• 한국세라믹학회지
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• 제23권3호
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• pp.87-93
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• 1986

Yttria-bismuth-stabilized zirconia was investigated with respect to the amount of $Bi_2O_3$ addition in the ran-ge of 0.5~5mol% to the base composition of $(ZrO_2)_{0.92}(Y_2O_3)_{0.08}.Bismuth was introduced into the ma-terial with $Bi_2O_3-SiO_2$ glasses in order to reduce the evaporation of components. The sinterbility evaporation of components phase formation and microstructure were evaluated depending on the amount of $Bi_2O_3-SiO_2$ glass addition. Two probe A. C conductivity measurement was subjected to all the specimens and the result was discussed on the possible substitution of $Bi^{3+}$ for $Zr^{4+}$ and interistial $Si^{4+}$ in the fluorite structure of zirconia crystal there-upon the possible change in the capability of oxygen transference within the material. It was found that the addition of $Bi_2O_3$ could improve the sinterbility of material very much while not so much.oxygen sensing material suitable for relative low temperature firing.

• 한국지구과학회지
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• 제23권1호
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• pp.52-58
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• 2002

A colorless and transparent zirconium oxide ($Zr_{0.73}Y_{0.27}O_{1.87}$) crystal has been synthesized by the Bridgman-Stockbager method. The gem-quality material is produced by adding 20${\sim}$25 wt.% $Y_2O_3$ (stabilizer) and 0.04 wt.% $Nd_2O_3$ (decolorising agent) to the $ZrO_2$ powder. It shows a vitreous luster with a slight oily appearance. Under a polarizing microscope, it shows isotropic nature with no appreciable anisotropism. Mohs hardness value and specific gravity is measured to be 8${\sim}$$8{\frac{1}{2}}$ and 5.85, respectively. Under ultraviolet light it shows a faint white glow. The crystal structure of yttria-stabilized zirconia with 0.27 at.% Y has been re-investigated, using single crystal X-ray diffraction, and confirmed to be a cubic symmetry, space group $Fm{\overline{3}}m$ ($O^5_h$) with a=5.1552(5) ${{\AA}}$, V=136.99(5) ${{\AA}}^3$, Z=4. The stabilizer atoms randomly occupy the zirconium sites and there are displacements of oxygen atoms with amplitudes of ${\Delta}/a{\sim}$0.033 and 0.11 along <110> and <111> from the ideal positions of the fluorite structure, respectively.

• 한국지하수토양환경학회지:지하수토양환경
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• 제20권3호
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• pp.65-73
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• 2015

The hydrofluoric acid (HF) leakage accident occurred on September 2012 in Gumi, Korea affected the surrounding soils and plants. In this study, we investigated fluoride migration in Gumi area through geochemical properties of soil-liquid phase (pore water F and water-soluble F). The concentrations of porewater F and water-soluble F were obtained from N.D (Not detected) to 9.79 mg/L and from 0.001 to 21.4 mg/L, respectively. F in pore water seemed to be affected by artificial and natural origin, and PHREEQC results implied that fluorite is F control factor. F concentrations of soil and soil-liquid phase did not exceed concern level of regulatory criteria and showed similar trends compared by previous studies. Therefore, F contents remained in the soil and soil-liquid phase were considered to be not affected by HF leakage accident.

• 한국세라믹학회지
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• 제37권10호
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• pp.1008-1013
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• 2000

SrTi $O_3$(001) 단결정 기판 위에 졸-겔 스핀코팅으로 $SrBi_2(Ta,Nb)_2O_9$ 박막을 도포하고 그 결정화 과정을 고온 X-선 회절분석 (HTXRD)으로 추적하면서 Pt(111)/Ti/ $SiO_2$/Si 위에 성장한 박막과 비교하였다. SrTi $O_3$(001) 단결정 기판 위에 도포된 $SrBi_2Nb_2O_{9}$ 박막은 fluorite-like phase와 같은 transient phase를 거치지 않고 곧바로 순수한 $SrBi_2Nb_2O_9$ 상으로 결정화가 시작되었으며 결정화가 시작되는 온도인 ${\sim}540^{\circ}C$부터 c축 배향성장하였다. 또한 $SrB i_2(Ta,Nb)_2O_9$ 박막은 Ta/Nb 비에 관계없이 $SrTiO_3$(001) 위에서 모두 $(00{\ell})$로 배향되었으며, 코팅 횟수가 늘어나 필름의 두께가 증가함에 따라 c축 배향성은 미세한 감소를 보였다. $SrBi_2Nb_2O_9/SrTiO_3$단면을 TEM으로 관찰한 결과 $SrBi_2Nb_2O_9$은 대체로 불규칙한 크기의 다결정체로 되어 있었으나 계면 부근에서는 [001]$_{SBN}$//[001]$_{SrTi}$ $O_3$/, [100]$_{SBN}$//[100]$_{SrTi}$ $O_3$/라는 결정학적 관계를 가지며 에피탁샬 성장했음을 알 수 있었다.있었다.

• 자원환경지질
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• 제27권6호
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• pp.537-548
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• 1994

The Weolyu gold-silver deposits at Hwanggan, Chungcheongbukdo, is of a late Cretaceous $(74.24{\pm}1.63Ma)$ epithermal vein-type, and is hosted in the quartz porphyry of late Cretaceous age. Based on mineral paragenetic sequence interpreted from vein structure and mineral assemblages, three stages mineralization were distinguished. A variety of ore minerals occurs including pyrite, sphalerite, chalcopyrite, galena with small amount of electrum, native silver, argentite, pearceite, sb-pearceite, argyrotite. The gangue minerals are quartz, rutile, calcite, apatite, fluorite and rhodochrocite. Wall-rock alteration such as pyritization, chloritization, sericitization, silicification is observed near the quartz veins. Au-Ag minerals were crystallized at middle and late stage of the two mineralization sequences. Results from the analysis of fluid inclusion and thermodynamic calculation indicate that Au-Ag mineral deposits were formed primarily by cooling and dilution of hydrothermal fluids($165{\sim}313^{\circ}C$, 0.4~2.4wt.% equivalent NaCl) with some degree mixing of meteoric water.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2007년도 하계학술대회 논문집 Vol.8
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• pp.42-42
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• 2007

In the future, electronic components will be integrated on flexible polymer substrates and then miniaturized by thin films using suitable thin film technologies. In this article, the concept of a room temperature CVD is demonstrated using $Bi_3NbO_7$ (BNO) films with a cubic fluorite structure and their structural and electrical properties were investigated in films deposited without substrate heating. Effects of substrate temperature on electrical properties of BNO films were also studied. Films deposited without substrate heating (real temperature of $50^{\circ}C$) show partially crystallized BNO single phases with grain size of approximately 6.5 nm. Their dielectric and leakage properties are comparable to those of films deposited by pulsed laser deposition at room temperature. The concept of room temperature CVD will become a new paradigm in the deposition of dielectric thin films for flexible electron device applications.

• 한국재료학회지
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• 제25권3호
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• pp.144-148
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• 2015

Cubic mesocrystal $CeO_2$ was synthesized via a hydrothermal method with glutamic acid ($C_5H_9NO_4$) as a template. The XRD pattern of a calcined sample shows the face-centered cubic fluorite structure of ceria. Transmission electron microscopy (TEM) and the selected-area electron diffraction (SAED) pattern revealed that the submicron cubic mesocrystals were composed of many small crystals attached to each other with the same orientation. The UV-visible adsorption spectrum exhibited the red-shift phenomenon of mesocrystal $CeO_2$ compared to commercial $CeO_2$ particles; thus, the prepared materials show tremendous potential to degrade organic dyes under visible light illumination. With a concentration of a rhodamine B solution of 20 mg/L and a catalyst amount of 0.1 g/L, the reaction showed higher photocatalytic performance following irradiation with a xenon lamp (${\geq}380nm$). The decoloring rate can exceed 100% after 300 min.

• 자원환경지질
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• 제19권spc호
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• pp.3-17
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• 1986

Hundred mineral deposits including W-Mo, Pb-Zn-Cu, fluorite and talc occur in the Cambre-Ordovician limestone contacting with the Cretaceous Muamsa and Wolak granitoids in the Susanri-Hwanggangri mineralized zone. In most mineral deposits characterized by metasomatic replacement, skarn and hydrothermal vein types, two distinct tendencies were found as W-Mo mineralization in or/and near granitoid batholith and ($Pb-Zn-Cu(CaF_2)$) mineralization which is gradually increased toward the batholith. W-Mo veins of extensive vein system occupy northly striking fractures whilst $Pb-Zn-Cu-CaF_2$ veins strike northeast or northwest. In this work, three representative lead-zinc-copper deposits choosing the Dangdu, Useog and Eoksu mines were dealt with in detail. Skarn ore bodies in the Dangdu mine were grouped into early diopside rich clinopyoxene-garnet, barren skarn and ore bearing late hedenbergite rich clinopyroxene-garnet skarn. Temperature and $X_{CO_2}$, obtained from hedenbergite-andradite-calcite-quartz mineral equilibria in the Dangdu ore deposits were $580{\sim}650^{\circ}C$ and 0.15~0.3, respectively. Fluid inclusien evidence in the Useog mine indicates that main stage mineralization temperature ranges from 224 to $389^{\circ}C$ with a salinity of 2~17 equivalent wt. percent NaCl. Sphalerites from the Dangdu and Useog mines have 16~17.7 mole percent in FeS which is relatively consistent to those of some other lend-zinc ore deposits in South Korea. Filling tcmjCerature of fluid inclusion frem the Eoksu mine shows deposition of ore within the temperature ranges from 237 to $347^{\circ}C$ and within the salinity ranges from 2.6 to 10.77 equivalent wt. percent NaCl.

• 자원환경지질
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• 제28권6호
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• pp.599-612
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• 1995

Some REE ore deposits are located in the middle part the of Korean peninsula. Geotectonically, the REE ore deposits situated on the Kyemyeongsan Formation of northern margin of the Okcheon geosynclinal belt and in the transitional zone between Kyeonggi massif and the Okcheon belt, with a deep-seated fracture separating the two tectonic units. The Kyemyeongsan Formation are different in lithology and metamorphic grade from the Gyeonggi massif and the Okcheon super group. The sequence of Kyemyeongsan Formation is dominantly composed of acidic metavolcanic and volcaniclastic rocks associated with alkaline igneous rocks which are related to volcano-plutonism. The REE ore deposits contain mainly Ce-La, Ta-Nb, Y, Y-Nd and Nd-Th group minerals. More than 15 RE and REE minerals have been found in the deposits, such as allanite, fergusonite, thorite bestnaesite, euxenite, polyclase, monazite, columbite, (Nb)-rutile, okanoganite, sphene, zircon, illmenite and some other unknown minerals. According to the characteristics of the mineral association, the REE ore deposits may be divided into 4 ore types; Zircon-REE, allanite-REE, feldspar-REE and fluorite-REE type. The Sm-Nd isochron age of the REE ore is 330 Ma, and the Sm-Nd model age is 1.11 Ga with ${\varepsilon}_{Nd(t)}$ being - 2.9. This data suggest that the REE ore deposit was formed in the early Carboniferous, and the ore-forming material came from the mantle. The REE ores show distinct light REE enrichment with strong negative Eu anomaly. The REE patterns of schistose rocks from Kyemyeongsan Formation are similar to felsic volcanics from rifts or back arc basins in or near continental crust. The genesis of the REE ore deposit is quite complicated. Different geologic processes are displayed in the studied area; sedimentation, volcanic activity, metamorphism and hydrothermal replacement. Alkali granite has suffered extensive post-magmatic metasomatism of a high temperature to produce alkali metasomatites. Geochemical charateristics show that metasomatism of alkaline fluid was probably the dominant ore-forming process in Chungju district.

• 한국입자에어로졸학회지
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• 제12권2호
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• pp.37-42
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• 2016

$CeO_2$ nanoparticles were prepared by a flame spray pyrolysis from aqueous solution of cerium nitrate. The morphology, structure crystallinity and specific surface area of as-prepared nanoparticles were characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), and Brunauer-Emmett-Telle (BET). The $CeO_2$ nanoparticles about 5 nm in diameter showed a cubic fluorite structure and polyhedral morphology. The average particle size increased as the cerium nitrate concentration increased. UV absorption performance of the as-prepared nanoparticles was measured by UV-visible spectroscopy. UV absorption of $CeO_2$ nanoparticles was more effective than that of commercial $TiO_2$ nanoparticles. Effect of dopants such as Ti and Zn to $CeO_2$ nanoparticles on UV absorption properties was also investigated. In case of $Ti/CeO_2$, and $Zn/CeO_2$ nanoparticles, they showed a little higher UV absorption values compared with $CeO_2$ nanoparticles. The as-prepared nanoparticles can be promising materials with high UV absorption value.