• The Journal of the Korea Contents Association
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• v.12 no.5
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• pp.311-322
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• 2012

Restoration materials used to investigate effects of fluorine such as enamel strengthening and anti-caries effects in several types of dental restoration materials were five kinds including Ionoseal(VOCO GmbH, Cuxhaven, Germany), Fuji Filling LC(GC Co. Tokyo, Japan), Quadrant Universal LC(CAVEX Holland BV, Netherlands), PermaCem$^{(R)}$(DMG, Hamburg, Germany) and Dyract$^{(R)}$ AP(Dentsply GmbH, Germany), and the amount of fluorine-releasing was measured with ICS-5000 Reagent-FreeTM Ion Chromatography(RFICTM, Dionex, U.S.A.). The results of this study are as follows. 1. In all types of restoration materials, the amount of fluoride-releasing was reduced with time passage and it was declined sharply to show significance in four weeks. Fuji Filling LC(12.445PPM) or resin-reinforced glass ionomer and PermaCem$^{(R)}$(16.121PPM) or compomer were found to release fluorine for a long term(P<.001). 2. Ionoseal(0.887PPM) or glass ionomer and Quadrant Universal LC(0.957PPM) or composite resin released a few fluorine of 1PPM or less than 1PPM after one week, and Dyract$^{(R)}$ AP or compomer released fluorine of 8.631PPM in one week and its amount of releasing decreased dramatically in two and four week by recording 0.175PPM and 0.116PPM, respectively. Therefore, the effect of releasing fluorine in four weeks was observed to be poor (P<.001). 3. Fuji Filling LC or resin-reinforced glass ionomer and PermaCem$^{(R)}$ or compomer released fluorine of 33.372 and 1.902PPM, respectively in one week and their amount of releasing increased to be 36.371 and 18.223PPM, respectively in two weeks. So, their amount of fluorine-releasing recorded the highest levels in two weeks(P<.001).

• The korean journal of orthodontics
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• v.28 no.3 s.68
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• pp.399-407
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• 1998

In order to resolve enamel demineralization around orthodontic bracket, fluoride-releasing materials, glass ionomer cements and fluoride-containing resin, were introduced in orthodontic department. There were many studies about their fluoride release, but their results were controversial. The purpose of this study was to clarify the pattern and amounts of fluoride release from glass ionomer cements and a fluoride-containing resin during 70 days in vitro. Disc shaped specimens were prepared and immersed in polyethylene tube containing 2ml distilled deionized water. The daily amounts of the fluoride released from each specimens were measured after experiment 1 day, 3 days, 7 days, 14 days, 42 days and 70 days. They were measured by fluoride-specific electrode combined pH/Ion meter. The following results were as follow, 1. Fluorides released from fluoride-containing resin during 1 day were significantly less than those from glass ionomer cements. 2. On experiment 70 days, mean daily amounts of fluoride released from Miracle-$Mix^{\circledR}$were $3.4{\mu}g/cm^2$, those from Fuji GC $II^{\circledR}$ were $2.7{\mu}g/cm^2$, those from $Orthobond^{\circledR}$ were $2.3{\mu}g/cm^2$, those from Fuji GC $LC^{\circledR}$were $1.4{\mu}g/cm^2$ and those from fluoride-containing resin, $Heliomolar^{\circledR}$, were $0.1{\mu}g/cm^2$. 3. There were no significant differences in daily amounts of fluoride released from between self-curing glass ionomer cements and light-curing glass ionomer cements. Amounts of released fluoride varied among commercially available products. 4. In all experimental materials, amounts of released fluoride decreased rapidly until experimental 3 days and then decreased slowly until 14 days and more slowly until 70 days.

• Journal of Dental Rehabilitation and Applied Science
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• v.24 no.4
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• pp.361-369
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• 2008

The purpose of this study is to make porous oxide film on the surfaces of pure Ti through anodic spark discharge in electrolytic solution containing calcium and phosphate ions, to improve osseointergration by treating fluoride agent. In addition, it is to evaluate the fluoride modified effect on the surface. Commercial pure Ti plate with $20{\times}10{\times}2mm$ and Ti wire with a diameter of 1.5mm and a total length of 15mm were used. After making titanium oxide films converted by anodic spark discharge, anodizing was performed. Fluoride was spreaded to titanium laboratory plate and maintained for 30 minutes after anodizing breakdown. Fluoride ion discharge amount was measured per 24 hours after dipping titanium plate into saline (10ml) and sustaining 90rpm in a pyrostat. Some plates and wires were dipped in Hanks solutions for a month to examine biocompatibility using SEM and XRD. $TiO_2$ film formed by anodic discharge technique showed great roughness and uniform pores which were $1{\sim}3{\mu}m$ in a diameter. Roughness of the films treated with anodic discharge after blasting were higher than the turned ones(P<0.05). Rapid surface activity was observed in the samples treated with $TiF_3$ agent, which immersed in Hanks solution for 30 days. Taking the results into consideration, the fluoride modified implant with anodic discharge demonstrates that it makes uniformly porous oxide film on the surface of implant and properly increase roughness for osseointegration. The implants will achieve greater bone integration after short healing time by improving surface activity.

• Journal of the korean academy of Pediatric Dentistry
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• v.35 no.3
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• pp.469-476
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• 2008

This study was performed to compare the fluoride release pattern and compressive strength of recently developed resin-modified glass ionomers($Ketac^{TM}$ N 100 and Fuji Fil LC) with those of conventional glass ionomer restorative material(Fuji II LC). Fifteen sample discs(6 mm diameter and 1 mm height) were prepared for each tested material. The fluoride release was measured by pH/ISE meter(750P, Istek, Korea) for 31 days. For compressive strength experiment, fifteen cylindrical specimens were prepared for each tested material. Each specimen was submitted to compressive strength testing in an universal testing machine(Kyung-sung Testing Machine Co., Korea) at crosshead speed of 5.0mm/min until failure. The results can be summarized as follows; 1. Fuji Fil LC released the highest amount of fluoride, followed by Fuji II LC and $Ketac^{TM}$ N 100(p<0.05). 2. The compressive strength of Fuji Fil LC was the lowest(p<0.05). However, no significant difference was found from Fuji II LC and $Ketac^{TM}$ N 100(p>0.05). By considering the above results, careful case selection and accurate clinical application is recommended when using $Ketac^{TM}$ N 100 and Fuji Fil LC.

• The korean journal of orthodontics
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• v.29 no.5 s.76
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• pp.589-597
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• 1999

The purpose of this study was to evaluate the effects of fluoride releasing orthodontic sealants, light-cured (Group L1&L2) and self-cured (Group S1&S2) $FluoroBond^{\circledR}$, on enamel microhardness under artificial carious solution in vitro.112 extracted human premolar teeth were collected for experiments and divided into seven groups. A Tukon microhardness tester equipped with a Knoop diamond indenter was employed to determine microhardness. Tukon 23 program converted the number of microhardness into KHN (Knoop hardness number). The results were as follows: 1. The microhardness of enamel depth of all groups were the least at the depth of $50{\mu}m$ and that of all groups except L2 group, the greatest at the depth of $200{\mu}m$, were the greatest at the depth of $300{\mu}m$. And as the enamel depth of all groups except L2 and S2 group increased, the microhardness value also increased. 2. There was a little preventive effect in enamel decalcification both light-and self-cured orthodontic sealant groups, but had no statistical significance between the groups(p>0.05). 3. Light-cured orthodontic sealant groups had a progressive inhibiting effect in enamel decalcification at the depth of $100{\mu}m,150{\mu}m,\;and\;200{\mu}m$ (p<0.05). 4. Self-cured orthodontic sealant groups had a progressive inhibiting effect in enamel decalcification at the depth of $150{\mu}m$ (p<0.05). 5. There was no difference of the anti-enamel demineralization effect between light- and self-cured orthodontic sealant groups (p>0.05).

• Journal of the korean academy of Pediatric Dentistry
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• v.37 no.4
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• pp.422-428
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• 2010

Giomer is fluoride-releasing, resin-based dental materials that comprise PRG(pre-reacted glass ionomer) filler. The purpose of this study was to evaluate the shear bond strength of Giomer using self-etching primer systems to bovine dentin. Bovine incisors were mounted in self-curing orthodontic resin and the facial surfaces were wet ground on SIC paper to expose the dentin. Total 100 samples were made and divided randomly into 4 groups, Giomer group(I), Composite resin group(II) and Compomer group(III), Giomer and single bottle adhesive group(IV). The shear bond strengths of 25 samples per each group were measured using universal testing machine. And data were analyzed statistically with One-way ANOVA and Scheffe test. Giomer group(I) showed the significantly higher bond strength than Compomer group(III)(p<0.05). There was no significant difference between Giomer group(I) and Composite resin group(II)(p>0.05). And there is no significant difference between gourp(I) and group(IV). Based on the results of present study, the use of Giomer as an esthetic restorative material for primary teeth might be justified. It is considered that more study about the fluoride releasing ability is needed to evaluate the anticariogenic effect of giomer.

• The korean journal of orthodontics
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• v.36 no.5
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• pp.360-368
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• 2006

Objective: Surface characteristics of dental materials play an important role in bacterial adhesion. The purpose of this study was to investigate surface characteristics of 5 different light-cured orthodontic adhesives (1 fluoride-releasing composite, 3 non-fluoride-releasing composites, and f resin-modified glass ionomer). Methods: Surface roughness was measured using a confocal laser scanning microscope. Contact angle and surface free energy components were analyzed using the sessile drop method. Results: Surface roughness was significantly different between adhesives despite a relatively small variation (less than $0.05\;{\mu}m$). Lightbond and Monolok2 were rougher than Enlight and Transbond XT. There were also significant differences in contact angles and surface free energy components between adhesives. In particular, considerable differences in contact angles and surface free energy components were found between resin modified glass ionomer and the composites. Resin modified glass ionomer showed significantly smaller contact angles in 3 different probe liquids and had higher total surface free energy and stronger polarity, with notably stronger basic property than the composites. Conclusion: Resin modified glass ionomer may provide a more favourable environment for bacterial adhesion than composite adhesives.

• The korean journal of orthodontics
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• v.40 no.4
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• pp.260-266
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• 2010

Objective: The aim of this study was to determine whether different types of adhesive systems and enamel-protective agents will affect the tensile bond strength of lingual brackets. Methods: A total of 75 extracted mandibular incisors were randomly divided into 5 groups and lingual brackets were bonded. Group 1 specimens received Transbond XT (3M Unitek, Monrovia, CA, USA), Group 2 required the application of a fluoride-releasing resin (Ortho-coat, Pulpdent, Watertown, MA, USA) with Transbond XT, Group 3 specimens received a chlorhexidine varnish (Cervitec Plus, Ivoclar Vivadent, Schaan, Lichtenstein) with Transbond XT. In Group 4, a light-cured orthodontic adhesive (Aegis Ortho, Bosworth, Skokie, USA) was applied and in Group 5, an antimicrobial self-etching primer (Clearfil Protect Bond, Kuraray, Osaka, Japan) was used. Results: There were no significant differences in bond strength whether fluoride-releasing resin or chlorhexidine varnish were used or not. Group 5 had significantly higher bond strength and adhesive remnant index (ARI) values than other groups (p < 0.001). The application of enamel-protective products did not have an adverse affect on the bond strength of lingual brackets. Conclusions: These products might provide benefits both for the patient and the clinician, by supporting the oral hygiene during lingual orthodontic treatment. The higher ARI score may be beneficial for Clearfil Protect Bond but its excessive bond strength should be considered in clinical practice, especially where the enamel is thin.

• The korean journal of orthodontics
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• v.27 no.6 s.65
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• pp.979-995
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• 1997

The purpose of this study was to identify the preventive and the progressive inhibitory effects of enamel demineralization with fluoride releasing light-and self-cured orthodontic sealants(FluoroBond), in vitro, under the polarizing light microscope and the scanning electon microscope. The polarizing light microscopic group was subdivided into seven groups(Group A-Group G). The scanning electron microscopic group was also subdivided into seven groups(Group A'-Goup G'). For polarizing light microscopic evaluation, longitudinal sections were made longitudinally by Maruto cutter(Maruto Co., Japan) and Maruto grinding machine(Maruto Co., Japan). Sections were examined and photographed by the polarizing light microscope(Olympus Optical Co., Japan) using crossed polars and with the enamel rod longitudinal axis oriented at $45^{\circ}$ to the extinction position. For scanning electron microscopic evaluation, the specimens were coated with a highly conducting layer of gold palladium in a model Hus-4 high-vacuum evaporator and examined in an ISI-100B scanning electron microcope operated at 20kV. The results of this study were as follows : 1. The mean depths of artificial carious lesions under a polarized light microscope were $Group\;A(5.08{\mu}m),\;Group\;B(47.82{\mu}m,\;Group\;C(8.42{\mu}m),\;Group\;D(7.20{\mu}m),\;Group\;E(85.41{\mu}m),\;Group\;F(60.38{\mu}m),\;Group\;G(60.13{\mu}m)$. 2. There were statistically significant differences in Group B compared with Group A, C, and D(p<0.05), and also, in Group I compared with Group F and Group G(p<0.05). 3. Light-and self-cured orthodontic sealants had the preventive effects of enamel demineralization. 4. Light-and self-cured orthodontic sealants had the progressive inhibitory effects of enamel demineralization. 5. The time progress of demineralizing agent had no influence on the samples of light-and self-cured orthodontic sealants under the scanning electron microscope. 6. There was no difference between the specimens of light-and self-cured orthodontic sealants both in the polarized light microscopic group and in the scanning electron microscopic group.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.35 no.1
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• pp.72-79
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• 2022

Piezoelectric energy harvesting technologies, which can be used to convert the electricity from the mechanical energy, have been developed in order to assist or power the wearable electronics. To realize non-toxic and biocompatible electronics, the lead-free (Ba_0.85Ca_0.15)(Ti_0.90Zr_0.10)O₃ (BCTZ) nanoparticles (NPs) are being studied with a great attention as flexible energy harvesting device. Herein, piezoelectric hybrid nanocomposites were fabricated using BCTZ NPs-embedded poly(vinylidene fluoride-trifluoroethylene) [P(VDF-TrFE)] matrix to improve the performance of flexible energy harvester. Output performance of the fabricated energy device was investigated by the well-optimized measurement system during the periodically bending and releasing motions. The generated open-circuit voltage and the short-circuit current of the piezoelectric hybrid nanocomposite-based energy harvester reached up to ~15 V and ~1.1 ㎂, respectively; moreover, the instantaneous power of 3.5 ㎼ is determined from load voltage and current at the external load of 20 MΩ. This research is expected to cultivate a new approach to high-performance wearable self-powering electronics.