• 한국화재소방학회논문지
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• 제25권2호
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• pp.95-100
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• 2011

본 연구는 현장방염처리 물품에 대한 성능검사와 관련하여 불합리한 제도를 개선하고, 합리적인 방염성능검사 방법을 통하여 현장방염처리 물품에 대한 방염의 신뢰성을 확보하는데 궁극적인 목적이 있다. 이를 위해 최근 2년 동안 일선 소방관서에서 실시한 현장방염처리 물품에 대한 방염성능검사 실적을 토대로 최근에 사용되는 인테리어 마감자재 및 현장방염처리 경향에 대한 분석을 하였다. 또한 현장방염처리물품에 대한 성능검사 방법 및 절차, 방염처리업 등록제도의 문제점 등을 분석하여 현 실정에 적합한 방염성능검사 방법 및 성능검사의 신뢰성 확보를 위한 개선방안을 제시하고자 하였다.

• 한국화재소방학회논문지
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• 제16권4호
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• pp.65-71
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• 2002

무기계 난연제로 널리 사용되고 있는 aluminum trihydrate와 antimony trioxide의 첨가에 의한 열화거동과 난연효과를 열분석 및 화염특성시험(LOI test, flammabilty을 45 degree test)을 통하여 알아보았다. 일반 구조용 glass fiber/unsaturated polyester 복합재료 제조 시 난연 조성에 따른 난연 효과와 기계적 특성(경도, 인장강도, 탄성률) 변화를 조사하였다. 항공우주용 구조에 사용되는 난연 처리된 glass fiber/epoxy prepreg 복합재료 제조 시 공정조건에 따른 난연 특성을 비교 분석하였다. 실험결과를 이용하여 난연제의 난연 기구 및 기계적 물성을 고려한 최적 난연 조성은 ATH의 경우 10∼20 phr이였으며, autoclave 공정압력이 증가할수록 높은 LOI 값을 보였다.

• 한국안전학회지
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• 제33권4호
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• pp.15-20
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• 2018

In this study, we have performed the Cone Calorimeter test and Smoke density test in accordance with ISO 5660-1 and ASTM E662 respectively to check the smoke production characteristics of rubber flooring materials for railway vehicle. Early in the ASTM E662 test, more smoke was produced in the flame mode test than non-flame mode test, but later more smoke was produced in non-flame mode test. The correlation($R^2$) between TSR(Total Smoke Release) by ISO 5660-1 and Ds(Specific Optical Density) by ASTM E662 Flame mode was 0.782. The $R^2$ between TSR by ISO 5660-1 and Ds by ASTM E662 Non-flame was 0.930.

• 한국응용과학기술학회지
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• 제25권3호
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• pp.332-340
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• 2008

Two component polyurethane (PU) flame retardant coatings were prepared by blending trichloro modified polyesters (TCMPs) and isophorone diisocyanate isocyanurate. TCMPs were synthesized by polycondensation of trichlorobenzoic acid (TCBA), a flame retardant component, with adipic acid, 1,4 butanediol, and trimethylolpropane. The content of TCBA was varied in 10, 20, and 30 wt% for the reaction. Theses new flame retardant coatings showed various properties comparable to other non flame retardant coatings. Moreover, we carried out the combustion test and the flammability test for our flame retardant coatings. The results of vertical burning test for the coatings containing more than 20 wt% of TCBA were determined as no burn. The results of flammability test for the coatings with 20 wt% and 30 wt% of TCBA contents indicated the limiting oxygen index (LOI) values of 26% and 29% respectively, which implied relatively good flame retardancy.

• 한국가스학회지
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• 제19권5호
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• pp.36-40
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• 2015

본 연구에서는 소형(1L 미만) 재충전 가능 프로판 용기의 안전성을 향상시키기 위하여, 화염 노출 시나리오에 대한 실험을 실시하였다. 화염에 노출된 용기는 내부 프로판의 액팽창에 의해 내압이 급격히 상승하게 되어 파열의 가능성이 존재한다. 따라서 내부의 과압을 해소시키기 위한 열 감응식 안전밸브를 부착하여, 용기가 파열되지 않고 내부 프로판을 외부로 분출하도록 유도하였다. 용기를 감싼 화염의 온도는 평균 $600^{\circ}C$였으며, 안전밸브를 통해 분출되는 프로판이 2차 연소를 유발하여 최대 $700^{\circ}C$까지 상승하였다. 그 결과 용기의 변형은 발생하였지만, 파열은 일어나지 않았다. 프로판용 압력용기의 화염시험 규정이 존재하지 않는 만큼, 화염에 노출 가능성이 존재하는 레저용 용기에 대한 선행연구로써, 본 연구의 결과는 추후 프로판 압력용기의 성능 평가에 있어 중요한 자료가 될 것으로 기대한다.

• 한국안전학회지
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• 제28권6호
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• pp.17-22
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• 2013

The production of flame-retardant polypropylene powder coating with the addition of flame retardant (PP) controlled rheology (CR) and polypropylene, were discussed comparing the mechanical properties, such as safety and topical coating properties. Mechanical properties measurements showed almost the same as AA-1 where the flame retardant is not added. These results appear to, and because it is excellent in compatibility with polypropylene and flame retardant. Physical properties of the coating film, a test piece flame retardant organic is added, although it shows the physical properties of the coating film was stable, did not show the physical properties satisfactory is the test piece flame retardant of weapons has been added. In the safety of the topic, AA-4, AA-5 the results of thermal analysis but it is excellent, the LOI is excellent in 27.8 vol% 27.0 vol% in AA-4 and AA-2, AA-3, and 27.4 vol%, did not show many obstacles flame AA-5 result UL94.

• Elastomers and Composites
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• 제55권1호
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• pp.40-45
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• 2020

In this study, the mechanical and flame-retardant properties of ethylene-propylene-diene-termonomer (EPDM) based rubber compounds and various other environmentally friendly inorganic flame retardants were investigated. Alumina trihydrate (ATH) and magnesium hydroxide (MDH) were used as inorganic flame retardants. The mechanical properties after thermal oxidation aging and the flame-retardant properties of the EPDM compounds were measured using a moving die rheometer, a universal testing machine, a compression set, and a UL 94 V flammability test. We focused on how the properties were affected by the type and amount of flame retardants. The results demonstrated that the optimal mechanical and flame-retardant V-0 grade properties were obtained at an ATH content of 200 phr.

• 한국응용과학기술학회지
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• 제17권4호
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• pp.240-247
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• 2000

Two-component polyurethane flame-retardant coatings were prepared by blending trichloro aromatic modified polyesters(TCMPs) and polyisocyanate. TCMPs were synthesized by polycondensation of trichlorobenzoic acid(TCBA), a flame-retardant component, with adipic acid, 1,4-butanediol, and trimethylolpropane. The content of TCBA was varied in 10, 20, and 30 wt% for the reaction. These new flame-retardant coatings showed various properties comparable to other non-flame-retardant coatings. Moreover, we carried out the combustion test and the flammability test for our flame-retardant coatings. The results of vertical burning test for the coatings containing more than 20 wt% of TCBA were determined as 'no burn'. The results of flammability test for the coatings with 20 wt% and 30 wt% of TCBA contents indicated the limiting oxygen index(LOI) values of 25% and 28% respectively, which implied relatively good flame retardancy.

• 한국화재소방학회논문지
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• 제24권2호
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• pp.21-30
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• 2010

본 연구는 화학보호복 원단들에 대하여 내화학성 및 난연성을 조사하기 위하여 ASTM 및 ISO의 방법을 이용하여 내화학성 및 화재위험성시험을 실시하였다. 시험결과 폴리에틸렌의 경우 전혀 난연성이 없는 것으로 분석되었지만 고무에 데카브롬 등 난연성 물질이 첨가된 불소고무 원단이 뛰어난 난연성을 보였다. 특히 현재 소방용 방열복으로도 사용되고 있는 알루미늄 필름에 아라미드원단을 라미네이팅한 원단이 가장 뛰어난 난연성을 보였다. 하지만 내화학성에 있어 알루미늄은 4% NaOH에 부식되는 결과를 보이고 있어 이를 극복하기 위한 방안으로는 다층의 베리어성 필름을 사용하는 것이 좋을 것으로 사료된다. 아울러 난연성 시험결과 알루미늄필름과 폴리머 베리어성 필름을 소재로 만든 Dual skin과 불소고무에 난연성 물질이 포함된 것을 소재로 만든 Single skin이 화학보호복으로 적합한 것으로 판단된다. 또한 열방호실험과 열전달지수실험결과 두께의 증가와 다층구조일수록 TPP와 HTI 증가하는 것으로 나타났다. 향후 화학 보호복 원단의 화재위험성 및 내화학성시험 등 지속적 연구와 보완이 적절한 화학보호복 원단 성능개선에 기여할 것으로 기대된다.

• Journal of the Korean Wood Science and Technology
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• 제51권5호
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• pp.410-418
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• 2023

In this study, the combustion characteristics of the Tulip tree, which is the representative broad-leaved afforestation tree in Korea, were analyzed. The flame retardant performance of the Tulip tree was analyzed by analyzing combustion characteristics on a total of three test samples; flame retardant treated, both flame retardant and oil stain-treated, and untreated. Then the flame retardance grade was classified for each of them. According to the result, test samples showed the strongest flame retardance were in order of flame retardant treated (C), both flame retardant and oil stain-treated (B), and untreated (A). As a result of analyzing the total heat emission and maximum heat emission rates, which is the evaluation standard for interior materials of Korean domestic buildings, test samples with flame retardant treat or flame retardant and oil stain treat were qualified for the flame-retardant standard. Both flame retardant and oil stain-treated samples showed higher total heat release (THR) and heat release rate compared to flame retardant-treated samples as the oil causes combustion with oxygen. On the other hand, they didn't qualify the THR in Quasi-non-combustible standards. To determine the correlation between the physical and combustion characteristics of wood, the combustion characteristics of other diffuse porous wood species, with which the Tulip tree is affiliated were analyzed, and noticed that the characteristic correlates with the density and quantity of wood. The results of this study are expected to be used as basic information on the combustion characteristics of the Tulip tree.