• International Journal of Highway Engineering
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• v.16 no.5
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• pp.9-18
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• 2014

PURPOSES : The objective of this study is to evaluate the applicability of the pitch, which is produced during SDA petroleum upgrading process, as a pavement paving material. In order for the purpose, the physical and chemical properties of the pitch are analyzed, and then the various plasticizers are applied in the pitch. METHODS : Two types of pitch are selected from oil refinery companies, which are owned the SDA petroleum upgrading process. Also, two types of asphalt binders, PG 64-22 and PG 58-22, are employed to compare with the pitch because these two types of asphalt binders are currently used as paving materials. For the chemical property of the pitch, the composition of SARA (Saturate, Aromatic, Resin, Asphaltene), the elementary composition, and the functional group are analyzed. For the physical property of the pitch, the basic material property tests, such as penetration test, softening point test, flash point test, ductility test, and rotational viscometer test, are performed. Also, the DSR (Dynamic Shear Rheometer) test and the BBR (Bending Beam Rheometer) test are conducted using asphalt binder specimens obtained by both short term aging (Rolling Thin Film Oven, RTFO) and long term aging (Pressure Aging Vessel, PAV) processes. The rheological property of each pitch type is evaluated as a function of temperatures and loading cycles. PG 64-22 asphalt binder is used as a control material. RESULTS AND CONCLUSIONS : The Pitch may not be suitable for the pavement paving material without modifications, but the pitch can be used as alternatives of modified addictive or asphalt. If low molecular component, such as saturate and aromatic components, are added in the pitch based on the development of various plasticizers, it has a strong possibility for the pitch to be used as a alternative. However, in order to verify the performance property of the pitch, further research is needed.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.24 no.2
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• pp.238-245
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• 2014

Objectives: It was known that workers in synthetic leather company are mainly co-exposed to dimethylformamide(DMF) with methyl ethyl ketone(MEK) or toluene(TOL) instead of a single dimethylformamide. This study was examined to the physico-chemical properties in single DMF and binary mixture DMF with MEK or TOL. Materials: Physico-chemical properties were measured by Korean and American Standard Test Methods. Results: Boiling point, specific gravity and flash point in single DMF were significantly higher than binary mixture DMF with MEK or TOL and such difference was dependent on the mixing ratio of MEK and TOL, and low explosion limit in binary mixture DMF with TOL was only significantly lower than single DMF. However, Reid vapor pressure had significantly higher in binary mixture DMF with MEK or TOL compared with single DMF. Conclusions: Our results demonstrate that the binary mixture DMF with MEK or TOL synergistically increases volatilization of DMF. It was concluded that the interaction between DMF and MEK and/or TOL might play a key role in the volatilization process of DMF under environmental conditions of workplace.

• Proceedings of KOSOMES biannual meeting
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• 2006.11a
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• pp.291-297
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• 2006

Recently it is a tendency that the use of the heavy fuel oil is investigated even from the middle&small class vessel in order to reduce the operating cost of vessel caused by with rise of international gas price. In this study, analyzed the physical & chemical properties and examined the effect of refining treatment and a fuel oil additive for MF30 fuel oil which is a mixture fuel oil mixed M.G.O and the heavy oil MF380 use to be possible in the middle&small class vessel. As a results, the effects of two of pre-refinery treatment methods as centrifugal purifier and heating & homogenizing system(M.C.H) are some feeble, but the pour point and the flash point came to be low more or less. The effect of property improvement which is caused by with the fuel oil additive did not appear positively.

• Toxicological Research
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• v.32 no.4
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• pp.337-343
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• 2016

We determined the toxicity of mixtures of ethyl acetate (EA), isopropyl alcohol (IPA), methyl ethyl ketone (MEK), toluene (TOL) and xylene (XYL) with half-maximal effective concentration ($EC_{50}$) values obtained using human hepatocytes cells. According to these data, quantitative property-activity relationships (QPAR) models were successfully proposed to predict the toxicity of mixtures by multiple linear regressions (MLR). The leave-one-out cross validation method was used to find the best subsets of descriptors in the learning methods. Significant differences in physico-chemical properties such as boiling point (BP), specific gravity (SG), Reid vapor pressure (rVP) and flash point (FP) were observed between the single substances and the mixtures. The $EC_{50}$ of the mixture of EA and IPA was significantly lower than that of contained TOL and XYL. The mixture toxicity was related to the mixing ratio of MEK, TOL and XYL (MLR equation $EC_{50}=3.3081-2.5018{\times}TOL-3.2595{\times}XYL-12.6596{\times}MEK{\times}XYL$), as well as to BP, SG, VP and FP (MLR equation $EC_{50}=1.3424+6.2250{\times}FP-7.1198{\times}SG{\times}FP-0.03013{\times}rVP{\times}FP$). These results suggest that QPAR-based models could accurately predict the toxicity of polar and nonpolar mixtures used in rotogravure printing industries.

• Bulletin of the Korean Chemical Society
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• v.35 no.12
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• pp.3637-3641
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• 2014

In this study, we analyzed the toxicity of mixtures of dimethylformamide (DMF) and methyl ethyl ketone (MEK) or DMF and toluene (TOL) and predicted their toxicity using quantitative structure-activity relationships (QSAR). A QSAR model for single substances and mixtures was analyzed using multiple linear regression (MLR) by taking into account the statistical parameters between the observed and predicted $EC_{50}$. After preprocessing, the best subsets of descriptors in the learning methods were determined using a 5-fold cross-validation method. Significant differences in physico-chemical properties such as boiling point (BP), specific gravity (SG), Reid vapor pressure (rVP), flash point (FP), low explosion limit (LEL), and octanol/water partition coefficient (Pow) were observed between the single substances and the mixtures. The $EC_{50}$ of the mixture of DMF and TOL was significantly lower than that of DMF. The mixture toxicity was directly related to the mixing ratio of TOL and MEK (MLR $EC_{50}$ equation = $1.76997-1.12249{\times}TOL+1.21045{\times}MEK$), as well as to SG, VP, and LEL (MLR equation $EC_{50}=15.44388-19.84549{\times}SG+0.05091{\times}VP+1.85846{\times}LEL$). These results show that QSAR-based models can be used to quantitatively predict the toxicity of mixtures used in manufacturing industries.

• Applied Chemistry for Engineering
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• v.28 no.6
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• pp.714-719
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• 2017

The contaminated engine oil by fuel can intimidate driver safety due to vehicle problems such as engine abrasion, fire and sudden unintended acceleration. In this study, we investigate various functional properties of the engine oil contaminated with fuel. The test results indicated that the engine oil contaminated with fuel had relatively low values of the flash point, pour point, density, kinematic viscosity and cold cranking simulator. Furthermore, a four ball test suggested that the contaminated engine oil increased wear scar due to the poor lubricity. Moreover, SIMDIST (simulated distillation) using ASTM D2887 was applied to analyze fuel characteristics in an engine oil. The SIMDIST analysis result showed a lower carbon number, and the fuel was detected at an earlier retention time than that of using engine oil in chromatogram. Also, it is possible to quantitatively analyze for fuel contents in the engine oil. The SIMDIST method for the diagnosis of oil conditions can be used whether the fuel was involved or not, instead of analyzing other physical properties that require various analytical instruments, large volumes of oil samples, and long analysis time.

• Analytical Science and Technology
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• v.6 no.1
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• pp.65-75
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• 1993

A number of alternative cleaning solvents to CFC 113 which was identified as a ozone-depleting meterial were collected to measure their experimental physecal properties of density, surface tension, Refractive Index, boiling point, pH, viscosity, flash point, and soltbility. They might be classified as aqueous, simi-aqeous, alcohol ketone, and halogen cleaning solvents. The solubilities of abietic acid, a major component of flux used in PCB (Printed Circuit Board) of the electronic indystry, into the cleaning solvents including CFC 113 were determined for comparison. The assorted cleaning solvents have their own advantages and disadvantages. Therefore a end-user carefully needs to choose the best-fit cleaning solvent after the safety, stability, and economics as well as the effectiveness by physical properties of the alternative cleaning solvents are integratedly considered.

• Journal of the Korean Society of Marine Environment & Safety
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• v.13 no.1 s.28
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• pp.39-45
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• 2007

Recently it is a tendency that the heavy fuel oil is considered to be used on board even middle or small sized vessels in order to reduce the operating cost of vessel mused by a rise in international oil prices. In this study, analyzed the physical & chemical properties and examined the effect of refining treatment and a fuel oil additive for MF30 fuel oil which is a mixture fuel oil mixed M.G.O and the heavy oil MF380 use to be possible in the middle&small class vessel. As a results, the effects of two of pre-refinery treatment methods as centrifugal purifier and heating & homogenizing system(M.C.H) are some feeble, but the pour point and the flash point came to be low more or less. The effect of property improvement which is mused by the fuel oil additive did not appear positively.

• Journal of the Korean earth science society
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• v.24 no.3
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• pp.181-189
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• 2003

This study analyzes the results of thunderstorm data observed in the mid-western part of Japan during the winter of 1996-1997. There were 35 instances of thunderstorms with 4,426 instances of lightning detected during the observation period. This study estimates the frequency of lightning occurrence through classification of detected lightning into two types, and analyzes the relationship between lightning types and synoptic pattern. According to the analyzed results, cloud-to-cloud discharge and positive polarity occupied 78% and 42.3% of total discharge, respectively. It is rare for lightning to occur in the winter season, usually occuring during the night (midnight to 5 a.m.). Lightning frequently occurs when there is a prevailing synoptic wind from the norhwest. According to the analyzed results of multiplicity and multi-point lightning, the mean values of multiplicity and multi-point lightning are 1.4 and 1.2, respectively.

• Fire Science and Engineering
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• v.31 no.4
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• pp.1-6
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• 2017

A fire resistance certification needs to be obtained before fire protection paint can be used in Korea. In the case of paint, the tests for certification are fire, gas hazard and bond strength. According to the hazard test standard of combustion gas, 16 mice are sacrificed every test. Therefore, there are ethical problems for the experimenter and legal problems for the laboratory. Accordingly, many alternatives are being assessed, such as combustion gas analysis, but they have not replaced animal testing yet. With gas hazard testing, the exhaust gas temperature can be measured. The property of the initial reaction of a specific fire paint can be characterized by this temperature. The purpose of this study was to consider the improvement point for a gas hazard test through comparative analysis of the exhaust temperature and the time of death of the mice.