• Title/Summary/Keyword: Flameless

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Numerical Investigation on the Thermal Characteristics of Mild Combustion According to Co-axial Air (동축공기에 따른 Mild 연소의 열적 특성에 대한 수치연구)

  • Hwang, Chang-Hwan;Baek, Seung-Wook;Kim, Hak-Young
    • Journal of the Korean Society of Combustion
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    • v.15 no.4
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    • pp.1-8
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    • 2010
  • Mild combustion is considered as a promising combustion technology for energy saving and low emission of combustion product gases. In this paper, the controllability of reaction region in mild combustion is examined by using co-axial air nozzle. For this purpose, numerical approach is carried out. Propane is considered for fuel and air is considered for oxidizer and the temperature of air is assumed 900K slightly higher than auto ignition temperature of propane. But unlike main air, the atmospheric condition of co-axial air is considered. Various cases are conducted to verify the characteristics of Co-Axial air burner configuration. The use of coaxial air can affect reaction region. These modification help the mixing between fuel and oxidizer. Then, reaction region is reduced compare to normal burner configuration. The enhancement of main air momentum also affects on temperature uniformity and reaction region. The eddy dissipation concept turbulence/chemistry interaction model is used with two step of global chemical reaction model.

Studies on the Contents of Trace Metals in Crude Drugs (시판생약(市販生藥)의 미량금속(微量金屬) 함량(含量)에 관(關)한 연구(硏究))

  • Park, Chae-Joo;Yang, Ki-Sook
    • Korean Journal of Pharmacognosy
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    • v.8 no.2
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    • pp.61-68
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    • 1977
  • The content of micro inorganic compounds in the 145 kinds of crude drugs on market was determined with Model 207 Atomic Absorption Spectrophotometer and Model 306 Flameless A.A. Content of Fe, Cu, Ni, Mn, Cd, Cr, Sn, and Pb was examined and the results revealed that the crude drugs which are using as a hematics and emmenagogues contained high content of iron, and those which are using as a antiinflammatory and emmenagogues contained high content of copper. Aromatic stomachics contain manganese and zinc, and diuretics and antiinaflammatory agents do tin. High content of Ni was found in tonics, but chronium and cadmium were not detected in crude drugs. There were no differences of content of trace metals in the various site of plants used.

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A Study on Characteristics of Mild Combustion using the Radiative Flamelet Model (비단열 화염편 모델을 이용한 Mild Combustor의 연소특성 해석)

  • Kim Gunhong;Kim Yongmo;Ahn Kookyoung
    • Transactions of the Korean Society of Automotive Engineers
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    • v.13 no.1
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    • pp.60-67
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    • 2005
  • Mild combustion or Flameless oxidation(FLOX) have been considered as one of the most prospective clean-combustion technologies to meet both the targets of high process efficiency and low pollutant emissions. A mild combustor with high air preheating and strong internal exhaust gas recirculation is characterized by relatively low flame temperature, low NOx emissions, no visible flame and no sound. In this study, the Steady Flamelet Approach has been applied to numerically analyze the combustion processes and NOx formation in the mild combustor. The detailed discussion has been made f3r the basic characteristics of mild combustor, numerical results and limitation of the present combustion modeling.

Studies on the Germanium Components of Zingiberis Rhizoma (생강중 게르마늄 성분에 관한 연구)

  • 백남호;박만기;최승호;문동철
    • YAKHAK HOEJI
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    • v.25 no.4
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    • pp.193-197
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    • 1981
  • Germanium (Ge) content in Zingiberis Rhizoma was determined by flameless atomic absorption spectrometry with a graphite tube atomizer. The Ge content of the cortical layer was 65.mu.g/g, the central cylinder, $98\mu$g/g and the total, $87\mu$g/g. In the effect of the extraction of Ge by various solvents, polar solvent was more effective than the nonpolar one, Especially, water was the most effective solvent. The water extract of Zingiberis Rhizoma, separated by sephadex G-25 gel filtration, was fractionated into 2 peaks at 254nm. Both the peaks showed atomic absorptions of Ge. It may be concluded that the Ge components of Zingiberis Rbizoma exist as the form of an aqueous organic compounds or associated forms with proteins.

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Determination of Li generated from 10B(n·α)7Li reaction in Boric acid solution (붕산수용액에서 10B(n·α)7Li 핵반응에 의해 생성된 Li 정량)

  • Choi, Ke-Chon;Jung, Yongju;Yoon, Jei-Won;Kim, Won-Ho
    • Analytical Science and Technology
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    • v.16 no.6
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    • pp.443-449
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    • 2003
  • Thermal neutron irradiation experiment of boric acid solution was carried out using HANARO in following three conditions: (A) $^{10}B$ concentration = $203.0{\mu}g/mL$, irradiation time = 1 hr; (B) $^{10}B$ concentration = $381.4{\mu}g/mL$, irradiation time = 1 hr; (C) $^{10}B$ concentration = $381.4{\mu}g/mL$, irradiation time = 0.5 hr. The amount of lithium produced from $^{10}B(n{\cdot}{\alpha})^7Li$ reaction which was generated on neutron irradiation, was measured by flameless atomic absorption spectroscopy. The concentration of $^7Li$ measured in the three experiments was $0.18{\mu}g/mL$ (78.3% of theoretical value, $0.23{\mu}g/mL$) in (A), $0.31{\mu}g/mL$ (70.5% of theoretical value, $0.44{\mu}g/mL$) in (B) and $0.16{\mu}g/mL$ (71.6% of theoretical value, $0.22{\mu}g/mL$) in (C). The pH value of irradiated boric acid was shifted to considerably low. It is estimated that boric acid would be transformed into the polyborate fonn, by radiolysis products of water, which has high dissociation constant.

Pretreatment Effect on the Analysis of Insoluble Hexavalent Chromium (전처리방법에 따른 불용성 6가 크롬 분석에 관한 연구)

  • Lee, Eun Jung;Roh, Jae Hoon;Won, Jong Uk;Chun, Mi Ryonng;Cho, Myung Hwa;Kim, Chi Nyon
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.6 no.2
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    • pp.292-300
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    • 1996
  • Hexavalent chromium($Cr^{+6}$) compounds are considered to be particularly hazardous, primarily because of the associated risk of allergic reaction and cancer. The analytic method of hexavalent chromium such as the s-diphenylcarba-zide(DPC) method and all ether previously used methods are often made uncertain due to significant interferences from organic components. This report can provide a technique for the more rapid and simple determination of total hexavalent chromium. than other currently using methods. The s-diphenylcarbazide method proposed by the U.S. National Institute for Occupational Safety and Health has low recovery rate(15.67 - 48.20%) due to interference, iron chloride and nickel chloride. A microwave oven technique has high recovery rate(about 70%) of insoluble hexavalent chromium. For the difference of ionic charges of $Cr^{+3}$-ethylenediamine tetraacetic acid(EDTA) chelate and $CrO_4{^{-2}}$, we could detect them simultaneously by ion exchanged high performance liquid chromatography. The confirmation of $Cr^{+3}$ and $Cr^{+6}$ were checked by fraction collector and flameless atomic absorption spectrometer. We observed that the small amount of hexavalent chromium is converted to trivalent chromium due to enhancement of chromium reduction by $Fe^{+3}$ or $Ni^{+2}$. As a result of this study, on the analysis of insoluble hexavalent chromium with microwave oven was used for, it may be better and more precise analysis after pretreatment by 2% NaOH-3% $Na_2CO_3$ and then analysis UV-spectrophotometer. It should be done for various studies on insoluble hexavalent chromium on the basis work environmental monitoring so called welding, painting etc.

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Investigation on Combustion Characteristics of Pressurized Oxy-fuel Combustion System using Low Calorific Value Syngas (저열량 합성가스를 이용한 가압 순산소 연소 시스템의 연소 특성 분석 연구)

  • Kim, Dong-hee;Lee, Young-jae;Yang, Won
    • Journal of the Korean Society of Combustion
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    • v.21 no.4
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    • pp.39-47
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    • 2016
  • The aims of this research were to investigate combustion characteristics of lab-scale pressurized oxy-fuel combustion(POFC) system. In this study, the reactor, 800 mm long, was equipped with co-axial burner. Low calorific value syngas that is composed of mainly CO and $H_2$ was used as fuel whereas pure oxygen was used as an oxidant. Thermal heat input to the reactor varied from 2.6 kW to 6.1 kW. The reactor pressure also increases from atmospheric up to 15 bar. The results show that as the pressure increase, the temperature of reactor decreases on the whole in all cases. A significant temperature drop was observed especially at the bottom section of the reactor that exist flame. In addition, the flame instability increases as the pressure increases. Furthermore $NO_x$ emissions increases from atmospheric up to 2 bar. However beyond 2 bar, $NO_x$ emission reduces as pressure increases. Lastly $NO_2$ ratio in $NO_x$ also increases as pressure increases.

Experiment on the Characteristics of Jet Diffusion Flames with High Temperature Air Combustion (고온공기를 이용한 제트확산화염의 연소특성에 관한 실험)

  • Cho, Eun-Seong;Ohno, Ken;Kobayashi, Hideaki;Chung, Suk-Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.3
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    • pp.359-364
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    • 2004
  • For the development of high efficiency and low emission combustion systems, high temperature air combustion technology has been tested by utilizing preheated air over 1100 K and exhaust gas recirculation. In this system, combustion air is diluted with large amount of recirculated exhaust gases, such that the oxygen concentration is relatively low in the reaction zone, leading to low flame temperature. Since, the temperature fluctuations and sound emissions from the flame are small and flame luminosity is low, the combustion mode is expected to be flameless or mild combustion. Experiment was performed to investigate the turbulent flame structure and NO$_x$ emission characteristics in the high temperature air combustion focused on coflowing jet diffusion flames which has a fundamental structure of many practical combustion systems. The effect of turbulence has also been evaluated by installing perforated plate in the oxidizer inlet nozzle. LPG was used as a fuel. Results showed that even though NO$_x$ emission is sensitive to the combustion air temperature, the present high temperature air combustion system produce low NO$_x$ emission because it is operated in low oxygen concentration condition by the high exhaust gas recirculation.

Study on the Precision in Determinations of Lead and Zinc in the Whole Blood (혈중 연 및 아연 분석의 정도에 관한 연구)

  • Park, Jung-Duck
    • Journal of Preventive Medicine and Public Health
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    • v.19 no.1 s.19
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    • pp.76-84
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    • 1986
  • Analyses of lead and zinc were made by means of standard addition method using atomic absorption spectrophotometer(Baird Ltd., Model A5100) with flameless method for lead and flame method for zinc. The blood samples used were merely diluted with triton x-100, because it was simple, rapid and minimal risk of contamination. Mean recovery rate for lead added to the blood ranged from 97.7 to 101.3% with coefficient of variation ranging from 1.9 to 10.7%, and that for the added zinc ranged from 99.0 to 102.2% with coefficient of variation ranging from 2.1 to 9.1%. In repeated measurements of zinc in the blood, good reproducibility and interindividual variation were proved(p<0.01). In comparison of the lead and zinc concentrations in the blood determined by the standard addition method and standard method, there were good correlations between 2 sets of data (r=0.9731 for lead and r=0.9785 for zinc), although lead levels were estimated higher by the former method(p<0.01) and zinc levels by the latter method(p<0.01). It can be concluded that lead and zinc levels in blood standard addition method is reliable for determination of lead and zinc in the blood with good accuracy and reproducibility.

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An Experimental Study of the Characteristics with High Temperature Air Combustion in Jet Diffusion Flames (제트확산염의 고온공기연소특성에 관한 실험적 연구)

  • Cho, Eun-Seong;Ohno, Ken;Kobayashi, Hideaki;Chung, Suk-Ho
    • 한국연소학회:학술대회논문집
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    • 2003.12a
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    • pp.89-94
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    • 2003
  • For the development of high efficiency and low emission combustion systems, high temperature air combustion technology has been tested by utilizing preheated air over 1100 K and exhaust gas recirculation. In this system, combustion air is diluted with large amount of exhaust gases ($N_2$, $CO_2$), such that the oxygen concentration is relatively low in the reaction zone, leading to low flame temperature. Since, the temperature fluctuations and sound emissions form the flame are small and flame luminosity is low, the combustion mode is expected to be flameless or mild combustion. Experiment was performed to investigate the turbulent flame structure and $NO_X$ emission characteristics in the high temperature air combustion focused on coflowing jet diffusion flames which has a fundamental structure of many practical combustion systems. The effect of turbulence has also been evaluated by installing perforated plate in the oxidizer inlet nozzle. LPG was used as a fuel. Results showed that even though $NO_X$ emission is sensitive to the combustion air temperature, the present high temperature air combustion system produce low $NO_X$ emission because it is operated in low oxygen concentration condition in excess of dilution.

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