• Title/Summary/Keyword: Form removal

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KEY IMPACT PARAMETERS FOR APPLICATION OF ALTERNATIVE SOURCE TERM TO KORI UNIT 1

  • Lee, Seung-Chan
    • Nuclear Engineering and Technology
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    • v.42 no.4
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    • pp.394-413
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    • 2010
  • The object of this paper is to identify the key elements that impact a radiation dose at EAB (Exclusion Area Boundary). This study is based on the AST (Alternative Source Terms) as defined in Regulatory Guide 1.183. The LOCA (Loss of Coolant Accident) and the LRA (Locked Rotor Accident) are selected as limiting cases. A sensitivity analysis of accidental behavior with respect to various parameters during LOCA and LRA at Kori Unit 1 is also undertaken for the following objectives: to determine the limiting parameters, to find the impact trend of the radiation dose, and to find the safety margin between AST and TID (Technical Information Document) methodologies. This work confirms that key parameters are particulate removal rate, decontamination factor, iodine chemical form, gap fraction, partitioning factor, and the impact of isotopes group. Comparing TID with AST, the radiation dose of TID is about 80% greater than that of AST under a LOCA, and about 60% greater than that of AST for the case of a LRA; thus the safety margin is remarkably increased when the AST is used. In this work, the sensitivity analysis results are presented in terms of a sensitivity index called the "NDD (Normalized Dose Difference)", which compares the impact of parameters with that of a reference case. These values are derived by using a combination of the leak rate (primary to secondary), iodine chemical form, gap fraction, partitioning factor, spray removal rate, source term, and other variables.

Effect of Hydrochloric Acid Concentration on Removal Efficiency and Chemical Forms of Heavy Metals During Dredged Sediment Acid Washing (준설토 산세척 시 염산 농도가 중금속의 정화효율 및 존재형태에 미치는 영향)

  • Kim, Kibeum;Choi, Yongju
    • Journal of Soil and Groundwater Environment
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    • v.25 no.1
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    • pp.74-83
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    • 2020
  • In this study, the effect of hydrochloric acid (HCl) concentrations on removal efficiency and chemical forms of heavy metals in dredged sediment during acid washing was investigated. The removal efficiencies of Zn, Cu, Pb, Ni and Cd by acid washing were 18.4-92.4%, 7.2-83.7%, 9.4-75%, 8.1-53.4% and 34.4-70.8%, respectively. Overall, the removal efficiencies of heavy metals were remarkably enhanced with the increase of the acid strength. However, the removal efficiencies for 0.5 and 1.0 M HCl were comparable, and both cases met the Korean soil contamination standard. Based on the sequential extraction results, concentration of the exchangeable fraction (F1), the most labile fraction, increased whereas concentrations of the other fractions decreased with increasing acid strength. Particularly, the carbonate (F2) and Fe/Mn oxides (F3) fractions drastically decreased by using 0.5 M or 1.0 M HCl. The current study results verified that acid washing could effectively reduce heavy metal concentrations and its potential mobility in dredged sediments. However, the study also found that acid washing may cause significant increase in bioavailable fraction of heavy metals, suggesting the need to evaluate the changes in chemical forms of heavy metals by acid washing when determining the acid strength to be applied.

Modeling of Foam Separator for Sea Water Treatment (해수 포말분리공정의 해석 및 모델)

  • HUR Hyun-Chul;SEO Jae-Koan;PARK Eun-ju;KIM Sung-Koo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.32 no.2
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    • pp.165-169
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    • 1999
  • Experiments were conducted to evaluate a experimental model developed for the protein removal by foam separation. The foam separator was operated in well-mixed tank which would be considered as a completely mixed condition. The feasibility of foam separation to remove protein from sea water was investigated. Protein removal characteristics of the foam separator were obtained by batch experiments. To find the effect of the operating parameter to protein removal rate, the foam separation was carried with variation of initial protein concentration and superficial air velocity. The result indicated that the protein removal efficiency was increased with increasing protein concentration and superficial air velocity. The relationship between operation parameters and protein removal rate were evaluated by non-linear regression as the form of exponential function, Using both relationships, the simplified model was determined. The simplified foam separator operation model was verified by the batch operation. The simulation results showed a good relationship with the experimental data.

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Phosphate Removal in the Wastewater by the different Size of Granular Converter Slag (입상 전로슬래그의 입도 차이에 따른 인공폐수의 인산염 제거에 관한 연구)

  • Lee, Sang-Ho;Lee, In-Gu
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.8 no.1
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    • pp.136-142
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    • 2007
  • Recent publications have paid attention on the utilization of solid reagents for the removal of substances causing eutrophication, in particular $PO_4^{3-}$ ions. The adsorption of dissolved inorganic phosphate on slag produced by the refining process of iron ore was fundamentally studied for suppressing the liberation of phosphate from wastewater. This study has been conducted in order to find a possibility to improve the phosphate removal and to evaluate the phosphate removal variation to form hydroxyapatite, when the converter slag is used for phosphate removal. The result shows that the converter slag can be applied to remove phosphate using Freundlich isotherm. The size of converter slag, $2{\sim}0.425 mm$ was more efficient than $2{\sim}4.75mm$ to remove phosphate. In particular, 1 mg/L of phosphate can be removed up to 80% of the initial concentration for the continuous column experiment.

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Performances of submerged membrane photocatalysis reactor during treatment of humic substances

  • Halim, Ronald;Utama, Robert;Cox, Shane;Le-Clech, Pierre
    • Membrane and Water Treatment
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    • v.1 no.4
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    • pp.283-296
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    • 2010
  • During the disinfection of potable water, humic substances present in the solution react with chlorine to form potential carcinogenic compounds. This study evaluates the feasibility of using a submerged membrane photocatalysis reactor (SMPR) process for treatment of humic substances through the characterization of both organic removal efficiency and membrane hydraulic performance. A simple SMPR was operated and led to the removal of up to 83% of the polluting humic matters. Temporal rates of organic removal and membrane fouling were found to decrease with filtration time. Using tighter membrane in the hybrid process resulted in not only higher organic removal, but also more significant membrane fouling. Under the experimental conditions tested, optimum $TiO_2$ concentration for humic removal was found to be 0.6 g/L, and increasing initial pollutant concentration expectedly resulted in a more substantial membrane fouling. The importance of the influent nature and pollutant characteristics in this type of treatment was also assessed as various water sources were tested (model humic acid solution vs. local water containing natural organic matters). Results from this study revealed the promising nature of the SMPR process as an alternative technique for organic removal in the existing water treatment system.

Phosphate Removal from Aqueous Solution by Aluminum (Hydr)oxide-coated Sand

  • Han, Yong-Un;Park, Seong-Jik;Park, Jeong-Ann;Choi, Nag-Choul;Kim, Song-Bae
    • Environmental Engineering Research
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    • v.14 no.3
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    • pp.164-169
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    • 2009
  • A powder form of aluminum (hydr)oxides is not suitable in wastewater treatment/filtration systems because of low hydraulic conductivity and large sludge production. In this study, aluminum (hydr)oxide-coated sand (AOCS) was used to remove phosphate from aqueous solution. The properties of AOCS were analyzed using a scanning electron microscopy (SEM) combined with an energy dispersive X-ray spectrometer (EDS) and an X-ray diffractometer (XRD). Kinetic batch, equilibrium batch, and closed-loop column experiments were performed to examine the adsorption of phosphate to AOCS. The XRD pattern indicated that the powder form of aluminum (hydr)oxides coated on AOCS was similar to a low crystalline boehmite. Kinetic batch experiments demonstrated that P adsorption to AOCS reached equilibrium after 24 h of reaction time. The kinetic sorption data were described well by the pseudo second-order kinetic sorption model, which determined the amount of P adsorbed at equilibrium ($q_e$ = 0.118 mg/g) and the pseudo second-order velocity constant (k = 0.0036 g/mg/h) at initial P concentration of 25 mg/L. The equilibrium batch data were fitted well to the Freundlich isotherm model, which quantified the distribution coefficient ($K_F$ = 0.083 L/g), and the Freundlich constant (1/n = 0.339). The closed-loop column experiments showed that the phosphate removal percent decreased from 89.1 to 41.9% with increasing initial pH from 4.82 to 9.53. The adsorption capacity determined from the closed-loop experiment was 0.239 mg/g at initial pH 7.0, which is about two times greater than that ($q_e$ = 0.118 mg/g) from the kinetic batch experiment at the same condition.

Removal of Post Etch/Ash Residue on an Aluminum Patterned Wafer Using Supercritical CO2 Mixtures with Co-solvents and Surfactants: sc-CO2 Mixture for the Removal of Post Etch/Ash Residue

  • You, Seong-sik
    • Journal of the Semiconductor & Display Technology
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    • v.16 no.1
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    • pp.22-28
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    • 2017
  • The result of stripping process for the removal of the post etch/ash Photoresist (PR) residue on an aluminum patterned wafer by using supercritical $CO_2$ ($sc-CO_2$) mixture, was investigated by scanning of electron microscope (SEM) inspection of wafer, measuring the cloud points and visual observation of the state of $sc-CO_2$ mixtures. It was found that $sc-CO_2$ mixtures were made by mixing additives and $sc-CO_2$ should form homogeneous and transparent phase (HTP) in order to effectively and uniformly remove the post etch/ash PR residue on the aluminum patterned wafer using them. The additives were formulated by mixing and co-solvents like an amine compound and fluorosurfactants used as HTP agents, and the PR residue on the wafer were able to be rapidly and effectively removed using the $sc-CO_2$ mixture of HTP. The five kinds of additives were formulated by the recipe of mixing co-solvents and surfactants, which were able to remove PR residue on the wafer by mixing with $sc-CO_2$ at the stripping temperature range from 40 to $80^{\circ}C$. The five kinds of $sc-CO_2$ mixtures which were named as PR removers were made, which were able to form HTP within the above described stripping temperature. The cloud points of $sc-CO_2$ mixtures were measured to find correlation between them and HTP.

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Application of Gas to Particle Conversion Reaction to increase the DeSOx/DeNOx Efficiency under Pulsed Corona Discharge (DeSOx/DeNOx 효율 개선을 위한 펄스 코로나 방전하에서 기체미립자 전환반응의 적용)

  • Choi, Yu-ri;Kim, Dong-Joo;Kim, Kyo-Seon
    • Journal of Industrial Technology
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    • v.18
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    • pp.249-258
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    • 1998
  • In this paper, we investigated the post-combustion removal of nitrogen oxide($NO_x$) and sulfur oxide($SO_x$) which is based on the gas to particle conversion process by the pulsed corona discharge. Under normal pressure, the pulsed corona discharge produces the energetic free electrons which dissociate gas molecules to form the active radicals. These radicals cause the chemical reactions that convert $SO_x$ and $NO_x$ into acid mists and these mists react with $NH_3$ to form solid particles. Those particles can be removed from the gas stream by conventional devices such as electrostatic precipitator or bag filter. The reactor geometry was coaxial with an inner wire discharge electrode and an outer ground electrode wrapped on a glass tube. The simulated flue gas with $SO_x$ and $NO_x$ was used in the experiment. The corona discharge reactor was more efficient in removing $SO_x$ and $NO_x$ by adding $NH_3$ and $H_2O$ in the gas stream. We also measured the removal efficiency of $SO_x$ and $NO_x$ in a cylinder type corona discharge reactor and obtained more than 90 % of removal efficiency in these experimental conditions. The effects of process variables such as the inlet concentrations of $SO_x$, $NH_3$ and $H_2O$, residence time, pulse frequencies and applied voltages were investigated.

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Reduction of Hydrogen Sulphide in Chicken Manure by Immobilized Sulphur Oxidising Bacteria Isolated from Hot Spring

  • Hidayat, M.Y.;Saud, H.M.;Samsudin, A.A.
    • Microbiology and Biotechnology Letters
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    • v.47 no.1
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    • pp.116-124
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    • 2019
  • The rapid development of the poultry industry has led to the production of large amounts of manure, which produce substances like hydrogen sulfide ($H_2S$) that contribute to odor pollution. $H_2S$ is a highly undesirable gas component and its removal from the environment is therefore necessary. Sulfur-oxidizing bacteria (SOB) are widely known to remove contaminating $H_2S$ due to their ability to oxidize reduced sulfur compounds. In this study, three potential SOB (designated AH18, AH25, and AH28) that were previously isolated from a hot spring in Malaysia were identified by 16S rRNA gene analysis. Laboratory-scale biological deodorization experiments were conducted to test the performance of the three isolates-in the form of pure or mixed cultures, with the cells immobilized onto alginate as a carrier-in reducing the $H_2S$ from chicken manure. On the basis of 16S rRNA phylogenetic analysis, isolate AH18 was identified as Pseudomonas sp., whereas isolates AH25 and AH28 were identified as Achromobacter sp. The most active deodorizing isolate was AH18, with an $H_2S$ reduction rate of 74.7% (p < 0.05). Meanwhile, the reduction rates for isolates AH25 and AH28 were 54.2% and 60.8% (p > 0.05), respectively. However, the $H_2S$ removal performance was enhanced in the mixed culture, with a reduction rate of 81.9% (p < 0.05). In conclusion, the three potential SOB isolates were capable of reducing the $H_2S$ from chicken manure in the form of a pure culture immobilized on alginate, and the reduction performance was enhanced in the mixed culture.

A Study on Process of Change and Assumption of Archetype of Winsborough Hall at Speer Girls' School in Gwangju (광주구수피아여학교 윈스브로우홀의 변화와 원형추정 연구)

  • Shin, Woong-Ju;Sung, Dae-Chul
    • Journal of the Korean Institute of Rural Architecture
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    • v.14 no.4
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    • pp.97-105
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    • 2012
  • Winsborough Hall built by Martin L. Winehart who was the missionary of the Presbyterian Church of America in 1927 was built by Mrs. Winsborough's birthday contribution. Winsborough Hall was clearly divided into the original form built in 1927 and remodelled form by extension. Most of walls were constructed with several kinds of bricks for both sides and opening in the original form and remodelled form. Each room divided by inner wall was kept with original form because it is difficult to remodel it on the characteristics of building. But, it was confirmed through the related literatures that security of opening at some rooms and annexation of rooms through removal of the wall on the 2nd floor which was relatively easy to transform wall compared to the first floor were made. Variability of the wall affected the truss structure of roof and it created rare double truss structure. Architectural value of Winsborough Hall was in its first architectural trial using red brick in Gwangju region since 1920s. It suggested that it was differential architectural trial from Korean-Western mixed building constructed by the missionaries from 1940 to 1910 and buildings made of gray bricks prevailed from 1911 to 1920 and it showed the advancement in the architectural structure and materials.