• Resources Recycling
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• v.3 no.1
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• pp.17-24
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• 1994

Recovery of precious metal values from petrochemical spent catalyst is important from the viewpoint of environmental protection and resource recycling. Two types of spent catalysts were used in this study. One used in the manufacture of ethylene contains 0.3% Pd in the alumina substrate. The other used in oil refining contains 0.3% Pt and 0.3% Re. Both spent catalysts are roasted to remove volatile matters as carbon and sulfur. Then, metallic Pd powder from Pd spent catalyst is obtained in the course of grinding, hydrochloric acid or aqua regia leaching and cementation with iron. For the recovery of Pt and Re from Pt-Re spent catalyst, Pt and Re are leached with either HCI or aqua regia, first. Metallic Pt powder is recovered from the leach solution by cementation with Fe powder. Re in sulfide form is precipitated by the addition of sodium sulfide to the solution obtained after Pt recovery. It is found that 6N HCI can be successfully used as leaching agent for both types of spent catalyst. 6N HCI is considered to be better than aqua regia in consideration of reagent and equipment cost.

• Journal of Technologic Dentistry
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• v.45 no.4
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• pp.87-94
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• 2023

Purpose: This study aimed to observed changes in the shape of dental barrels based on application time. Machinability measures the angle of alloy specimens. Polishing performance measures the surface roughness of alloy specimens. Methods: The dental barrel polishing equipment used in this study was a Snow Barrel (DK Mungyo). Three types of cobalt-chromium alloys for partial dentures were used as specimens (BC CAST R [BP]; Bukwang, Vera PDI [VP]; Aalbadent, and GM 800+ [GP]; Dentaurum). Specimens were prepared in the form of plates (10 mmx10 mmx2 mm). Dental barrel polishing was performed at 450 rpm for 60 minutes with intervals of 5 minutes. The processing angle was measured using a microscope (SZ61; Olympus). Results: For the angle measurement, the VPC specimen was measured at 78.64°, 36.00° for the VP60 specimen, 79.57° for the BP control (BPC) specimen, 28.07° for the BP60 specimen, 75.01° for the GPC specimen, and 39.92° for the GP60 specimen. For the surface roughness measurements, the average surface roughness of the VPC and VP15 specimens were 1.09 ㎛ and 0.26 ㎛, respectively. The average surface roughness of the BPC and BP20 specimens were 1.77 ㎛ and 0.29 ㎛, respectively. The average surface roughness of the GPC and GP15 specimens were 1.08 ㎛ and 0.27 ㎛. Conclusion: The results were excellent after about 20 minutes of dental barrel polishing conditions presented in this study.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.48 no.2
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• pp.34-45
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• 2016

Global warming and climate change have been caused by combustion of fossil fuels. The greenhouse gases contributed to the rise of temperature between $0.6^{\circ}C$ and $0.9^{\circ}C$ over the past century. Presently, fossil fuels account for about 88% of the commercial energy sources used. In developing countries, fossil fuels are a very attractive energy source because they are available and relatively inexpensive. The environmental problems with fossil fuels have been aggravating stress from already existing factors including acid deposition, urban air pollution, and climate change. In order to control greenhouse gas emissions, particularly CO2, fossil fuels must be replaced by eco-friendly fuels such as biomass. The use of renewable energy sources is becoming increasingly necessary. The biomass resources are the most common form of renewable energy. The conversion of biomass into energy can be achieved in a number of ways. The most common form of converted biomass is pellet fuels as biofuels made from compressed organic matter or biomass. Pellets from lignocellulosic biomass has compared to conventional fuels with a relatively low bulk and energy density and a low degree of homogeneity. Thermal pretreatment technology like torrefaction is applied to improve fuel efficiency of lignocellulosic biomass, i.e., less moisture and oxygen in the product, preferrable grinding properties, storage properties, etc.. During torrefacton, lignocelluosic biomass such as palm kernell shell (PKS) and empty fruit bunch (EFB) was roasted under an oxygen-depleted enviroment at temperature between 200 and $300^{\circ}C$. Low degree of thermal treatment led to the removal of moisture and low molecular volatile matters with low O/C and H/C elemental ratios. The mechanical characteristics of torrefied biomass have also been altered to a brittle and partly hydrophobic materials. Unfortunately, it was much harder to form pellets from torrefied PKS and EFB due to thermal degradation of lignin as a natural binder during torrefaction compared to non-torrefied ones. For easy pelletization of biomass with torrefaction, pellets from PKS and EFB were manufactured before torrefaction, and thereafter they were torrefied at different temperature. Even after torrefaction of pellets from PKS and EFB, their appearance was well preserved with better fuel efficiency than non-torrefied ones. The physical properties of the torrefied pellets largely depended on the torrefaction condition such as reaction time and reaction temperature. Temperature over $250^{\circ}C$ during torrefaction gave a significant impact on the fuel properties of the pellets. In particular, torrefied EFB pellets displayed much faster development of the fuel properties than did torrefied PKS pellets. During torrefaction, extensive carbonization with the increase of fixed carbons, the behavior of thermal degradation of torrefied biomass became significantly different according to the increase of torrefaction temperature. In conclusion, pelletization of PKS and EFB before torrefaction made it much easier to proceed with torrefaction of pellets from PKS and EFB, leading to excellent eco-friendly fuels.

• Transactions of the Korean Society of Automotive Engineers
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• v.22 no.5
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• pp.20-28
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• 2014

The high velocity oxygen fuel spraying (HVOF) is a kind of surface modification process technology to form the sprayed coating layer after spraying the powder to molten or semi-molten state by the ultra-high speed at the high-temperature heat source and conflicting with a substrate. It is desirable to melt completely the thermal spray powder in order to produce the coating layer with an optimal adhesion, however, because a semi-molten powder in a spray process has the low efficiency and become a factor that degrades the mechanical property by the inducement of pore-forming within the coating layer. To improve the wear resistance, corrosion resistance and heat resistance, in this study, the plungers of high-speed and ultra-high pressure reciprocating hydraulic pumps for oil and water used in ironwork are produced with $420J_2$ and the coating layers of plungers are formed by the powders of WC-Co-Cr and WC-Cr-Ni including the high hardness WC. The surface of these plungers is modified by the super-mirror face grinding machine using variable air pressure developed in this laboratory, and then the characteristics of cross-sectional microstructure, and surface roughness and hardness values between no operation and 100 days-operation are examined and made a comparison. The fine tops and bottoms on surface roughness curve of oil-hydraulic pump plunger sprayed by WC-Cr-Ni are molded more and higher than those of water-hydraulic pump sprayed by WC-Co-Cr because the plunger diameter of oil-hydraulic pump is 0.4 times smaller than that of water-hydraulic pump and the pressure of oil-hydraulic pump exerted on the plunger is operated with the 70 bars higher than that of water-hydraulic pump. As a result, it is found that the values of centerline average surface roughness and maximum height for oil-hydraulic pump plunger are bigger than those of water-hydraulic pump plunger.

• The Korean Journal of Pesticide Science
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• v.14 no.3
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• pp.219-225
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• 2010

The solubility in water of granular pesticides is not equal because the difference of methods of producing a granular pesticide. This study was conducted to investigate fish acute toxicity of butachlor 5% GR, fipronil 0.4% GR by impregnation and carbosulfan 3% GR, diazinon 0.4% GR by coating, using carp (C. carpio), medaka (O. tatipes) and loach (M. anguillicaudatus). The test solution of each pesticide was prepared by direct addition of granular pesticide and add after grinding granular pesticide to powder in test water, We also investigated $LC_{50}$ and residual concentration until 96 hours. Test results were appeared that the treatment of powder was 1.2~4 time higher than granular and toxicity increased clearly according to elapsed time, And the residual amounts by time were detected much at early time in the powder treatment of butachlor GR and diazinon GR. Conclusively, fish acute toxicity and residual concentration in test solution appeared higher in the powder treatment than treat granular form directly in water. Also, 96 hours toxicity values were stable comparatively and the error is less than 48 hours.

• Proceedings of the Korean Society for Agricultural Machinery Conference
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• 2002.02a
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• pp.263-268
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• 2002

본 연구는 고추분쇄용 세라믹 롤 분쇄기를 이용하여 고춧가루 생산시, 분쇄효율을 향상시키고자 기존의 롤 분쇄속도 40rpm(0.352m/s)에서 80rpm(0.704%)으로 증가시키고, 기존의 롤 회전비 2:1에서 5:1로 증가시켜 고추분쇄시 전단력 증가로 분쇄능을 향상시켰고, 연구 내용의 주요 결과를 요약하면 다음과 같다. 1. 세라믹치형롤 분쇄속도 40rpm(0.352m/s)에서는 롤 회전비 2:1에서 1,190$\mu\textrm{m}$ 입자가 32.7%, 590$\mu\textrm{m}$ 입자가 19.7%였고, 롤 회전비를 5:1로 증가시 590$\mu\textrm{m}$ 입자가 30.9%, 420$\mu\textrm{m}$ 입자가 17.2%로 중간 미분쇄 영역의 분포가 증가하여 미분쇄 효율이 향상됨을 알 수 있었다. 2. 분쇄물의 롤 통과횟수에 따른 분쇄능은 세라믹치형롤 모두 분쇄속도 80rpm(0.704m/s)에서 분쇄물의 미분쇄능이 향상되었고, 분쇄생성물의 임계처리 횟수가 3~4차임을 분석할 수 있었다. 3. 보통 고춧가루를 생산하는데 분쇄속도 40rpm(0.352m/s), 80rpm(0.704m/s), 두 롤의 회전비 2:1, 3:1, 4:1하에서는 생산되지 않았으나, 롤 회전비 5:1에서는 분쇄속도 40rpm(0.352m/s)일 경우 7차 분쇄후에, 분쇄속도 80rpm(0.704m/s)일 경우 5차분쇄후에 생성되어 분쇄처리횟수가 2회정도 단축되어 전단력 증가로 인하여 분쇄능이 향상된 것으로 분석되었다. 4. 기존의 고춧가루 분쇄조건인 분쇄속도 40rpm(0.352m/s), 롤 회전비 2:1보다 본 연구에서 개발한 분쇄속도 80rpm(0.704m/s), 롤 회전비 5:1인 분쇄조건이, 분쇄처리 횟수 단축 등이 분석됨으로서 섬유질이 많이 포함된 고춧가루 등의 재료가공 분쇄기술이 향상된 것으로 분석되었다.. 마늘재배 일관기계화에 의한 노동투하시간과 비용 -종자준비부터 통마늘선별까지의 일관기계화로 투입된 주요작업의 노력은 75∼76%가 절감되고, 재배규모 3ha기준시 비용은 44-53%절감되었음. the annealing texture. Observations by TEM and EBSD revealed the formation of very fine grains of ∼1.0$\mu\textrm{m}$ after CCSS.he dislocations form local defect arrangements at the grooves permitting the substantial reduction in defect density over the remainder of the interfacial area.한 최대의 감자 재배지역을 형성하였다. 제주도는 산지지형과 따뜻한 기온으로 2기작이 가능하고, 감자가공 공장설립과 교통발달에 따른 육지 시장과의 접근이 용이해졌기 때문에 남한에서 2번째로 큰 감자재배지역이 되었다.(요약 및 결론에서 발췌)그람양성균에서 효과적이었으며, 농도별 항균력시험 결과 농도가 증가할수록 비례하여 저해율도 증가함을 알 수 있었다. 첨가농도를 달리하여 미생물의 생육도를 측정한 결과, fraction II磎꼭\ulcorner경우 그람양성균에 대해 500 ppm 이상에서 뚜렷한 증식억제효과를 나타내었다.서 뚜렷한 증식억제효과를 나타내었다.min/+}$계 수컷 이형접합체 형질전환 마우스에 AIN-76A 정제사료만을 투여한 대조군은 1.40$\pm$0.24(100%)에 비하여 I3C 저농도 투여 실험군(Group 1; 0.85$\pm$0.23; 61%, P<0.01), 그리고 I3C 고농도 투여 실험군(Group 2 ; 1.32$\pm$0.29 ; 94%)의 순으로 감소하였다. 선종의 크기별 종양의 발생개수의

• Resources Recycling
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• v.33 no.3
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• pp.48-56
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• 2024

In this study, physical property evaluation and physical separation of the target product were performed to investigate the possibility of using sewage sludge gasification solid residue (GSRs) as a circulating resource. Firstly, the GSRs used in this study was supplied by Sudokwon Landfill Management Corporation, and generally the GSRs was in the form of porous pellets with a particle size of several millimetres. In addition, the partially black areas were confirmed to be unburned and ungasified carbon, and the average carbon content was 5%. In addition, the content of silica, alumina and phosphorus oxide was more than 70% of the total content. It was confirmed that the metallic components of the wet grinding product were separated into individual elements. As a physical separation of metallic and non-metallic components was required, it was finally found that flotation screening was suitable. Accordingly, cationic and anionic surfactants were selected to separate metallic components in which a relatively large amount of non-metallic components were concentrated, and the separation characteristics were confirmed. As a result, it is expected that the concentration of non-metallic components such as silica, alumina and phosphorus will be easier than the separation of metallic components. Therefore, since it is possible to physically treat the gasified sludge residue, it is judged to have potential as a circular resource according to the proposed recycling method for the separated product.