• Journal of the Korean Institute of Gas
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• v.25 no.5
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• pp.1-10
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• 2021

Semiconductor Photo Resist (PR) automation equipment uses a mixture of several flammable substances, and when it leaks during the process, it can lead to various accidents, therefore, risk assessment is necessary. This study analyzed the frequency of leakage of Acetone and PGMEA used in PR automation equipment and the frequency at which such leakage could lead to a fire accident through the frequency analysis method, and evaluated the need for additional risk reduction measures in the current facility. Based on the process leak data and ignition probability data of IOGP, leak frequency analysis and ignition probability were derived, and the frequency of actual fire accidents was analyzed by combining them. The frequency of material leakage in semiconductor PR process is 7.30E-03/year, and fire accidents can occur by acetone that exists above the flash point when the material is leaked, the frequency was calculated at the level of 1.24E-05/year. According to the UK HSE, for a major accident occurring with a frequency of 1.24E-05/year, it is defined as "Broadly Acceptable", a level that does not require additional measures for risk reduction when it causes 7 or less deaths, and due to the process operated by two people, no additional risk reduction are required.

• Journal of the Korean Institute of Gas
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• v.28 no.1
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• pp.11-18
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• 2024

If flammable liquid leaks, vapor evaporated from the pool can cause poisoning or suffocation to workers, leading to secondary accidents such as fires and explosions. To prevent such damage, ventilation facilities shall be installed when designing indoor workplaces. At this time, the behavior varies depending on the characteristics of the leaked chemical, so it is necessary to select a suitable vent location according to the material. Therefore, 3D CFD simulations were introduced to derive optimal vent position and ventilation efficiency was quantitatively evaluated by vent position. At this time, assuming a situation in which flammable liquids leak at indoor workplaces to form pools, the concentration of vapor evaporated from pools was compared to derive the optimal vent position. As a result of research on toluene with high vapor density, ventilation efficiency was confirmed to be the highest at the upper supply-lower exhaust, and it is judged that introducing it can achieve about 3.7 times ventilation effect at the same maintenance cost. Through this study, it is expected that the workplace will be able to secure workers' safety by applying simulation results and installing ventilation ports.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 2008.11a
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• pp.262-269
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• 2008

Chemical products have had an favorable influence on our everyday life, and contributed very much to the development of human culture. According to the rapid change of industry and the development of scientific technique the using chemical products are increasing more and more. Chemical products can have any hazardous property such as flammability or explosiveness. There are occurring many accidents in the international trade due to the different classification and labelling of chemicals produced in various countries. The main purpose of this work is the development of global standard test methods for the chemicals, and the classification and labelling in building block approach by means of the basic technical data. Oxidizing solids, combustible solids, spontaneously combustible materials, water-prohibitive materials, flammable liquids, self-reactive materials and oxidizing liquids have been tested. The results have been classified according to the hazard material safety regulation and the UN regulation, and summarized in a data-base.

• Textile Coloration and Finishing
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• v.24 no.3
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• pp.204-212
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• 2012

This study was used a thermogravimetric analyzer to determine thermal characteristics, a hair analysis system to examine morphological changes of wefts-human hair, poly vinyl chloride(PVC) and polyethylene terephthalate (PET)-used in manufacturing wigs. According to a flammability test on human hair and synthetic wefts for wigs, the best results were observed in human hair. According to a thermal test, PET was the best in terms of thermal stability. Also good tensile strength was observed as well. In a scanning electron microscope observation, no human hair scale layer was found because of chemical treatment. In the PVC sample, homogeneous unevenness was observed. Due to a lack of human hair supply and increase in its price, recently, PET weft has emerged as a great substitution for human hair. Because it can be curled using an electric curling device and is more efficient than the conventional non-flammable material PVC in terms of thermal resistance, it will become the next-generation weft for wigs.

• Journal of the Korean Society of Safety
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• v.17 no.2
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• pp.69-75
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• 2002

Current fire safety in the construction sites has developed piecemeal over a considerable period of time. However, the law and regulation of fire safety is insufficient to protect fro in the construction sites. The frequency of fire in the construction sites is very rare but it brings longterm deterioration durability of building structure and large scale industrial calamity. There are many process of works and each work deals with many kind of flammable material, so it is very difficult to find a proper safety fire prevention. This study executed the questionnaire and fire experiment of the welding work to provide effective fire prevention counterplan.

• Korean Chemical Engineering Research
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• v.58 no.4
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• pp.610-617
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• 2020

In process installations, chemicals operate at high temperature and high pressure. Propylene is used as a basic raw material for manufacturing synthetic materials in the petrochemical industry; However, it is a flammable substance and explosive in the gaseous state. Thus, caution is needed when handling propylene. To prevent explosions, an inert gas, carbon dioxide, was used and the changes in the extent of explosion due to changes in pressure and oxygen concentration at 25 ℃, 100 ℃, and 200 ℃ were measured. At constant temperature, the increase in explosive pressure and the rates of the explosive pressure were observed to rise as the pressure was augmented. Moreover, as the oxygen concentration decreased, the maximum explosive pressure decreased. At 25 ℃ and oxygen concentration of 21%, as the pressure increased from 1.0 barg to 2.5 bar, the gas deflagration index (K_g) increased significantly from 4.71 barg·m/s to 18.83 barg·m/s.

• Journal of the Korea Safety Management & Science
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• v.12 no.1
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• pp.1-9
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• 2010

Recently, in circumstantial situation it is recommended positively to utilize of EIFS(Exterior Insulating and Finishing System) as energy policy for economizing energy. But internal EPS insulators of EIFS are exterior panel of high fire risk, because of constituting of flammable materials to be fragile in fire. In this study, fire risk is assessed by experiment Con Calorimeter test and SBI(Single Burning Item) test. As the result of experiment, Con Calorimeter tests do not reach to capability standard of internal incombustible grade, and are assessed as low grade in SBI incombustible grade. Because EIPS is exterior material in buildings with high fire risk in spite of good efficiency, it is required rapidly to take measures to meet situation through various studies(for instance, adjusting law regulation, etc.) in the future.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.27 no.4
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• pp.424-431
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• 2003

The evaporation cooling phenomenon of a droplet containing a surfactant on a heated surface has been studied experimentally. The two kinds of heater modules made of brass and Teflon$^{TM}$ were tested to investigate the cooling characteristics of droplet. Solutions of water containing Sodium Lauryl Sulfate(0 ppm, 100 ppm, 1000 ppm) were tested in the experiments. The results showed that the contact angle decrease as the concentration of surfactant increases. The tendency did not very with different heated solid materials. As initial temperature of the heated surface becomes high, time averaged heat flux increases and evaporation time decreases with the denser concentration of surfactant. Therefore, water with denser concentration of surfactant could be effective to cool flammable materials. However, the effect of surfactant becomes low as the material temperature is higher than the boiling temperature of water.

• Journal of the Korean Society of Tobacco Science
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• v.7 no.2
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• pp.169-178
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• 1985

In the previous paper, the kinetics of cellulose were described. In this study, the ability of some additives to act as a flame promoter for cellulose was investigated using dynamic thermogravimetry and differential scanning calorimetry. The treated cellulose was thermally decomposed through the two model as previously noted with the untreated cellulose. The first step was associated with the flaming combustion of volatile material released in the fraunentation process and the second was caused by the glowing combustion of carbonaceous residue. The first group of the additives, which could be divided into two groups by the pyrolytic mechanism of cellulose, appeared to catalyze the fragmentation, maximizing the degradation to produce tarry products, with gaseous flammable substrate. The heat evolved in flaming combustion mode was increased significantly by the treatment of the cellulose retained 1-5% of the first group additives.

• International Journal of Precision Engineering and Manufacturing
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• v.9 no.4
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• pp.63-65
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• 2008

The increased interest in reducing the environmental effects caused by releasing organic compounds and aqueous waste has motivated the development of polymeric materials in supercritical fluids. Recently, supercritical fluids have been used in material synthesis and processing because of their special properties, such as high diffusivity, low viscosity, and low surface tension. Supercritical carbon dioxide is the most attractive because it is non-toxic, non-flammable, and has moderate critical temperature and critical pressure values. Supercritical carbon dioxide can also swell most polymers. In this study, we prepared polymer/clay nanocomposites using supercritical fluids. Cloisites 10A, 15A, 25A, and 30B used in this study are montmorillonites modified with a quaternary ammonium salt. The nanocomposites of polymer/clay were characterized by X-ray diffraction, thermogravimetric analysis, and differential scanning calorimetry.