• Title/Summary/Keyword: Fluxes of air pollutants

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Aircraft Measurement of SO$_2$, NO$_{x}$ over Yellow Sea Area (항공기를 이용한 서해안에서의 SO$_2$ 및 NO$_{x}$의 측정)

  • 김병곤;차준석;한진석;박일수;김정수;나진균;최덕일;안준영;강창국
    • Journal of Korean Society for Atmospheric Environment
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    • v.13 no.5
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    • pp.361-369
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    • 1997
  • In order to investigate the abundance and transboundary fluxes of air pollutants over the Yellow Sea, airborne measurements were made aboard the SF-600 aircraft (Pan-Asia Engineering) in March, 1996. The data presented in this paper are preliminary results and airborne experiment will be carried out until 1999. The vertical profile of relevant meteorological parameters such as temperature, water vapor, wind direction and wind speed were also observed at Taean. Mixing layer height was about 1000~1100m during the flights. The SO$_2$ and NO$_{x}$ concentrations were 3~6 ppb and 5~7 ppb below 1000 m, within 1 ppb and 3~5 ppb at 1000~2000m, respectively. Backward trajectory analyses were also carried out. A mathematical method by Lelieveld et al.(1989) was used to estimate the flux of air pollutants through the planetary boundary layer of Yellow Sea area. Transboundary fluxes were calculated using the measurement results with respect to the pollutants concentration, depth of the planetary boundary layer, wind speed and wind direction. The estimated transboundary flux of SO$_2$through the western boundary of Korea was about 39~42 tons/hour.r.

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Estimation of Fluxes of Air Pollutants in Seoul Conurbation Using ISCLT3 (ISCLT3를 이용한 수도권 도시간 대기오염물질 유출입량 추정)

  • 홍민선;김순태;김영제;양소희;이동섭;장영기
    • Journal of Korean Society for Atmospheric Environment
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    • v.17 no.2
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    • pp.147-155
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    • 2001
  • ISCLT3 model was applied in Seoul metropolitan area to investigate the source-receptor relationships among 17 cities in the Kyonggi Province. For the purpose of the model simulation, emission rates of NO$_2$, SOx, and PM(sub)10 were prepared for grid scale with 1$\times$1 km, and receptors were located on every 2$\times$2 km grid. Meterological data for the last 10 years(88~97) were used as input data. According to our study, NO$_2$ concentration of the cities ranged from 10 to 45 ppb with the highest value appearing from Puchon city. The concentrations of SOx and PM(sub)10 concentrations fell in the range of 5~20 ppb and 20~70$\mu\textrm{g}$/㎥, respectively. It was also found out that air quality in one city can be affected greatly by the air pollutants originating from other cities.

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Estimation of Gaseous Air Pollutants Deposition Fluxes at Yong-dam Reservoir (용담호 주변지역 가스상 대기오염물질 침적량 추정)

  • 김학민;정구회;김재분;정재호;이범진;김선태
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2003.11a
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    • pp.364-365
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    • 2003
  • 최근 대기기인 오염물질이 환경계에 미치는 영향에 대한 관심이 높아짐에 따라 호소수질에 직ㆍ간접적으로 영향을 주는 대기오염물질에 대한 관심이 커지고 있다. 특히 호소에 유입되는 영양염류 중 질소화합물에 대한 기여수준을 평가한 최근자료에 의하면 대규모 호소 중 89%에 상당하는 호소수내의 질소성분이 자연적으로 존재하는 양을 초과하고 있는 것으로 판단하고 있으며, 초과된 질소성분 중 최고 38%가 대기오염물질과 관련된 질소성분인 것으로 보고하고 있다. (중략)

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Prediction of spatial distribution of air pollutants within tunnel (터널 내 대기오염물질의 공간분포 예측)

  • Park, Il-Gun;Hong, Min-Sun;Kim, Beom-Seok;Kang, Ho-Geun
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.14 no.6
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    • pp.607-616
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    • 2012
  • The need for management of tunnel air quality is imminent considering the rapid increase of number and span of tunnels in Korea. To investigate spatial distribution of $CO_2$ within tunnels, $CO_2$ were measured and model simulations were performed in Namsan 1 tunnel. Results show that $CO_2$ concentrations were 250 ppm to 400 ppm higher in the exit than tunnel entrance. Also, $CO_2$ concentrations were 200 ppm to 300 ppm lower inside no ventilating vehicle than in the tunnel. Both experimental and model simulation results show that spatial distribution and concentration gradient of air pollutant inside tunnel are highly dependent on traffic density.

Estimation of Atmospheric Deposition Velocities and Fluxes from Weather and Ambient Pollutant Concentration Conditions : Part I. Application of multi-layer dry deposition model to measurements at north central Florida site

  • Park, Jong-Kil;Eric R. Allen
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.4 no.1
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    • pp.31-42
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    • 2000
  • The dry deposition velocities and fluxes of air pollutants such as SO2(g), O3(g), HNO3(g), sub-micron particulates, NO3(s), and SO42-(s) were estimated according to local meteorological elements in the atmospheric boundary layer. The model used for these calculations was the multiple layer resistance model developed by Hicks et al.1). The meteorological data were recorded on an hourly basis from July, 1990 to June, 1991 at the Austin Cary forest site, near Gainesville FL. Weekly integrated samples of ambient dry deposition species were collected at the site using triple-fiter packs. For the study period, the annual average dry deposition velocities at this site were estimated as 0.87$\pm$0.07 cm/s for SO2(g), 0.65$\pm$0.11 cm/s for O3(g), 1.20$\pm$0.14cm/s for HNO3(g), 0.0045$\pm$0.0006 cm/s for sub-micron particulates, and 0.089$\pm$0.014 cm/s for NO3-(s) and SO42-(s). The trends observed in the daily mean deposition velocities were largely seasonal, indicated by larger deposition velocities for the summer season and smaller deposition velocities for the winter season. The monthly and weekly averaged values for the deposition velocities did not show large differences over the year yet did show a tendency of increased deposition velocities in the summer and decreased values in the winter. The annual mean concentrations of the air pollutants obtained by the triple filter pack every 7 days were 3.63$\pm$1.92 $\mu\textrm{g}$/m3 for SO42-, 2.00$\pm$1.22 $\mu\textrm{g}$/m-3 for SO2, 1.30$\pm$0.59 $\mu\textrm{g}$/m-3 for HNO3, and 0.704$\pm$0.419 $\mu\textrm{g}$/m3 for NO3-, respectively. The air pollutant with the largest deposition flux was SO2 followed by HNO3, SO42-(S), and NO3-(S) in order of their magnitude. The sulfur dioxide and NO3- deposition fluxes were higher in the winter than in the summer, and the nitric acid and sulfate deposition fluxes were high during the spring and summer.

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Studies on Estimating Dry Deposition Velocities for Atmospheric Aerosol and Metal Elements in Korea (한국에서 분진 및 금속원소의 건식 침착속도 추정에 관한 연구)

  • 김성천;김동술
    • Journal of Korean Society for Atmospheric Environment
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    • v.12 no.1
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    • pp.101-112
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    • 1996
  • Dry and wet deposition is an impertant removal mechanism of the amobient aerosol in the atmospheric environment. Since the deposition flut provides adverse impacts on various encironmental media including aquatic and ecological system as well as human health, it is essential to quantitatively estimate the removal fluxes of many air pollutants. Thus, the purposes of this experimental study are to investigate seasonal deposition flux variations of the total dustfall and various inorganic elements in the local ambient air and then to finally estimate their dry deposition velocities. To perform the study, the total of 90 dustfall samples were collected from January, 1994 thru February, 1995 in 5 different cities of Korea including Seoul, Suwon, Daejon, Kwangju, and Kangrung. Each sample was analyzed by an AAS and an ICP to determine the quantities of the 11 inorganic elements, such as Zn, Cd, Cr, K, Na, Pb, Ca, Fe, Mn, Mi, and Cu. As results, deposition fluxes, soluble/insoluble fractions, and deposition velocities for each element were extensively investigated. The resulting dry deposition velocities of some elements in Suwon were estimated by ranges of 0.57 .sim. 0.87 cm/sec for Zn, 0.35 .sim. 0.45 cm/sec for Pb, 1.25 .sim. 3.52 cm/sec for Ca, 0.21 .sim. 0.48 cm/sec for Fe, 0.95 .sim. 9.31 cm/sec for Mn, and 2.08 cm/sec for Cu.

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Deposition Process of Sulfate and Elemental Carbon in Japanese and Thai Forests

  • Sase, Hiroyuki;Matsuda, Kazuhide;Visaratana, Thiti;Garivait, Hathairatana;Yamashita, Naoyuki;Kietvuttinon, Bopit;Hongthong, Bundit;Luangjame, Jesada;Khummongkol, Pojanie;Shindo, Junko;Endo, Tomomi;Sato, Keiichi;Uchiyama, Shigeki;Miyazawa, Masamitsu;Nakata, Makoto;Lenggoro, I. Wuled
    • Asian Journal of Atmospheric Environment
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    • v.6 no.4
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    • pp.246-258
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    • 2012
  • Particulate matter deposited on leaf surfaces may cause erosion/abrasion of epicuticular wax and the malfunction of stomata. However, the deposition processes of particulate matter, such as elemental carbon (EC), has not been studied sufficiently in Asian forest ecosystems. Deposition processes for particulate ${SO_4}^{2-}$ and EC were studied in a Japanese cedar forest in Kajikawa, Niigata Prefecture, Japan, and in a dry evergreen forest and a dry deciduous forest in Sakaerat, Nakhon Ratchasima province, Thailand. The ${SO_4}^{2-}$ fluxes attributed to rainfall outside the forest canopy (RF), throughfall (TF), and stemflow (SF) showed distinct seasonalities at both sites, increasing from November to February at the Kajikawa site and in March/April at the Sakaerat site. Seasonal west/northwest winds in winter may transport sulfur compounds across the Sea of Japan to the Kajikawa site. At the Sakaerat site, pollutants suspended in the air or dry deposits from the dry season might have been washed away by the first precipitations of the wet season. The EC fluxes from RF and TF showed similar variations by season at the Kajikawa site, while the flux from TF was frequently lower than that from RF at the Sakaerat site. Particulate matter strongly adsorbed onto leaf surfaces is not washed away by rainfall and contributes to the EC flux. At the Kajikawa site, Japanese cedar leaf surfaces accumulated the highest levels of particulate matter and could not be neglected when calculating the total flux. When such leaf-surface particles were considered, the contribution of dry deposition to the total EC flux was estimated to be 67%, 77%, and 82% at the Kajikawa site, and at the evergreen and deciduous forests of the Sakaerat site, respectively. Leaf-surface particles must be included when evaluating the dry and total fluxes of particulate matter, in particular for water-insoluble constituents such as EC.

Measurement of Dry Deposition Flux of Air Pollutants to the Waterbody (수체로의 대기오염물질 건식침적량 측정)

  • 김영성;진현철;김용표
    • Journal of Korean Society for Atmospheric Environment
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    • v.20 no.3
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    • pp.421-426
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    • 2004
  • Dry deposition fluxes of inorganic acidic species to the waterbody were measured by the dry deposition sampler (DDS). DDS was composed of three pans filled with pure water. An average concentration increase during the sampling time, after removing an abnormal value if existed, was considered as the input by deposition. Important operation parameters such as the amount of water used and sampling time were determined through a series of laboratory experiments. The deposition flux measured by DDS was compared with that by the water surface sampler developed by Yi et ai. (1997a,b).

Assessment of DMS photochemistry at Jeju Island During the Asian Oust-Storm Period of Spring 2001 : Comparison of Model Simulations with Field Observations

  • Shon, Zang-Ho;Hilton Swan;Keith N. Bower;Kim, Ki-Hyun;Lee, Gangwoong;Kim, Jiyoung
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2002.11a
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    • pp.343-343
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    • 2002
  • This study examines the influence of long-range transport of dust particles and air pollutants on both local/regional DMS oxidation chemistry and the distribution of sulfur compounds at Jeju Island (33.17$^{\circ}$ N. 126.10$^{\circ}$ E) during the Asian dust-storm(ADS) period in April 2001. The atmospheric concentrations of these sulfur species were measured at a ground station on Jeju Island. Korea as Part of the ACE-Asia intensive operation. Three ADS events were observed during the periods of 10-12, 13-14. and 25-26 April. respectively. The concentrations of DMS and CS$_2$ were higher during the ADS period than during the non-Asian-dust-storm (NADS) period. Conversely. a difference in SO$_2$ levels during the ADS period was not distinguishable from those during the NADS period. The diurnal variation pattern of DMS observed was largely different from that in the remote marine boundary layer. DMS loss by NO$_3$ in the atmospheric boundary layer was dominant due to significantly high NOx levels influenced by the long-range transport of pollutants from East Asia to Jeju Island The DMS maximum during the ADS period was observed in the late afternoon. The oceanic fluxes of DMS during the ADS and NADS periods were estimated to be 5.7$\pm$2.3 and 2.9 (+2.8/-1.5) mole m$^{-2}$ day$^{-1}$ . respectively. The contribution of oxidized DMS to SO$_2$ levels at Jeju Island during the study period was found to be insignificant.

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Environmental Mobilization Characteristics of Total Gaseous Mercury in the Western Coast of Korea During the Yellow Sand Period, 2001 (2001년 봄철 황사기간 중 서해안지역에서 관측한 대기 중 수은의 환경유동특성 연구)

  • Kim, Min-Young;Shin, Jae-Young;Cho, Suk-Choo;Kim, Joon;Lee, Gang-Woong;Kim, Ki-Hyun
    • Journal of the Korean earth science society
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    • v.22 no.6
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    • pp.480-490
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    • 2001
  • The soil-air exchange processes of Hg were investigated from the Hari area of Kang Hwa Island during the late March 2001. In the course of our study, we determined the concentration gradients of Hg and combined these gradient data with micrometeorological components to derive its fluxes. Results of our study indicate that the concentration levels of Hg in the study area are notably lower than those typically found in urbanized areas of Korea. However, the computed fluxes were seen to be significantly larger for relatively remote areas, reaching over 200 ng/m$^2$/hr. Comparison of environmental conditions shows that the concentrations of most pollutant species including NO$_X$ and PM were significantly higher during emission, while meteorological conditions were characterized by high temperature and low humidity. Results of correlation analysis also indicate that such pollutants as hydrocarbons, nitrogen oxides, and PM generally exhibit strong positive correlations with Hg-related parameters during emission events, while such relationships were reversed during dry deposition events. The results of our present study suggest the possibility that the concentrations and fluxes of total gaseous Hg observed during deposition events can be influenced by the processes that are also important for the fine, rather than coarse, size fraction of particles.

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