• Fire Science and Engineering
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• v.29 no.6
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• pp.45-50
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• 2015

The flash point is one of the most important properties for characterizing the fire and explosion hazard of liquid solutions. In this study, a Tag open-cup apparatus was used to measure the flash points of two flammable binary mixtures, n-decane + n-octanol and acetic acid + n-butanol. The flash point temperature was estimated using the UNIFAC (Universal Functional Activity Coefficient) group contribution model and optimization method. The experimentally derived flash point was also compared with the predicted flash point. The two methods can estimate the flash point fairly well for the n-decane + n-octanol and acetic acid + n-butanol systems.

• Journal of the Korea Safety Management & Science
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• v.19 no.3
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• pp.1-9
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• 2017

In the industrial field, various type of fuel have been used for product processing facilities. Recent for 10 years, the usage of natural gas (NG) was gradually increased. Because it has many merits; clean fuel, no transportation, storage facility and so on. There are common safety concept that strict explosion protection approaches are needed for facilities where explosive materials such as flammable liquid, vapor and gases exist. But some has an optimistic point of view that the lighter than air gases such as NG disperse rapidly, hence do not form explosion environment upon release into the atmosphere, many parts has a conventional safety point of view that those gases are also inflammable gases, hence can form explosion environment although the extent is limited and present. In this paper, the heating equipments (Hot Oil Heater) was reviewed and some risk management measures were proposed. These measures include hazardous area classification and explosion-proof provisions of electric apparatus, an early gas leak detection and isolation, ventilation system reliability, emergency response plan and training and so on. This study calculates Hazardous Area Classification using the hypothetical volume in the KS C IEC code.

• Journal of the Korean Society of Industry Convergence
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• v.22 no.2
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• pp.105-110
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• 2019

Most titanium alloy waste with cutting oil was discarded without recycling process so that it can be caused by metal and oil fires. However, there is no fire management system and studies on the titanium or titanium alloy waste in spite of high fire risk. The purpose of this experimental study is to identify the fire risk of the titanium alloy waste with cutting oil. We collected the 120g waste which was made in the biomedical titanium alloy cutting process. The waste was burned and conducted thermal image analysis with infrared camera. The experimental results which illustrated the process, characteristics, and trends of fire are presented. Firstly, the cutting oil was burned and partially the titanium alloy waste was burned. The maximum temperature of the fire was more than $650^{\circ}C$ in some specific spots. These results means when a lot of titanium alloy waste with cutting oil was ignited, this fire could connect the titanium fire. In other words, the fire has a flammable liquid fire and combustible metal fire at the same time. The experimental study could be used fire prevention, response, and investigation of the titanium alloy waste.

• Earthquakes and Structures
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• v.16 no.5
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• pp.523-532
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• 2019

Different types of gas reservoir such as Liquid Natural Gas (LNG) are among the strategic infrastructures, and have great importance for any government or their private owners. To keep the tank and its contents safe during earthquakes especially if the contents are of hazardous or flammable materials; using seismic protection systems such as base isolator can be considered as an effective solution. However, the major deficiency of this system can be the large deformation in the isolation level which may lead to the failure of bearing system. In this paper, as a solution, the efficacy of an optimally designed combined vibration control system, the combined laminated rubber isolator and rotational friction damper, is investigated to evaluate the enhancement of an existing metal tank response under both far- and near-field earthquakes. Responses like impulsive and convective accelerations, base shear, and sloshing height are studied herein. The probabilistic framework is used to consider the uncertainties in the structural modeling, as well as record-to-record variability. Due to the high calculation cost of probabilistic methods, a simplified structural model is used. By using the Mont-Carlo simulation approach, it is revealed that this combined isolation system is a highly reliable system which provides considerable enhancement in the performance of reservoir, not only leads to the reduction of probability of catastrophic failure of the tank but also decrease the reservoir damage during the earthquake. Moreover, the relative displacement of the isolation level is controlled very well by this combined system.

• International Journal of Advanced Culture Technology
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• v.11 no.3
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• pp.346-357
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• 2023

The purpose of this study is to suggest improvement plans for prevention regulations by reflecting the toxicity, fire and explosion effects of hazardous materials factories and surrounding areas using an off-site consequence assessment program. Regarding the effects of the hydrogen cyanide leak accident, which is the 1st petroleum of the 4th class flammable liquid, Areal Locations of Hazardous Atmospheres (ALOHA) program was used to compare and analyze the extent of damage effects for toxicity, overpressure, and radiation. As a result, the toxicity was analyzed to exceed 5km in the area with Acute exposure guideline level (AEGL)-2 concentration or higher, the overpressure was 103m in the range of 1 psi or more, and the radiant heat was analyzed to be 724m in the range of 2kw/m² or more. Toxicity and radiation affected the area outside the hazardous material storage area, but the overpressure was limited to the inside of the hazardous material storage area. Therefore, we propose to improve the safety management of hazardous materials by conducting a risk assessment for hazardous materials and reflecting the results in internal and external emergency response plans to prepare prevention regulations.

• Korean Chemical Engineering Research
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• v.61 no.1
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• pp.74-79
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• 2023

As the demand for hydrogen increases, the facilities for storing hydrogen has been important, and a few laws for hydrogen facilities should be complied. According to the Occupational Safety and Health Act in Korea, in case liquid hydrogen with a storage capacity of 5 tons or more is handled, a Process Safety Management (PSM) system should be complied. However, there are some standards which are not proper for flammable low-temperature liquefied substances on the current Occupational Safety and Health Act. In this study, 7 key points in process safey information and safety operation procedures among PSM components are suggested and how these key points should be improved is derived based on scientific analysis.

• Journal of Environmental Health Sciences
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• v.46 no.4
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• pp.423-432
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• 2020

Objectives: In this study, we analyzed the current state of delivery containers and packages and established handling guidelines to safely transport delivery containers and packages for use in research, testing, and examination reagents. Methods: Handling guidelines were revised in such categories as maintenance of the handling facilities, storage, loading and unloading, containers and packages, transportation, etc. In addition, we analyzed the current state of domestic sales for hazardous chemicals used for research, testing, and examination reagents, and investigated the handling guidelines related to delivery transportation in the USA, EU, and Japan by chemical property. Results: There are 6,160 companies selling hazardous chemicals. Among them, the 476 companies selling reagents for use in research, testing, and examination were investigated. Total amounts handled reached 425,000 tons, contributing to 0.2% of the total. For delivery transportation, internal containers and packaging was specified for chemical properties as follows: within 1 L for flammable gas, within 5 L for flammable liquid, and within 18 L for others. In addition, the maximum size of the outer package was set within 130 cm for total length, width, and height, and no dimension of the packaging could exceed 60 cm. Sixty-four hazardous chemicals with explosiveness or acute inhalation toxicity were prohibited for delivery transportation. Conclusion: Specified handling guidelines for inner and outer containers as well as packaging were regulated for delivery transportation of hazardous chemicals used for reagents. In addition, 64 hazardous chemicals were prohibited for delivery transportation. These are designed to prevent transportation accidents involving hazardous chemicals for reagents and thus protect the safety and health of transporters who handle hazardous chemicals.

• Journal of the Korean Society of Safety
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• v.35 no.1
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• pp.1-11
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• 2020

Article 325 (Prevention of Fire Explosion due to Electrostatic) of the Rule for Occupational Safety and Health Standard specifies that in order to prevent the risk of disasters caused by static electricity, fire, explosion and static electricity in the production process, However, in order to do this, it is absolutely necessary to use a pre-detection technology and a detector for antistatic discharge prediction, which is a precautionary measure by static electricity in a fire / explosion hazard place, but in Korea, And there is no technical standard for the application of the technology of the explosion proof structure of the related equipment. Research methods include domestic and overseas electrostatic discharge detection technology and literature investigation of related equipment explosion proofing technology, domestic and foreign electrostatic discharge detection device production and use situation investigation, advanced foreign technology data analysis and benchmarking. In particular, we sought to verify the results of empirical experiments using electrostatic discharge detection technology through sample purchase and analysis of related major products, development of optimization technology through prototype production, evaluation, and supplementation, and expert knowledge through expert consultation. The results of this study were developed and fabricated two prototypes of electrostatic discharge detector based on the technology / standard related to electrostatic discharge detection technology in Korea and abroad through development of electrostatic discharge detection technology and development and production of detector. In addition, based on the development of electrostatic discharge detection technology, we developed an intrinsic safety explosion proof ib class explosion proof technology applicable to the process of using and handling flammable gas and flammable liquid vapor and combustible dust. In the case of the over voltage and minimum voltage are supplied to the explosion-proof structure ESD detector, check the state of the circuit and the transient and transient currents generated by the coil and capacitor elements during the input and standby of the signal pulse voltage. Explosion-proof equipment-Part 11: Intrinsically safe explosion proof structure The comparative evaluation with the reference curve in Annex A of "i" confirms that the characteristics of the intrinsically safe explosion protection structure are met.

• Fire Science and Engineering
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• v.15 no.4
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• pp.41-48
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• 2001

Halogen-based fire suppressing agents have been the most effective fire suppressants and widely used for flammable liquid and electric fire. However they have environmental problems causing stratospheric ozone depletion and globe warming. As a substitution of halon, fire suppression system using fine water mist is one of an effective fire suppressant. Suffocating and cooling effects of water mist are increased by the evaporation characteristics because it has droplet size less than 1,000 $\mu{m}$ and very large surface area. In this study, the extinguishing characteristics of fire was measured with changing of water mist droplet size, flow density; discharge pressure, and fire size. As a result, the extinguishing time of pool fire was shortened with the increase of flow density and in case of low flow density less than 0.5$\pm$0.05 ml/$\textrm{cm}^2$ . min, the extinguishing time was shortened with the increase of droplet size. The cycling discharge was effective for $\eta$-heptane pool fire, and total amount of water mist required to extinguish fire was reduced to a quarter compare with continuous discharge.

• Korean Chemical Engineering Research
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• v.52 no.6
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• pp.755-767
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• 2014

Chlorine is one of the most produced and most used non-flammable chemical substances in the world even though its toxicity and high reactivity cause the ozone layer depletion. However, in modern life, it is impossible to live a good life without using Chlorine and its derivatives since they are being used as an typical ingredient in more than 40 percent of the manufactured goods including medicines, detergents, deodorant, fungicides, herbicides, insecticides, and plastic, etc. Even if Chlorine has been handled and distributed in various business (small and medium-sized businesses, water purification plants, distribution company, etc.), there have been few researches about its possible health hazard and transportation risks. Accordingly, the purpose of this paper is to make a detailed assessment of Chlorine-related risks and to model an index of chemicals transportation risks that is adequate for domestic circumstances. The assessment of possible health hazard and transportation risks was made on 13 kinds of hazardous chemicals, including liquid chlorine. This research may be contributed to standardizing the risk assessment of Chlorine and other hazardous chemicals by using an index of transportation risks.