응용)

  • 변홍식;박병규;홍병표;여광수;윤무홍;강남주
    • Membrane Journal
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    • v.14 no.2
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    • pp.108-116
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    • 2004
  • In this study, the pore-filled ion-exchange membranes were prepared by using the asymmetric PVDF membrane as a nascent membrane. First, the solution of PVBCI having the chlorornethylate aryl ring of 80 percents and DABCO was made with the mixed solvent of THF and DU (8:2). These mixed solution was then, filled in the pores of PVDF membrane, and left for a day to complete the gelation. Finally the pore-filled anion-exchange membrane is obtained fallowed by the amination of the remaining chloromethyl groups with trimethylamine (TMA, 40 wt% in water) forming the positive ammonium ion sites. This 2 step procedure enabled us to produce the pore-filled membranes without change of size, and to control the properties of final membrane with various degree of cross-linking. The results of SEM and AFM showed the polyelectrolyte existed in the pores of nascent membrane as a certain configuration. From the investigation of the solvent affecting much to the permeability and rejection, it was found that the membranes using mixed solvent of THE and DMF (8:2) showed better performances than the membranes produced by THF only. The result of an investigation for the water permeability of the final membrane at low pressure (100 Kpa) showed a typical ultrafiltration membrane's permeability (8 ∼ 10 kg/$m^2$hr) and good values of rejection (55∼60 percent).

Microstructure and plasma resistance of Y2O3 ceramics (Y2O3 세라믹스의 미세구조 및 플라즈마 저항성)

  • Lee, Hyun-Kyu;Lee, Seokshin;Kim, Bi-Ryong;Park, Tae-Eon;Yun, Young-Hoon
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.24 no.6
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    • pp.268-273
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    • 2014
  • $Y_2O_3$ ceramic specimens were fabricated from the granular powder, obtained by spray drying process from the slurry. The slurry was prepared by mixing PVA binder, NaOH for Ph control, PEG and $Y_2O_3$ powder. The $Y_2O_3$ specimen was shaped in size of ${\phi}14mm$ and then sintered at $1650^{\circ}C$. The characteristics, microstructure, densities and plasma resistance of the $Y_2O_3$ specimens were investigated with the function of forming pressure and sintering time. $Y_2O_3$ specimens were exposed under the $CHF_3/O_2/Ar$ plasma, the dry etching treatment of specimens was carried out by the physical reaction etching of $Ar^+$ ion beam and the chemical reaction etching of $F^-$ ion decomposed from $CHF_3$. With increasing sintering time, $Y_2O_3$ specimens showed relatively high density and strong resistance in plasma etching test.

Performance of Underwater Communication in Low Salinity Layer at the Western Sea of Jeju (제주도 서부 해역의 저염수층을 고려한 수중통신 성능)

  • Bok, Tae-Hoon;Kim, Ju-Ho;Lee, Chong-Hyun;Bae, Jin-Ho;Paeng, Dong-Guk;Pang, Ig-Chan;Lee, Jong-Kil
    • Journal of the Institute of Electronics Engineers of Korea TC
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    • v.48 no.1
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    • pp.16-24
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    • 2011
  • The sound speed of seawater can be calculated by the empirical formula as a function of temperature, salinity and pressure. It is little affected by salinity because the average salinity is 34 psu and varies within a few psu seasonally and spatially in the ocean. Recently, low-salinity water of 24 psu flows into the western sea area of Jeju Island due to the flood of the Yangtze River in China during summer, affecting sound speed profile. In this paper, it was analyzed how environmental changes affected to the underwater communication - the sound speed of low-salinity water was calculated, and the communication channel was estimated by the simulated acoustic rays while the transmitting and receiving depth and the range were varied with and without the low-salinity layer. And The BER (Bit error rate) was calculated by BPSK(Binary phase shift key) modulation and the effects of the low-salinity water on the BER was investigated. The sound speed profile was changed to have positive slope by the low-salinity layer at the sub-surface up to 20 m of depth, forming acoustic wave propagation channel at the sub-surface resulting in the decrease of most of the BER Consequently, this paper suggests that it is important to consider changes of the ocean environment for correctly analyzing the underwater communication and the detection capability.

A Study on the Costume of Ch'ing Dynasty in "Dream of the Read Chamber" ("홍루몽"에 나타난 청대복식 연구)

  • 나해연;전혜숙
    • Journal of the Korean Society of Costume
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    • v.24
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    • pp.59-82
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    • 1995
  • All kinds of art are the creatures of the daly and reflect the society and the life of the day in literary works. So, in which literary works, we can find the styles of those who lived in the specified days. And the styles of its character's costume are expressed with the day'mood and cultural backgrounds. In this study, we studied on the general meaning, which was shown in the Costume of early Ch'ing Dynasty that was forming the Costume of dress through dividing into the underwear and the outer garment in $\ulcorner$Dream of the read Chamber$\lrcorner$. During the Ch'ing Dynasty, according to the rule : Men followed it but women not" , they held on to the costume of them (both the Man and the Han) with a high pressure and a conciliatory policy. As a result, I have known that there is the Soojean clothe(수전의), which is the late Myung Dynasty's one and their is also Skirt (군), which held on the Costume of the Myung's. Hence in the Ch'ing , there are a lot of difference in the Costume , the economy and the politic because the ruler was not the han but the Ch'ing. Those characters are as follows. first, on the side of the style , it is occured in the coat and the over jacket of the round neckline. The style of the sleeves are also the tightly(고착). Second, on the side o f the material, the use of the furs are found. It seems that are influence of the north area. Third, it is involved not the traditional Costume of the Han, but the over jacket(which is waistlength), These characters had taken root into the Costume of the Ch'ing Dynasty. In case of the jacket, which are found in the novel most frequently , it was represented by the tight jacket (소오), the long jacket (대오), the short jacket(단오) and the Sam (삼). The skirt was used by women only. the Slacks were trousers only for men, so it was not foujnd in the women's wear. In the vest, the over jacket and coat, which are for putting on, its material, insiqnia and varied embroidery are very brillant and elaborate. The used materials are the silks , furs, wools and cottons. Among the dick silks are used most frequently . in case of the over jacket, the precious and varied furs are used for the collar, the sleeve or the decoration and the lining cloth. In the novel, mean followd the Costume of the Man and women followed the Costume of the Han. Especially, it is a special costume that there were women in male attire. Finally, the costume of the Ch'ing had built the unique one with holding on the advantage and the short point s of the northen race and the Han's. Also , I can find the brilliant , eleborate Customes of the aristocratic class in the novel.

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Changes of Nitrogen-Fixation Activity and Environmental Factors of Growth in Lespedeza bicolor Turcz (싸리(Lespedeza bicolor Turcz.)의 공생 질소고정활성과 생육환경요인의 변화)

  • 송승달
    • Journal of Plant Biology
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    • v.35 no.4
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    • pp.317-322
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    • 1992
  • The nitrogen fixation activity and environmental factors of Lespedeza bicli!oy Turcz, forming annual root nodules by symbiotic Rhizobium sp. were analyzed in the field conditions during the growing period. Seasunal changes of $N_2-fixation$ activity showed the maximum value of $120\;\mu\textrm{M}\;C_2_H4{\cdot}noduie\;g\;fw^{-1}{\cdot}hr^{-1}$ during the active growing period (June) and varied significantly depending on the growth phase and environmental factors. The maximum activities were attained at the conditions of pH 7, $30^{\circ}C$ of temperature, 18 Kpa of oxygen partial pressure and inhibited by water stress and nitrogen sources. The habitat soil was weak acidic and poor in nitrogen, phosphorus and organic matter contents. The leaf area ratios and chlorophyll contents were ranged from 442 to $48;\textrm{cm}^2{\cdot}g\;dw^{-1}$ and from 33 to $38\;\mu\textrm{g}\;chI{\cdot}\textrm{cm}^2$. Nitrogen contents in each organ showed the maximum of 46, 19 and $11\;mg{\cdot}g\;dw^{-1}, respectively for leaf, rool and stem in the early period. The highest phosphorus contents were 4.2, 1.2 and $0.6\;mg{\cdot}g\;dw^{-1}$, respectively for leaf. root and stem in early growing period. The allocation ratios of nitrogen quantity showed 60% for leaves and 73% for roots during the active and late growth period, and 22% [or stems in average. The allocalion ralios o[ phosphorus quantity showed 58% for leaves during the most productive period, 70% for roots in the pre-growth stage and 26% for stems in average.verage.

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