• Title/Summary/Keyword: Flux composition

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Preparation and Characterization of Chemically Stable PVDF-HFP Asymmetric Microfiltration (MF) Membranes

  • Lee, Yeon-Ee;JeGal, Jong-Geon
    • Membrane Journal
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    • v.22 no.2
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    • pp.104-112
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    • 2012
  • Chemically stable Polyvinylidene fluoride-hexa-fluoropropane (PVDF-HFP) copolymer asymmetric membranes were prepared by the conventional phase inversion process, using Dimethyacetamide (DMAc) as a solvent and water as a non-solvent. To control the pore size and porosity of the PVDF-HFP membranes, tetra-ethoxysilane (TEOS) was used as a pore-forming agent. The prepared membranes were characterized, using several analytical methods such as Fourier Transform Infrared spectroscopy (FTIR), Thermo-gravimetric analyzer (TGA), Field Emission Scanning Electronic Microscopy (FESEM). TEOS turned out to increase porosity and make homogeneous pores on the membranes. Depending on the composition of the dope solutions, the pore size was ranged from 0.1 to 1.0 ${\mu}m$. The flux of the PVDF-HFP membranes prepared by using TEOS as a pore forming agent was increased substantially without much decrease in the rejection. When 15 wt% PVDF-HFP solution was blended with 13 wt% TEOS solution at composition ratio of 70/30 in wt%, the water flux at 2 bars was about 2 $m^3/m^2day$.

Effects of Composition on the Hydration of Blastfurnace Granulated Slag (슬래그의 조성변화가 수화반응에 미치는 영향)

  • 오희갑;최상흘
    • Journal of the Korean Ceramic Society
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    • v.16 no.4
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    • pp.237-242
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    • 1979
  • In order to improve hydration reactivity of blast furnace slag, it's composition was changed by adding of CaO. The slags were quenched in water at 1,400℃. Hydration reactivityof modified slags was studied by x-ray diffractometer, conduction calorimeter and so on. Experimental results were summarized as follows. 1. Glass content and hydration reactivity of slag depend significantly on quenching temperature of the slag melt. To enhance the reactivity, slag melts which belongs to Frenkel-type liquid, must be quenched above 1,300℃. 2. Vitrification of slag melts was confirmed as CaO/SiO2 ratio increased up to 1.57 with flux, 1.51 without flux, also their hydration reactivity was improved.

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Comparison of flux and natural sapphire after heat-treatment (열처리 후 플럭스 사파이어와 천연 사파이어의 비교 분석)

  • Kim, Ki-In;Ahn, Yong-Kil;Seo, Jin-Gyo;Park, Jong-Wan
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.19 no.3
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    • pp.152-158
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    • 2009
  • Various fabrication methods have been used to synthesize sapphire which has qualities of jewelry well beyond the industrial class. Among them, the flux sapphire of Chatham Company which has as high value as jewelry was selected in order to compare natural and synthetic sapphire. First, the WD-XRF (Wavelength dispersive x-ray fluorescence spectrometer) was used to analyze the chemical composition of natural and synthetic sapphire. Although natural sapphire had very diverse chemical compositions, flux sapphire had small quantities of Mo, Pt and Pb elements in addition to the similar chemical ingredients to natural one. Pt is decisive proof of flux sapphire. Next, by investigating spectroscopic characteristics using UV-VIS Spectrophotometer after heat treatment at high temperatures of $1300^{\circ}C$ and $1500^{\circ}C$, the variation of 690 nm absorbance related to $Cr^{3+}$ was detected in the natural sapphire while those of the 690 nm absorbance (related to $Cr^{3+}$) as well as absorbance of 376 nm and 388 nm ($Fe^{3+}$) were seen in the flux sapphire. It was found that the difference in the absorbance variation of flux sapphire is greater than that of natural sapphire after heat treatment. The chemical composition and spectrum analysis were utilized to compare the natural sapphire and the flux synthetic sapphire.

Preparation of high-performance nanofiltration membrane with antioxidant properties

  • Yu, Feiyue;Zhang, Qinglei;Pei, Zhiqiang;Li, Xi;Yang, Xuexuan;Lu, Yanbin
    • Membrane and Water Treatment
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    • v.13 no.4
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    • pp.191-199
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    • 2022
  • In industrial production, the development of traditional polyamide nanofiltration (NF) membrane was limited due to its poor oxidation resistance, complex preparation process and high cost. In this study, a composite NF membrane with high flux, high separation performance, high oxidation resistance and simple process preparation was prepared by the method of dilute solution dip coating. And the sulfonated polysulfone was used for dip coating. The results indicated that the concentration of glycerin, the pore size of the based membrane, the composition of the coating solution, and the post-treatment process had important effects on the structure and performance of the composite NF membrane. The composite NF membrane prepared without glycerol protecting based membrane had a low flux, when the concentration of glycerin increased from 5% to 15%, the pure water flux of the composite NF membrane increased from 46.4 LMH to 108.2 LMH, and the salt rejection rate did not change much. By optimizing the coating system, the rejection rate of Na2SO4 and PEG1000 was higher than 90%, the pure water flux was higher than 40 LMH (60psi), and it can withstand 20,000 ppm.h NaClO solution cleaning. When the post treatment processes was adjusted, the salt rejection rate of NaCl solution (250 ppm) reached 45.5%, and the flux reached 62.2 LMH.

The Effect of the Ground Composition on Thermal Environment in Multi -residential Building Block (공동주택 단지 내 지반 특성 및 지반 구성에 따른 열적 특성에 관한 연구)

  • Hwang, Hyo-Keun;Song, Doo-Sam
    • Journal of the Korean Solar Energy Society
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    • v.29 no.5
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    • pp.88-97
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    • 2009
  • In these days, it attracts our attention to create a green outdoor environment around the building block in urban area. Green space and permeable ground covering are increased by laws and regulations. According to these trends, variety researches for improving outdoor environment are accomplished at this moment. However, the problems for outdoor environment such as heat island effect and air contaminant in urban area are still reported. The purpose of this study is to examine the variables to affect the formation of outdoor thermal environment by quantitative analysis. As a initial study, in this paper, the effect of ground composition on changes of surface temperature and heat flux in multi-residential building were analyzed by field measurement and numerical simulation. Through field measurement, the surface temperature and heat flux of artificial ground in multi-residential building in Suwon city were measured. The result showed that the surface temperature was decreased by about $20^{\circ}C$ with afforestation of artificial ground compared with those of concrete covering. Moreover, the inner temperature of artificial ground was changed as same behaviors of outdoor temperature changes to depths of 20cm. In simulation, the effect of soil types and depth of artificial ground on the changes of the surface temperature and heat flux were analyzed. As results, the natural soil ground was more effective against lowering the surface temperature than any other cases in the analyzed cases.

Removal of Chlorinated Organic Compounds Using Crosslinked PDMS Pervaporation Membrane (가교된 PDMS 투과증발 막을 이용한 유기 염소계 화합물의 제거)

  • Kim, Yong Woon;Hong, Yeon Ki;Hong, Won Hi
    • Clean Technology
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    • v.7 no.3
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    • pp.195-202
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    • 2001
  • In this study the trace of chlorinated organic compound in aqueous solution was separated by pervaporation process using crosslinked PDMS (polydimethylsiloxane) membrane. The flux of trichloroethylene(TCE) increased linearly with feed composition but the flux of water was slightly increased. The partial flux of TCE was greater than that of tetrachloroethylene(PCE). The partial flux of TCE was not changed with operating temperature, but increased rapidly with feed flow rates. High crosslinking density causes the reduction of solubility and diffusivity for target component. The reduction of flux and selectivity for TCE is due to the chain immobilization and reduction of diffusivity with crosslinking density.

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Crystal Growth and Solid Solution of Hexagonal Ferrites (육방정 페라이트의 고용성 및 단결정 육성 연구)

  • 강진기;박병규;정수진
    • Journal of the Korean Ceramic Society
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    • v.23 no.3
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    • pp.78-86
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    • 1986
  • single crystals of various hexagonal ferrites were grown by a flux technique. For the growing experiment platinum crucibles of size 40 cc and a horizontal siliconit tube furnace were used. Charges consisted of the flux of BaO(SrO)/$B_2O_3$ and the composition of crystals in the system of BaO $(SrO)-Fe_2O_3-ZnO$. The BaO(SrO)/$B_2O_3$ molar ratio of the flux were varied from 1 to 3. Crystals up to 12.5mm in diameter were grown by slow cooling of melts from a maximum temperature of 1, 30$0^{\circ}C$or 1, 350$0^{\circ}C$ to 95$0^{\circ}C$ or 1, 00$0^{\circ}C$ The grown crystals exhibited a tabular hexagonal habits with very well developed ba-sal planes and narrow pyramidal faces of {1011} {1012} and {0001}. For the identification of the grown crystals X-ray diffraction studies were carried out. The effects of va-riations in flux ratio flux percentage and cooling rate on the quality of the grown crystals were studied. Cry-stal habits hillocks etch steps and growth spirals were observed by optical microscope. Magnetic properties of single crystals were measured.

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Reuse of Weaving Wastewater by Membrane Bioreactor Equipped with a Hollow-fiber MF Membrane (중공사 정밀여과 MBR공정을 이용한 제직폐수의 재이용)

  • Jung, Yong-Jun;Bae, Jong-Hong;Min, Kyung-Sok
    • Journal of Korean Society on Water Environment
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    • v.20 no.4
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    • pp.365-369
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    • 2004
  • Submerged membrane bio-reactor equipped with a hollow fiber microfiltration was applied to reuse weaving wastewater of water jet loom, where two parameters such as the concentration of MLSS and the flux were controlled. While the flux at the concentration of MLSS around 900mg/L was constantly kept over 0.4m/d and 0.8m/d in a short time, the stable flux at around 300mg/L of MLSS was shown at the 8 days later. Regardless of MLSS and flux, BOD, CODcr and Turbidity of the permeate were 1~2mg/L, 7~10mg/L and below 1 NTU, which were 85~90%, 87~90% and 98% of removal efficiency, respectively. The stable operation without fouling was achieved because the contents of ECP were smaller than those of common MBR processes and the composition(saccharide/protein) was kept constantly. In this study, 0.5~1.0m/d of flux and 400~900mg/L of MLSS were considered as the most recommendable operating condition for the reuse of weaving wastewater.

Electrical Properties of a High Tc Superconductor for Renewed Electric Power Energy

  • Lee Sang-Heon
    • Journal of Electrical Engineering and Technology
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    • v.1 no.3
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    • pp.371-375
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    • 2006
  • Effects of $Ag_2O$ doping on the electromagnetic properties in the BiSrCaCuO superconductor. The electromagnetic properties of doped and undoped $Ag_2O$ in the BiSrCaCuO superconductor were evaluated to investigate the contribution of the pinning centers. It was confirmed experimentally that a larger amount of magnetic flux was trapped in the $Ag_2O$ doped sample than in the undoped one, indicating that the pinning centers of magnetic flux are related closely to the occurrence of the magnetic effect. We have fabricated superconductor ceramics by the chemical process. A high Tc superconductor with a nominal composition of $Bi_2Sr_2Ca_2Cu_3O_y$ was prepared by the organic metal salts method. Experimental results suggest that the intermediate phase formed before the formation of the superconductor phase may be the most important factor. The relation between electromagnetic properties of Bi HTS and the external applied magnetic field was studied. The electrical resistance of the superconductor was increased by the application of the external magnetic field. But the increase in the electrical resistance continues even after the removal of the magnetic field. The reason is as follows; the magnetic flux due to the external magnetic field penetrates through the superconductor and the penetrated magnetic flux is trapped after the removal of the magnetic flux. During the sintering, doped $Ag_2O$ was converted to Ag particles that were finely dispersed in superconductor samples. It is considered that the area where normal conduction takes place increases by adding $Ag_2O$ and the magnetic flux penetrating through the sample increases. The results suggested that $Ag_2O$ acts to amplify pinning centers of magnetic flux, contributing to the occurrence of the electromagnetic properties.

Characteristics of Heat Flux in a Compartment Fire - Reduced Scale Test (구획공간 화재의 열유속 특성 - 축소 실험)

  • Kim, Sung-Chan;Ko, Gwon-Hyun
    • Fire Science and Engineering
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    • v.25 no.5
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    • pp.128-133
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    • 2011
  • The present study performs a series of 40 % reduced scale of ISO-9705 fire test to investigate the characteristics of heat flux on the floor level in terms of fire characteristics and location in the compartment. The heat flux was measured with Schmidt-Boelter type heat flux gauge at two locations on the floor level of inside and doorway side of the compartment. Different types of fuel - methane, heptane, toluene, ethanol, polystyrene - were burned in this test series. The measured heat flux inside of the compartment was relatively higher than that of front side as the heat release rate of fire and upper layer temperature increased. The difference of measured heat flux at inside and doorway side increased for high sooty fire. The present study shows that the heat flux distribution at lower layer greatly depend on the thermal radiation from fire and upper layer, not only the upper layer temperature but also various fire characteristics such as composition of combustion gases, soot concentration, ventilation condition and so on.