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http://dx.doi.org/10.5012/bkcs.2014.35.11.3249

Synthesis of Triazole-functionalized Phenolic Resin and its Inherent Flame Retardant Property  

Poduval, Mithrabinda K.K. (Organic Material Synthesis Laboratory, Department of Chemistry, Incheon National University)
Kim, Tae-Hyun (Organic Material Synthesis Laboratory, Department of Chemistry, Incheon National University)
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Abstract
A novel triazole-functionalized phenolic resin was developed, and its thermal and flame-retardant properties were investigated. The triazole group was incorporated as a pendant unit on the phenolic resin via copper-mediated click chemistry between propargylated phenolic resin and benzyl azide. The newly-developed triazole-functionalized phenolic resin showed higher thermal stability and char yield, together with a reduced total heat release (THR), than the non-functionalized bare phenolic resin, indicating enhanced flame retardancy for the triazole-functionalized phenolic resin.
Keywords
Phenolic resin; Flame-retardant polymer; Char yield; Thermal properties; Triazole;
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