• 한국전기전자재료학회논문지
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• 제35권5호
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• pp.494-498
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• 2022

In this study, SiO₂ 20 phr, ATH 70 phr, and platinum flame retardant were mixed with raw silicone rubber and -10 kV was applied to measure electrostatic charge attenuation voltage, surface resistance, and volume resistance, and the following conclusions were obtained. When the platinum flame retardant was 0 phr, the humidity 74.6% and the temperature was 21.8℃, the potential was half-reduced to 0.63 kV, 0.57 kV, and 0.44 kV when the applied voltage was changed from -10 kV to -8 kV, and the time halved to 50% was increased to 2.40 seconds, 2.47 seconds, and 2.61 seconds. It was confirmed that as the platinum flame retardant increased from 0.1 to 0.3 phr, the potential half-reduced to 0.67 kV, 0.60 kV, and 0.595 kV decreased, and the charge potential attenuation time half-reduced to 50% decreased to 3.44 seconds, 1.78 seconds, and 1.60 seconds. It was confirmed that the surface resistance increased as the humidity decreased, and the volume resistance decreased as the platinum flame retardant increased.

• 한국염색가공학회지
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• 제34권4호
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• pp.217-223
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• 2022

Flame-retardant finished silk fabrics could release carcinogenic formaldehyde resulting from the conventional finishing agents. New water-soluble cyclophosphazene derivative can be used as a formaldehyde-free flame retardant for the silk protein. Dichloro tetrakis{N-[3-dimethylamino)propyl]methacrylamido}cyclophosphazene(DCTDCP) can be cured by heat or UV irradiation as a durable flame retardant for the silk fabrics. Treatment conditions were optimized including curing temperature and time, finishing formulations, and UV energy. At the 30% DCTDCP application, peak HRR and THR decreased by 42.6% and 49.6% respectively compared to the pristine silk fabrics. Also char residue increased up to 48% from 11% indicating solid-phase retarding mechanism. The flame-retardant silk fabrics showed a LOI of 31.1 and the washed sample maintained a LOI of 26.8 even after ten laundering cycles.

• 한국염색가공학회지
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• 제2권4호
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• pp.251-256
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• 1990

Bis-(p-bromopheny)phosphate(BBPP) , which serves as flame retardant for PET fabric, was synthesized from phenol and phosphorus oxychloride, and from bromine. In order to investigate the flame retardancy of BBPP, PET fabrics were steam-cured with diluted BBPP solution. The following conclusions were drawn : 1. Flame retardancy of PET fabrics treated with BBPP was excellent, and optimal treating condition was 10% concentration of flame retardant at $170^{\circ]C$ 2. Clark softness and tensile strength before and after the laundering of PET fabrics treated with flame retardant remained nearly unchanged.

• 한국응용과학기술학회지
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• 제20권2호
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• pp.110-117
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• 2003

Pyrophosphoric modified polyesters (TATBs) were synthesized by polycondensation of adipic acid, trimethylolpropane, 1,4-butanediol, and tetramethylene bis(orthophosphate). Two-component PU flame-retardant coatings (TATBCs) were prepared by blending TATBs with HDI-Biuret. Most of the physical properties of the flame-retardant coatings were comparable to those of non-flame-retardant coatings. Coatings containing 10 and 15wt% 1,4-butanediol, TATBC-10C and TATBC-15C were not flammable in the vertical flame-retardancy test.

• 한국응용과학기술학회지
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• 제17권3호
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• pp.203-211
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• 2000

Pyrophosphoric lactone modified polyester(PATT) that contains two phosphorous functional groups in one unit base resin structure was synthesized to prepare a non-toxic reactive flame retardant coatings. Then the PATT was cured at room temperature with isocyanate, Desmodur IL, to get a two-component polyurethane flame retardant coatings(PIPUC). Comparing the physical properties of the films of PIPUC with the film of non-flame retardant coatings, there was no degradation observed in physical properties by the introduction of a flame-retarding component into the resin. We found that the char lengths measured by $45^{\circ}$Meckel burner method were $3.1{\sim}4.4cm$ and LOI values recorded $27{\sim}30%$. These results indicate that the coatings prepared in this study is good flame retardant one. The surface structure of coatings investigated with SEM does not show any defects and phase separation.

• Bulletin of the Korean Chemical Society
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• 제35권11호
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• pp.3249-3253
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• 2014

A novel triazole-functionalized phenolic resin was developed, and its thermal and flame-retardant properties were investigated. The triazole group was incorporated as a pendant unit on the phenolic resin via copper-mediated click chemistry between propargylated phenolic resin and benzyl azide. The newly-developed triazole-functionalized phenolic resin showed higher thermal stability and char yield, together with a reduced total heat release (THR), than the non-functionalized bare phenolic resin, indicating enhanced flame retardancy for the triazole-functionalized phenolic resin.

• 폴리머
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• 제25권3호
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• pp.391-398
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• 2001

난연성분인 트리브로모아세트산의 함량을 10, 20, 30wt%로 변화시키면서 1,4-부탄디올, 아디프산 및 트리메틸올프로판과 축합중합을 하여 트리브로모 변성폴리에스테르(TBAO)를 합성한 후에, TBAO류와 이소시아네이트를 블렌드하여 2성분계 폴리우레탄(PU) 난연도료를 제조하였다. 제조된 난연도료의 도막물성을 측정한 결과, 결코 비난연도료보다 물성이 저하되지는 않았다. 또한 난연도료의 난연성 시험결과, 수직법에서 트리브로모아세트산 20 wt%에서 불꽃에 타지 않아서 양호한 난연도료임을 알 수 있었다.

• 한국화재소방학회논문지
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• 제31권3호
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• pp.11-18
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• 2017

본 연구에서는 건축물 내에 사용되는 실내장식물의 가연성으로 인해 화재 시 발생하는 연기로 인한 인명피해를 사전에 예방하기 위해 무기물의 실리케이트와 유기물의 실란커플링제를 졸-겔법으로 합성하여 방염성을 부여할 수 있는 비할로겐 방식의 유-무기 하이브리드 방염제졸을 새롭게 제조하였다. 제조된 방염제졸의 성능확인을 위해 방염성능기준에 의거한 연기밀도 측정기준인 ASTM E 662의 시험장치 및 절차에 따라 훈소모드 실험 및 불꽃모드 실험을 진행하여 성능을 확인하였다. 결과적으로 제조된 방염제졸은 기존의 방염제의 물성과 내열성능을 높여 화재 시 연기발생량을 감소시킬 수 있기 때문에 향후 다양한 실내장식물에서도 확대적용 함으로써 연기에 의한 피해에 있어 긍정적인 효과를 발휘할 것으로 생각된다.

• 한국화재소방학회논문지
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• 제30권3호
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• pp.67-72
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• 2016

본 연구에서는 최근 사회적으로 이슈가 되고 있는 다중이용시설의 화재 시 건축자재로 사용되는 내장재의 가연성으로 인한 화재확산 및 연소 시 유독가스 발생으로 인한 인명피해를 사전 예방하기 위한 방염제를 개발하고자 한다. 유-무기 하이브리드 소재로 실리카 졸에 방염성을 부여할 수 있는 방염 소재를 적용하여 졸-겔법에 의한 방염 접착제 또는 코팅제를 제조하였다. 기존의 방염소재는 물론 비방염소재의 방염화를 비할로겐 방법으로 적용가능하며, 기존의 접착 코팅제의 기본 물성과 특히 내열성능을 높여 화재 시 내열성 및 내구성을 향상시킬 수 있기 때문에 건축자재의 비할로겐 방염화를 확대하고자 한다.

• 공업화학
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• 제27권6호
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• pp.577-582
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• 2016

본 연구에서는 새로운 비할로겐-인계 난연제를 포함하는 경질 폴리우레탄 폼[BHP-RPUF]과 할로겐-인계 난연제를 포함하는 경질 폴리우레탄 폼[TCPP-RPUF] 그리고 난연제를 포함하고 있지 않은 폴리우레탄 폼[Pure-RPUF]의 기계적 물성 및 난연 특성에 대해 비교 분석하였다. 새로운 비할로겐-인계 난연제인 bis(3-(3-hydroxypropoxy)propyl) phenyl phosphate [BHP]는 disodium phenyl phosphate와 3-chloro-1-propanol의 반응을 통해 합성하였다. BHP-RPUF, TCPP-RPUF, 그리고 Pure-RPUF의 압축강도는 BHP-RPUF와 TCPP-RPUF가 비슷한 압축강도를 나타내었고, 열전도도에서는 BHP-RPUF가 TCPP-RPUF보다 낮은 값인 $0.023W/m{\cdot}K$를 갖는 것을 확인하였다. 반응속도와 SEM을 통해 기공의 크기를 측정하여 열전도도에 미치는 영향에 대하여 분석하였고, TGA 분석을 통해 내열성을 확인하였다. 난연성은 한계산소지수(Limited Oxygen Index) 측정 실험을 통하여, Pure-RPUF보다 BHP-RPUF에서 난연성이 향상됨을 확인하였다.