• Title/Summary/Keyword: Flash Point

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Calculation and Measurement of Flash Point for n-Decane + n-Octanol and Acetic Acid + n-Butanol Using a Tag-Open-Cup Apparatus (Tag 개방식 장치를 활용한 n-Decane + n-Octanol계 및 Acetic Acid + n-Butanol계의 인화점 측정과 계산)

  • Ha, Dong-Myeong;Lee, Sungjin
    • Fire Science and Engineering
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    • v.29 no.6
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    • pp.45-50
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    • 2015
  • The flash point is one of the most important properties for characterizing the fire and explosion hazard of liquid solutions. In this study, a Tag open-cup apparatus was used to measure the flash points of two flammable binary mixtures, n-decane + n-octanol and acetic acid + n-butanol. The flash point temperature was estimated using the UNIFAC (Universal Functional Activity Coefficient) group contribution model and optimization method. The experimentally derived flash point was also compared with the predicted flash point. The two methods can estimate the flash point fairly well for the n-decane + n-octanol and acetic acid + n-butanol systems.

The Measurement and Prediction of Maximum Flash Point Behavior for Binary Solution (이성분계 용액의 최대인화점 현상의 측정과 예측)

  • Ha, Dong-Myeong;Lee, Sungjin
    • Fire Science and Engineering
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    • v.27 no.5
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    • pp.70-74
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    • 2013
  • The flash point is one of the most important physical properties to charaterize fire and explosion hazard of liquid solutions. The maximum flash point of liquid mixture is larger than those of the individual components. In this study, the flash points of 2-pentanol+acetic acid system were measured by Seta flash closed cup tester. This system exhibited the maximum flash point behavior. The flash points were estimated by the Raoult's law and the optimization methods using the van Laar and Wilson equations. The calculated values by optimization methods were found to be better than those based on the Raoult's law.

Experimental Determination of Closed Cup Flash Point of Binary Flammable Solutions, 2-Propanol+Propionic acid and n-Hexanol+Formic Acid Solutions (가연성 이성분계 용액인 2-Propanol+Propionic acid 와 n-Hexanol+Formic acid 용액의 밀폐식 인화점의 실험적 결정)

  • Ha, Dong-Myeong;Lee, Sungjin
    • Journal of the Korean Institute of Gas
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    • v.19 no.3
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    • pp.18-24
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    • 2015
  • The flash point is one of the most important indicators of the flammabiliy of liquid solutions. The flash point is the lowest temperature at which there is enough concentration of flammable vapor to form an ignitable mixture with air. In this study the flash points of binary flammable solutions, 2-propanol+propionic acid and n-hexanol+formic acid systems, were measured using Seta flash closed cup tester. Particularly n-hexanol+formic acid system exhibited minimum flash point behavior. The measured values were compared with the calculated values using Raoult's law and optimization method. The calculated data by optimization method described the measured values more effectively than those calculated by Raoult's law.

The Lower Flash Points of the n-Butanol+n-Decane System

  • Dong-Myeong Ha;Yong-Chan Choi;Sung-Jin Lee
    • Fire Science and Engineering
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    • v.17 no.2
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    • pp.50-55
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    • 2003
  • The lower flash points for the binary system, n-butanol+n-decane, were measured by Pensky-Martens closed cup tester. The experimental results showed the minimum in the flash point versus composition curve. The experimental data were compared with the values calculated by the reduced model under an ideal solution assumption and the flash point-prediction models based on the Van Laar and Wilson equations. The predictive curve based upon the reduced model deviated form the experimental data for this system. The experimental results were in good agreement with the predictive curves, which use the Van Laar and Wilson equations to estimate activity coefficients. However, the predictive curve of the flash point prediction model based on the Willson equation described the experimentally-derived data more effectively than that of the flash point prediction model based on the Van Laar equation.

Estimation of the Flash Points for n-Propanol+Formic acid System Using the Binary Parameters Optimization Method (이성분계 파라미터 최적화 기법을 활용한 n-Propanol+Formic acid 계의 인화점 추산)

  • Ha, Dong-Myeong;Lee, Sung-Jin
    • Fire Science and Engineering
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    • v.22 no.4
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    • pp.65-69
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    • 2008
  • An accurate knowledge of the flash point is important in developing appropriate preventive and control measures in industrial fire protection. The lower flash points for the n-propanol+formic acid system were measured by Pensky-Martens closed cup apparatus. This binary mixture exhibited MFPB (minimum flash point behavior), which leads to the minimum on the flash point vs composition curve. The Raoult's law and optimization method using Wilson equation were used to predict the lower flash points and were compared with experimental data. The calculated values based on the optimization method were found to be better than those based on the Raoult's law.

The Evaluation of Hazard by Measurement of Combustible Characteristics of n-Tetradecane (노말테트라데칸의 연소특성치 측정에 의한 위험성 평가)

  • Ha, Dong-Myeong
    • Journal of the Korean Society of Safety
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    • v.27 no.5
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    • pp.70-76
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    • 2012
  • For the safe handling of n-tetradecane, the lower flash points and the upper flash point, fire point, AITs (auto-ignition temperatures) by ignition delay time were experimented. Also lower and upper explosion limits by using measured the lower and upper flash points for n-tetradecane were calculated. The lower flash points of n-tetradecane by using closed-cup tester were measured $104^{\circ}C$ and $112^{\circ}C$. The lower flash points and fire point of n-tetradecane by using open cup tester were measured $113^{\circ}C$ and $115^{\circ}C$, respectively. This study measured relationship between the AITs and the ignition delay times by using ASTM E659 apparatus for n-tetradecane. The experimental AIT of n-tridecane was $207^{\circ}C$. The calculated lower and upper explosion limit by using measured lower $104^{\circ}C$ and upper flash point $140^{\circ}C$ for n-tetradecane were 0.63 Vol.% and 3.18 Vol%.

The Measurement of Fire and Explosion Properties of n-Pentadecane (노말펜타데칸의 화재 및 폭발 특성치의 측정)

  • Ha, Dong-Myeong
    • Journal of the Korean Society of Safety
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    • v.28 no.4
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    • pp.53-57
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    • 2013
  • For the safe handling of n-pentadecane, the lower flash points and the upper flash point, fire point, AITs(auto-ignition temperatures) by ignition delay time were experimented. Also lower and upper explosion limits by using measured the lower and upper flash points for n-pentadecane were calculated. The lower flash points of n-pentadecane by using closed-cup tester were measured $118^{\circ}C$ and $122^{\circ}C$. The lower flash points and fire point of n-pentadecane by using open cup tester were measured $126^{\circ}C$ and $127^{\circ}C$, respectively. This study measured relationship between the AITs and the ignition delay times by using ASTM E659 apparatus for n-pentadecane. The experimental AIT of n-pentadecane was $195^{\circ}C$. The calculated lower and upper explosion limit by using measured lower $118^{\circ}C$ and upper flash point $174^{\circ}C$ for n-pentadecane were 0.54 Vol.% and 6.40 Vol.%.

A study on distinctions and successful elements of flash animation: Focused on distinctions of existing animation (플래시 애니메이션의 차별성 및 성공 요인에 관한 연구 - 기존 애니메이션과의 차별성을 중심으로)

  • Hong, Mi-Hee
    • Cartoon and Animation Studies
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    • s.6
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    • pp.172-190
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    • 2002
  • Flash animation occupied public attention since . It started to by payed attention through the internet first, and it spread into the off line. Flash animation becomes one of animation genre, as it tooks the place at the international animation festival. Also, as it is produced for tv, and the cinema, it has an infinite of possibilities. In this point, we have to notice that the domestic flash animation is the most successful in the world. Therefore, this paper will show accomplishment point and distinction of flash animation. Chapter 1, 2, will talk about basic outline and practical use of flash. Chapter 3 will look at a growth industry and process of flash animation, focused on Mashmaro, Zolaman, and Woobyboy. Chapter 4, will discuss about accomplishment point and distinction of flash animation compare with existing animation. Also it will conclude with a reflection on recommendations for further improvement.

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The Measurement of Flash Point for Unflammable-Flammable Binary Mixtures(CCl4+o-Xylene and CCl4+p-Xylene) Using Open Cup Tester (개방식 장치를 이용한 난연성-가연성 이성분계 혼합물(CCl4+o-Xylene and CCl4+p-Xylene)의 인화점 측정)

  • Kim, Chang-Seob;Lee, Sungjin;Ha, Dong-Myeong
    • Journal of Energy Engineering
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    • v.24 no.4
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    • pp.18-23
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    • 2015
  • The flash point is used to categorize inflammable liquids according to their relative flammability. The flash point is important for the safe handling, storage, and transportation of inflammable liquids. The flash point temperature of two binary liquid mixtures($CCl_4+o-xylene$ and $CCl_4+p-xylene$) has been measured for the entire concentration range using Tag open cup tester. The flash point temperature was estimated using Raoult's law, UNIQUAC model and empirical equation. The experimentally derived flash point was also compared with the predicted flash point. The empirical equation is able to estimate the flash point fairly well for $CCl_4+o-xylene$ and $CCl_4+p-xylene$ mixture.

Study on the Flash Point Determination of 2-Propanol-Toluene Mixtures (2-프로판올과 톨루엔 혼합물질의 인화점 측정에 관한 연구)

  • 목연수;최재욱;김영일;최일곤;하동명
    • Journal of the Korean Society of Safety
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    • v.12 no.3
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    • pp.114-119
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    • 1997
  • The lower flash points and upper flash points of 2-propanol and toluene mixtures were determined by air-blowing method instead of Tag-closed flash point tester. The relations between the flash points and the composition of the mixtures are as follows, $T_{F.L}=4.3182+6.0909X_1$ $T_{F.U}=39.3636-2.9091X_1$ As results, the experimental data and the estimated values from the relations are considerably agreed, and we could plotted the relative diagram between flash points and the explosive range.

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