• 제목/요약/키워드: Flat sheet

검색결과 203건 처리시간 0.027초

상전이법을 이용한 기체 분리용 Hydroxy Polyimide 막의 제조 (Preparation of Hydroxy Polyimde Membranes for Gas Separation by Phase Inversion Method)

  • 우승문;최종진;남상용
    • 멤브레인
    • /
    • 제22권1호
    • /
    • pp.62-71
    • /
    • 2012
  • 본 연구에서는 고투과성을 가지는 기체분리막 제조를 위해 6FDA와 APAF를 이용하여 하이드록시 폴리이미드를 합성하였다. H-NMR과 FT-IR 분석을 통해서 HPI의 합성여부를 확인하였으며 열적특성을 알아보기 위해 Differential scanning calorimetry (DSC)와 thermogravimetric analyzer (TGA)를 측정하였다. 특히 합성된 HPI는 약 $450^{\circ}C$에서 polybenzoxazole (PBO)로 변환이 됨을 확인 가능하였다. 고투과성 고분자 분리막의 제조를 위해 고분자, 용매 그리고 비용매-첨가제를 포함하는 3성분계의 시스템을 도입하였으며, 상전이법을 이용하여 HPI 비대칭 평막을 제조하였다. 최종적으로 각성분들에 따른 모폴로지 변화를 전계방출주사현미경(FE-SEM)을 통해 확인할 수 있었다.

평막형태의 폴리벤지다미졸 분리막의 연료전지, 기체분리막, 유기물분리용 나노여과막으로의 응용: 총설 (Flat Sheet Polybenzimidazole Membranes for Fuel Cell, Gas Separation and Organic Solvent Nanofiltration: A Review)

  • 아누남 다스;남상용
    • 멤브레인
    • /
    • 제33권6호
    • /
    • pp.279-304
    • /
    • 2023
  • 폴리벤즈이미다졸(PBI) 기반의 막은 내구성이 우수한 네트워크 구조를 가지는 구조재료로서의 우수한 강성과 더불어서 고온에서의 우수한 내열성, 우수한 기계적 및 인장 특성, 높은 유리전이온도(Tg), 물이 없는 무수 환경에서의 이온 전도성능, 산화와 화학적 내구성으로 지난 20년 동안 다양한 용도의 대중적인 막 재료로 다양한 문헌에서 보고되어 왔다. 이온 전도성 PBI 기반 막은 고온용 양이온 교환막 연료 전지(HT-PEMFC)에서 광범위하게 사용되어왔다. 또한 PBI 기반 막은 독특한 특성으로 인해 기체분리막 및 유기용매나노여과(OSN) 막 개발에서 광범위하게 사용되어왔다. 이번 리뷰에서는 고온용 연료전지, 기체분리 및 OSN 적용을 위한 다양한 유형의 PBI 기반 막의 최근 연구동향 및 적용가능성에 대해 설명하고자 한다.

고유전율/저유전율 LTCC 동시소성 기판의 휨 현상 (Warpage of Co-fired High K/Low K LTCC Substrate)

  • 조현민;김형준;이충석;방규석;강남기
    • 마이크로전자및패키징학회지
    • /
    • 제11권3호
    • /
    • pp.77-82
    • /
    • 2004
  • 본 연구에서는 고유전율(K100) 및 저유전율(K7.8) LTCC(Low Temperature Co-fired Ceramics) 그린 시트를 이종 LTCC 기판으로 동시 소성하는 경우, 고유전율 LTCC 내의 유리 분말 함유량에 따라 발생하는 수축 거동 변화가 이종 LTCC기판의 휨 특성에 미치는 영향에 대하여 평가하였다. 유리 분말 함유량의 증가에 따른 고유전율 LTCC 그린시트의 수축률 및 유전 특성을 측정하였으며, 고유전율/저유전율 비대칭형 적층체의 소결 거동을 고온 현미경을 이용하여 실시간으로 측정하였다. $50\%$ 유리가 첨가된 K100 조성의 경우 수축 개시 온도 및 수축 구간의 범위 , 최종 수축률이 K7.8 조성과 유사하였으며, 동시 소성 시 가장 우수한 휨 특성을 나타내었다.

  • PDF

OLED용 ITO박막의 공정조건과 품질특성 추론에 근거한 품질관리 (Quality Management of ITO Thin Film for OLED Based on Relationship of Fabrication and Characteristics)

  • 서정민;박근영;이상룡;이춘영
    • 제어로봇시스템학회논문지
    • /
    • 제14권4호
    • /
    • pp.336-341
    • /
    • 2008
  • Recently, research on a flat panel display(FPD) has focused on organic light-emitting display(OLED) which has wide angle of view, high contrast ratio and low power consumption. ITO(Indium-Tin-Oxide) films are the most widely used material as a transparent electrode of OLED and also in many other display devices like LCD or PDP. The performance and efficiency of OLED is related to the surface condition of ITO coated glass substrate. The typical surface defect of glass substrate is measured for electric characteristics and physical condition for transmittance and roughness. Since ITO coated glass substrate can be destroyed for inspection about surface roughness, sheet resistance, film thickness and transmittance, precise fabrication condition should be made based on the estimated relationship. In this paper, ITO films were prepared on the commercial glass substrate by the Ion-Plating method changing the partial pressure of gas(Ar, 02) and the chamber temperature between $200^{\circ}C$ and $300^{\circ}C$. The characteristics of films were examined by the 4-point probe, supersonic thickness measurement, transmittance measurement and AFM. We estimated the relationship between processing parameters(Ar gas, O2 gas, Temperature) and properties of ITO films (Sheet Resistance, Film Thickness, Transmittance, Surface Roughness).

ITO 박막의 $O_2$ 플라즈마 처리에 의한 휴지전기발광소자의 특성 향상 (Improvement of Organic Electroluminescent Device Performance by $O_2$ Plasma Treatment of ITO Surface)

  • 양기성;김두석;김병상;신훈규;권영수
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2004년도 춘계학술대회 논문집 반도체 재료 센서 박막재료 전자세라믹스
    • /
    • pp.137-140
    • /
    • 2004
  • We treated $O_2$ plasma on ITO thin film using RIE (Reactive Ion Etching) system, and analyzed the ingredient of ITO thin film according to change of processing conditions. The ingredient analysis of ITO thin film was used by EDS (Energy Dispersive Spectroscopy) and XPS (X-ray Photoelectron Spectroscopy) to compare and analyze the ingredient of bulk and surface. We measured electrical resistivity using Four-Point-Probe and calculated sheet resistance, and ITO surface roughness was measured by using AFM (Atomic Force Microscope). Finally, we fabricated OLEDs (Organic Light-Emitting Diodes) device using substrate that was treated optimum ITO surface. The result of the study for electrical and optical properties using I V L System (Flat Panel Display Analysis System), we confirmed that electrical properties (I-V) and optical properties (L-V) were improved.

  • PDF

Spray characteristics of misaligned impinging injectors

  • Subedi, Bimal;Son, Min;Kim, Woojin;Choi, Jangsu;Koo, Jaye
    • Journal of Advanced Marine Engineering and Technology
    • /
    • 제38권10호
    • /
    • pp.1257-1262
    • /
    • 2014
  • The variances of atomization characteristics with the misalignment of injectors defined as the fraction of skewness for various angles of impingement and pressure conditions were studied using the doublet impinging injectors with a like-on-like arrangement. Water was used as simulant and the spray characteristics along with the changes in the skewness were analyzed using the methods of spray image photography. Experiment was carried for the impinging nozzles of orifice diameter of 1.2 mm within Reynolds numbers ranging from $9{\times}10^3-4.5{\times}10^4$ and the fraction of skewness considered for the experiment ranges from 0.0 to 0.9 at ambient temperature condition. Flat sheet with a distinct rim produced perpendicular to the plane of impinging jets goes ondisappear and sheet appears comparatively shorterwith the increase in fraction of skewness resulting the atomization of fluid droplet very close to impingement point with decrease in breakup length and increase in spray angle up to certain extent. The maximum allowable skewness was found as the result. The skewness up to the certain extent can be considered as the parameter to control the atomization characteristics of simulant inside the combustion chamberproviding the high economic performance of fuel and time.

Optimization of GZO/Ag/GZO Multilayer Electrodes Obtained by Pulsed Laser Deposition at Room Temperature

  • Cheon, Eunyoung;Lee, Kyung-Ju;Song, Sang Woo;Kim, Hwan Sun;Cho, Dae Hee;Jang, Ji Hun;Moon, Byung Moo
    • 한국진공학회:학술대회논문집
    • /
    • 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
    • /
    • pp.336.2-336.2
    • /
    • 2014
  • Indium Tin Oxide (ITO) thin films are used as the Transparent Conducting Oxide (TCO), such as flat panel display, transparent electrodes, solar cell, touch screen, and various optical devices. ZnO has attracted attention as alternative materials to ITO film due to its resource availability, low cost, and good transmittance at the visible region. Recently, very thin film deposition is important. In order to minimize the damage caused by bending. However, ZnO thin film such as Ga-doped ZnO(GZO) has poor sheet resistance characteristics. To solve this problem, By adding the conductive metal on films can decrease the sheet resistance and increase the mobility of the films. In this study, We analyzed the electrical and optical characteristics of GZO/Ag/GZO (GAG) films by change in Ag and GZO thickness.

  • PDF

유한장 직선도체에 의한 자계의 계산 및 감소대책 (Calculation and Mitigation of Magnetic Field Produced by Straight Line-Conductor with Finite Length)

  • 강대하
    • 조명전기설비학회논문지
    • /
    • 제25권6호
    • /
    • pp.57-67
    • /
    • 2011
  • Purpose of this study is to find the mitigation method of magnetic field by finite length multi-conductors such as indoor distribution lines and to be applicable to design of the distribution lines. For this purpose, exact formula about the components $B_x$, $B_y$, $B_z$ of magnetic field need in case of straight line-conductor with finite length forward any direction. In this study simple formula of the components were deduced and by using these formula magnetic fields for various models of line-configurations were calculated. And also a calculation method of induced currents in conductive shield was presented and using this method, programing of calculation is relatively easy and calculation time is short. The magnetic field after cancellation by these induced currents was calculated. All of calculations were performed by Matlab 7.0 programs. Through the calculation results it could be obtained followings for the mitigation of magnetic fields. The separation between conductors ought to be smaller than smaller as possible. In case of 3-phase, delta configuration is more effective than flat configuration. In case of 3-phase, unbalanced currents ought to be reduced as possible.. In case of more than two circuits of 3-phase, adequate locations of each phase-conductor such as rotating configuration of 3-phase conductors are more effective. The magnetic shielding effect of the conductive shielding sheet is very high.

자동차용 합금화 용융아연도금강판의 도금층 미소물성 및 파괴 거동 (Microproperties and Fracture Behavior of Galvannealed Coating Layer of Automobiles)

  • 박춘달;고대철;김병민
    • 한국정밀공학회지
    • /
    • 제24권3호
    • /
    • pp.91-99
    • /
    • 2007
  • Fractures of galvannealed coating layer during actual press forming in automotive applications were observed by scanning electron microscopy in order to understand fracture mechanism. Fracture behaviors of galvannealed coating layer in extra deep drawing quality steels and high strength steels have been studied by performing the tests describing the representative plastic deformation in sheet metal forming such as uni-axial tensile test, compression test, bi-axial test and plane strain test. Growth and direction of cracks were deeply related to the plastic deformation modes and history. The material properties of galvannealed coating layer were investigated by nano-indentation test equipped with Berkovich diamond indentor for the specimens. Hardness and elastic modulus of the coating layer were higher than bared steels and that was the reason for crack of coating layer. Flat friction test and drawbead friction test were performed to observe the effect of the surface morphology on the frictional characteristics. The micro-plasto hydrodynamic lubrication were appeared and played an important role in reducing the coefficient of friction.

Transparent Conductive Single-Walled Carbon Nanotube Films Manufactured by adding carbon nanoparticles

  • Lee, Seung-Ho;Kim, Myoung-Soo;Goak, Jung-Choon;Lee, Nae-Sung
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2009년도 하계학술대회 논문집
    • /
    • pp.417-417
    • /
    • 2009
  • Although a transparent conductive film (TCF) belongs to essential supporting materials for many device applications such as touch screens, flat panel displays, and sensors, a conventional transparent conductive material, indium-tin oxide (ITO), suffers from considerable drawback because the price of indium has soared since 2001. Despite a recent falloff, a demand of ITO is expected to increase sharply in the future due to the trend of flat panel display technologies toward flexible, paper-like features. There have been recently extensive studies to replace ITO with new materials, in particular, carbon nanotubes (CNTs) since CNTs possess excellent properties such as flexibility, electrical conductivity, optical transparency, mechanical strength, etc., which are prerequisite to TCFs. This study fabricated TCFs with single-walled carbon nanotubes (SWCNTs) produced by arc discharge. The SWCNTs were dispersed in water with a surfactant of sodium dodecyl benzene sulfonate (NaDDBS) under sonication. Carbon black and fullerene nanoparticles were added to the SWCNT-dispersed solution to enhance contact resistance between CNTs. TCFs were manufactured by a filtration and transfer method. TCFs added with carbon black and fullerene nanoparticles were characterized by scanning electron microscopy (SEM), UV-vis spectroscopy (optical transmittance), and four-point probe measurement (sheet resistance).

  • PDF