• Corrosion Science and Technology
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• 제7권1호
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• pp.61-67
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• 2008

In this paper, electrochemical and microstructural characteristics of nickel-plated Alloy 600 were investigated in order to identify the performance of electroless Ni-plating on Alloy 600 in high-temperature aqueous condition with the comparison of electrolytic nickel-plating. For high temperature corrosion test of nickel-plated Alloy 600, specimens were exposed for 770 hours to typical PWR primary water condition. During the test, open circuit potentials (OCP's) of all specimens were measured using a reference electrode. Also, resistance to flow accelerated corrosion (FAC) test was examined in order to check the durability of plated layers in high-velocity flow environment at high temperature. After exposures to high flow rate aqueous condition, the integrity of surfaces was confirmed by using both scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). For the field application, a remote process for electroless nickel-plating was demonstrated using a plate specimen with narrow gap on a laboratory scale. Finally, a practical seal design was suggested for more convenient application.

• Corrosion Science and Technology
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• 제20권6호
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• pp.373-383
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• 2021

The effect of Cr addition to high Mn steel on flow-accelerated corrosion (FAC) behavior in a neutral aqueous environment was evaluated. For comparison, two types of conventional ferritic steels (API X70 steel and 9% Ni steel) were used. A range of experiments (electrochemical polarization and impedance tests, weight loss measurement, and metallographic observation of corrosion scale) were conducted. This study showed that high Mn steel with 3% Cr exhibited the highest resistance to FAC presumably due to the formation of a bi-layer scale structure composed of an inner Cr enriched Fe oxide and an outer Mn substituted partially with Fe oxide on the surface. Although the high Mn steels had the lowest corrosion resistance at the initial corrosion stage due to rapid dissolution kinetics of Mn elements on their surface, the kinetics of inner scale (i.e. Cr enriched Fe oxide) formation on Cr-bearing high Mn steel was faster in dynamic flowing condition compared to stagnant condition. On the other hand, the corrosion scales formed on API X70 and 9% Ni steels did not provide sufficient anti-corrosion function during the prolonged exposure to dynamic flowing conditions.

• Nuclear Engineering and Technology
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• 제37권4호
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• pp.375-384
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• 2005

To investigate the flow-accelerated corrosion (FAC) dependency of carbon steel (A106 Gr. B) and low-alloy steels (1Cr-1/2Mo, 21/4Cr-1Mo) on pH, orifice distance, and material, experiments were carried out. These experiments were performed using a flow velocity of 4 m/sec (partly 9 m/sec) at pH $8.0\~10.0$ in an oxygen-free aqueous solution re-circulated in an Erosion-Corrosion Test Loop at $130^{\circ}\;{\ldots}$ for 500 hours. The weight loss of the carbon steel specimens appeared to be positively dependent on the flow velocity. That of the carbon and low-alloy steel specimens also showed to be distinguishably dependent on the pH. At pH levels of $8.0\~9.5$ it decreased, but increased from 9.5 to 10.0. Utility water chemistry personnel should carefully consider this kind of pH dependency to control the water system pH to mitigate FAC of the piping system material. The weight loss of the specimens located further from the orifice in the distance range of $6.8\~27.2$ mm was shown to be greater, except for 21/4Cr-1Mo, which showed no orifice distance dependency. Low alloy steel specimens exhibited a factor of two times better resistance to FAC than that of the carbon steel. Based on this kind of FAC dependency of the carbon and low-alloy steels on the orifice distance and material, we conclude that it is necessary to alternate the composition of the secondary piping system material of NPPs, using low-alloy steels, such as 21/4Cr-1Mo, particularly when the system piping has to be replaced.

• 한국원자력학회:학술대회논문집
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• 한국원자력학회 2001년도 춘계학술발표회요약집
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• pp.319.2-319
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• 2001

• 한국원자력학회:학술대회논문집
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• 한국원자력학회 1999년도 추계학술발표회요약집
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• pp.228.2-228
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• 1999

• 플랜트 저널
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• 제9권4호
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• pp.26-30
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• 2013

유동가속부식에 의해 배관이 파손된 500 MW급 A 복합발전소 배열회수보일러 저압증기발생기 배관을 모델로 삼아 배관급수 내의 용존산소 부족이 유동가속부식의 주요 원인임을 도출하고 용존산소를 증가시키기 위해 적용된 하이드라이진 차단 수처리에 대한 적용효과를 분석하였다. 수처리 적용 1년 후 급수의 용존산소는 0.15 ppb에서 3~5 ppb로 상승되고, 산화환원전위도 -245 mV에서 170 mV로 산화성으로 상승되었다. 또한 유동가속부식에 의한 부식생성물인 철분함유량은 18.5 ppb에서 5~7 ppb로 감소되었다. 따라서 하이드라이진 차단 수처리로 급수의 용존산소가 증가되며 유동가속부식에 의한 배관의 부식생성물인 철분함유량이 감소됨을 확인하였다.

• 비파괴검사학회지
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• 제30권4호
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• pp.295-301
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• 2010

원자력발전소 탄소강 배관의 유체가속부식은 주요 경년열화 현상이며 발전소의 성능 및 안전성을 저해할 수 있다. 유체가속부식 검사는 보온재 제거 및 설치로 상당한 비용이 수반되므로 최근에 보온재 제거가 필요 없고 원거리 검사가 가능한 유도초음파에 대한 관심이 점점 증가되고 있다. 유체가속부식 검출에 유도초음파 적용이 가능하다면 검사 비용 절감이 예상된다. 본 연구의 목적은 유체가속부식 손상 유무를 확인하고 결함 검출능을 결정하기 위함이다. 본 연구에서는, 실제 유체가속부식 손상 시험편의 엘보우 첫 번째 용접부와 두 번째 용접부의 진폭 감쇄비를 측정하기 위하여 3가지 검사 기법을 사용하였다. 연구 결과, 유체가속부식 손상을 검출하기 위한 최적의 검사 기법과 최소 결함 검출능을 도출하였다.

• Corrosion Science and Technology
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• 제17권6호
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• pp.317-323
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• 2018

Assumptions have always been that wall thinning on the secondary side piping in nuclear power plants is mostly caused by Flow-Accelerated Corrosion (FAC). Recent studies have showed that wall thinning on the secondary side piping is caused by Liquid Droplet Impingement Erosion (LDIE), Solid Particle Erosion (SPE), cavitation, and flashing. To manage those aging mechanisms, several software such as CHECWORKS, COMSY, and BRT-CICERO have been used in nuclear power plants. Korean nuclear power plants have been using the CHECWORKS program since 1996 to date. However, many site engineers have experienced a lot of inconveniences and problems in using the CHECWORKS program. In order to work through the inconveniences and to remedy problems, KEPCO-E&C has developed a "3D-based pipe wall thinning management program (ToSPACE)" based on the experience of over 30 years in relation to the pipe wall thinning management. This study compares the results of FAC and LDIE analysis using both the CHECWORKS and ToSPACE programs with respect to validation of the wall thinning analysis results.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2000년도 추계학술대회 논문집 학회본부 A
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• pp.269-272
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• 2000

The flow accelerated galvanic corrosion characteristics of a carbon steel coupled to stainless steel were investigated in deaerated alkaline-chloride solutions as a function of flow velocities(0, 0.2, 0.4 and 0.6 m/s), pH(8, 9, and 10) and temperature(25, 50 and $75^{\circ}C$). The electrochemical properties of specimens were investigated by potentiodynamic test and galvanic corrosion test using RCE(Rotating Cylinder Electrode). Carbon steel did not show passive behavior in the alkaline-chloride solution. The galvanic current density increases with increasing flow velocity and temperature, but decreased with increasing pH. Flow velocity had a small effect on the galvanic current density at $25^{\circ}C$, whereas the flow velocity increased galvanic current density significantly at $50^{\circ}C$ and $75^{\circ}C$. This might be due to the increased solubility of magnetite at the higher temperature.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2004년도 춘계학술대회
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• pp.2017-2022
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• 2004

There are multistage preheaters in the power generation plan to improve the thermal efficiency of the plant and to prevent the components from the thermal shock. The energy source of these heaters comes from the extracted two phase fluid of working system. These two-phase fluid can cause the so-called Flow Accelerated Corrosion(FAC) in the extracting piping and the bubble plate of the heater for example, in case of point Beach Nuclear Power Plant and in the Wolsung Nuclear Power Plant. The FAC is due to the mass transport of the thin oxide layer by the convection. FAC is dependent on many parameters such as the operation temperature, void fraction, the fluid velocity and pH of fluid and so on. Therefore, in this paper velocity was calculated by FLUENT code in order to find out the root cause of the wall thinning of the feedwater heaters. It also includeed in the fluid mixing analysis model are around the number 5A feedwater heater shell including the extraction pipeline. To identify the relation between the local velocities and wall thinning, the local velocities according to the analysis results were compared with distribution of the shell wall thicknes by ultrasonic test.