• Title/Summary/Keyword: Fluoride-treatment

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The Analysis of Performance Limiting Factor in Small Water Treatment Plant (소규모정수장의 기능진단에 의한 성능제한 인자의 도출 및 검증 연구)

  • Ha, Eun-Jung;Oh, Jung-Woo;Kim, Jeong-Hyun;Yoon, Jang-Ken
    • Journal of Korean Society of Water and Wastewater
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    • v.14 no.3
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    • pp.240-250
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    • 2000
  • In this study, DWTP Advisor developed from U.S. EPA was adapted for performance assessment in small water treatment plant and studied for improvement advice about the problem. From results of performance assessment, the ability of each major unit process meets to Peak Instantaneous Flow(PIF) as Type I (above 95% of PIF) in N WTP. But, outlet condition in the sedimentation basin are permitting the loss of solids from the basin and the lack of proper solids removal is degrading the performance in N WTP. From results of the hydraulic analysis using fluoride tracer, flow rate in sedimentation basin is rapidly more lower than upper. The Reynolds number, Re, and Froude number, Fr which are used to predict flow condition in sedimentation basin is calculated to be 3159.98 and $2.06{\times}10^{-7}$, respectively. There is possibility of occurrence of short-circuiting and turbulence. Also, the different type of effluent trough makes unstable flow in sedimentation basin and increases carry-overing of sedimented solids.

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Effect of Low Temperature Plasma Pretreatment on the Color Depth of Wool Fabrics (양모직물의 염착농도에 미치는 저온플라즈마 처리의 영향)

  • 배소영;이문철
    • Textile Coloration and Finishing
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    • v.4 no.2
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    • pp.76-83
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    • 1992
  • Wool tropical and nylon taffeta were treated with low temperature plasma of $O_2$, $N_2$, NH$_3$, CF$_4$ and CH$_4$ for the intervals of 10 to 300 sec, and then dyed with leveling and milling type acid dyes in presence or absence of buffer solution. From the color depth of dyed fabrics, effect of plasma gases, treated time, dyeing time and temperature on dyeing property was studied. The results of the experiment can be summarized as follows: 1) The plasma treatments except methane gas increased the color depth of dyed wool fabrics, but not that of dyed nylon fabrics regardless of the plasma gases used. 2) The color depth of wool fabrics dyed in the dye bath without buffer solution was increased by the low temperature plasma, especially increased much more by CF$_4$ plasma treatment. It is found that with the identification of F- ion in the residual dye bath the hydrogen fluoride gas was adsorbed on wool fabrics in the plasma treatment. 3) The color depth of wool fabrics was increased with the time of $O_2$ and CF$_4$ plasma treatments. 4) In both cases of the leveling and milling type acid dyes, the rate of dyeing was increased in the low temperature plasma treatments, and it is found that the leveling type acid dye increased the color depth at relatively low temperature below 4$0^{\circ}C$, compared with the milling type acid dye.

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Preparation of PVDF/PEI double-layer composite hollow fiber membranes for enhancing tensile strength of PVDF membranes

  • Yuan, Jun-Gui;Shi, Bao-Li;Ji, Ling-Yun
    • Membrane and Water Treatment
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    • v.5 no.2
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    • pp.109-122
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    • 2014
  • Polyvinylidene fluoride (PVDF) hollow fiber membrane is widely used for water treatment. However, the weak mechanical strength of PVDF limits its application. To enhance its tensile strength, a double-layer composite hollow fiber membrane, with PVDF and polyetherimide as the external and inner layers, respectively, was successfully prepared through phase inversion technique. The effects of additive content, air gap distance, N,N-dimethyl-acetamide content in the inner core liquid, and the temperature of external coagulation bath on the membrane structure, permeation flux, rejection, tensile strength, and porosity were determined. Experimental results showed that the optimum preparation conditions for the double-layer composite hollow fiber membrane were as follows: PEG-400 and PEG-600, 5 wt%; air gap distance, 10 cm; inner core liquid and the external coagulation bath should be water; and temperature of the external coagulation bath, 40 C. A single layer PVDF hollow fiber membrane (without PEI layer) was also prepared under optimum conditions. The double-layer composite membrane remarkably improved the tensile strength compared with the single-layer PVDF hollow fiber membrane. The permeation flux, rejection, and porosity were also slightly enhanced. High-tensile strength hollow fiber PVDF ultrafiltration membrane can be fabricated using the proposed technique.

Evaluation of Hydraulic Characteristics Influenced by Different Deflector Baffles in the Sedimentation Basin with Inclined Plate Settler (경사판 침전지에서 저류벽의 설치위치에 따른 수리학적 특성의 평가)

  • Yu, Myong-Jin;Kim, Hyun-Chul;Ryu, Seong-Ho
    • Journal of Korean Society on Water Environment
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    • v.21 no.1
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    • pp.40-45
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    • 2005
  • Sedimentation is one of the most common and important units in conventional water treatment plant. Structure such as various baffle walls and inclined plate settler may be obstacles to the horizontal flow when it is poorly designed. Therefore, the effects of these structures on characteristics of hydraulic flow must be evaluated to improve the settling efficiency of the floc. The hydraulic characteristic of the two sedimentations at Y water treatment plant (YWTP), which have different deflector baffles inside the settling basin, were investigated by tracer (fluoride) test. The inclined plate settler installed inside settling basin caused an undesirable impact on horizontal flow and produced dead zone. Solid baffle wall under the plate settler could help to minimize the formation of density currents and flow short circuiting. NaF used as a tracer was recovered more than 90% at investigated all basins. Morill index ($t_{90}/t_{10}$), Modal index ($t_p/T-HRT$) and short-circuiting index ($[M-HRT-t_p]/M-HRT$) were determined from tracer test results performed at YWTP. Those indices ranged 2.95~3.02, 0.40~0.53 and 0.32~0.46, respectively.

Performance of PEG on immobilization of zero valent metallic particles on PVDF membrane for nitrate removal

  • Chan, Yi Shee;Chan, Mieow Kee;Ngien, Su Kong;Chew, Sho Yin;Teng, Yong Kang
    • Membrane and Water Treatment
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    • v.9 no.1
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    • pp.1-7
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    • 2018
  • The principal objective of this study is to investigate the effect of Polyethylene Glycol (PEG) crosslinking in Polyvinylidene Fluoride (PVDF) in immobilization of Fe and bimetallic Fe/Cu and Cu/Fe zero valent particles on the membrane and its efficiency on removal of nitrate in wastewater. PVDF/PEG polymer solution of three weight compositions was prepared to manipulate the viscosity of the polymer. PEG crosslinking was indirectly controlled by the viscosity of the polymer solution. In this study, PEG was used as a modifier of PVDF membrane as well as a cross-linker for the immobilization of the zero valent particles. The result demonstrates improvement in immobilization of metallic particles with the increase in crosslinking of PEG. Nitrate removal efficiency increases too.

Oxidative Transformation of Triclosan by Laccase (Laccase를 이용한 Triclosan의 처리)

  • Kim, Young-Jin
    • Journal of Environmental Health Sciences
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    • v.31 no.1
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    • pp.61-65
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    • 2005
  • The oxidative transformation of triclosan with laccase from Trametes versicolor was conducted in a closed, temperature controlled system containing phosphate buffer for pH control. The optimum pH for triclosan transformation showed about 5. Despite the observation that elevated temperatures tended to inactivate the enzyme, increased transformation of triclosan was observed up to $50^{\circ}C$. Of the mediators studied, ABTS was most successful at enhancing triclosan transformation. About 80% of the toxicity of the initial mixture was reduced after the enzymatic treatment. In the presence of 1.0 mM of anions such as sulfite, sulfide, and cyanide, triclosan transformation was greatly inhibited. Chloride and fluoride ions exhibited inhibition of triclosan transformation at 25 mM. Ferric ion substantially inhibited triclosan transformation at 1.0 mM.

Online preconcentration and preelutioin for the ion chromatographic determination of trace anions in high-sulfate wastewater

  • Song, Kyung-Sun;Kim, Sang-Yeon;Cheong, Young-Wook
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2005.05a
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    • pp.327-328
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    • 2005
  • Trace anions in high-sulfate wastewater from mainly derelict mines were determined by ion chromatography with on-line preconcentration and preelution technique. As the sample was preconcentrated and more strongly held ions were preeluted to the principal separation system, this approach was highly effective in removing large concentration of sulfate in high-sulfate wastewater. With this practical on-line preelution treatment, the peaks of fluoride and chloride showed good resolution even when the sulfate concentration was as high as 2000 mg/L and the analyzed total metal concentration was above 500 mg/L.

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A Study on the Physical Properties of Slag-based Glass-Ceramics (Slag를 위주로 한 Glass-Ceramics 의 물리적 성질에 관한 연구)

  • 장승현;정형진
    • Journal of the Korean Ceramic Society
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    • v.17 no.1
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    • pp.27-34
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    • 1980
  • The synthesis of glass-ceramic materials from glasses based on industrial wastes or natural rocks their physical properties were studied. Glasses of composition, CaO14.7∼16.1, MgO7.4∼9.0, Al2O38.3∼19.3, SiO2 48.9∼51.0wt% were prepared from domestic blast furnace slag, serpentine, sea sand and etc. with additions of chromic oxide, and fluoride as nucleating agent. The glasses were subjected to controlled heat treatments and yielded fine microstructure of glass-ceramics which were composed of monocrystalline phase of aluminous diopside. X-ray diffraction techniques were adopted to identify the crystalline phases and to determine the degree of crystallization quantitatively. Density, coefficient of thermal expansion, young's modulus, microhardness and modulus of rupture were measured and the resulting properties were discussed in terms of the heat-treatment conditions, the degree of crystallization, species of crystaline phase, the microstructures formed in glass-cramics and the chemical compositions of mother glasses.

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Effect of Mothers' Oral Health Knowledge and Behaviour on Dental Caries in Their Preschool Children (유아 어머니의 구강보건인식도에 따른 유아구강건강상태에 관한 연구)

  • Kim, Youn-Hwa
    • Journal of Korean society of Dental Hygiene
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    • v.5 no.2
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    • pp.147-157
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    • 2005
  • The purpose of this study was to assess how mothers' oral health cognition influence on dental caries status of their children. The 194 children and their mothers were selected for this study. The children were 5, 6, 7 years old in the three day care centers in Ulsan, Korea. Date were collected by oral examination on children and self-administrated questionnaire on their mothers. The questionnaire was surveyed mothers' cognition of oral health and their socio-demographic characteristics. The findings of this study were summarized as follows: 1. The higher mother's income, the lower infant's dental caries, there was significant relation. 2. There were no significant relationship between dental caries preventive cogniton, infant's preventive treatment, between-meals intake and infant's dental caries. 3. There was significant relationship between morther's toothbrushing frequency and infant's dental caries.

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Membrane distillation of power plant cooling tower blowdown water

  • Ince, Elif;Uslu, Yasin Abdullah
    • Membrane and Water Treatment
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    • v.10 no.5
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    • pp.321-330
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    • 2019
  • The objective of this study was to examine the recovery of the power plant cooling tower blowdown water (CTBD) by membrane distillation. The experiments were carried out using a flat plate poly vinylidene fluoride (PVDF) membrane with a pore diameter of $0.22{\mu}m$ by a direct contact membrane distillation unit (DCMD). The effects of operating parameters such as transmembrane temperature difference (${\Delta}T$), circulation rate and operating time on permeate flux and membrane fouling have been investigated. The results indicated that permeate flux increased with increasing ${\Delta}T$ and circulation rate. Whereas maximum permeate flux was determined as $47.4L/m^2{\cdot}h$ at ${\Delta}T$ of $50^{\circ}C$ for all short term experiments, minimum permeate flux was determined as $7.7L/m^2{\cdot}h$ at ${\Delta}T$ of $20^{\circ}C$. While $40^{\circ}C$ was determined as the optimum ${\Delta}T$ in long term experiments. Inorganic and non-volatile substances caused fouling in the membranes.