• Applied Chemistry for Engineering
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• v.8 no.1
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• pp.84-91
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• 1997

Diamond film was deposited on Mo substrate at atmospheric pressure using a combustion flame apparatus with the addition of $H_2$. With the substrate temperature, the nucleation density of the substrate was increased. At temperatures above $1000^{\circ}C$, some of diamond was partly converted into graphite and etched by hydrogen atoms. With an increase of the $C_2H_2/O_2$ ratio, the nucleation density was increased. But crystals were cauliflower-shaped and a large number of amorphous carbon were deposited. With the addition of $H_2$, the nucleation density of diamond was increased by the improvement of surface activity. Diamond film of high crystallinity was deposited by etching amorphous carbon. With an increase of deposition time, the thickness of diamond film was increased.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.30 no.5 s.248
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• pp.397-404
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• 2006

Effects of surface defect distribution on flame instability during flame-surface interaction are experimentally investigated. To examine chemical quenching phenomenon which is caused by radical adsorption and recombination processes on the surface, thermally grown silicon oxide plates with well-defined defect density were prepared. ion implantation technique was used to control the number of defects, i.e. oxygen vacancies. In an attempt to preferentially remove oxygen atoms from silicon dioxide surface, argon ions with low energy level from 3keV to 5keV were irradiated at the incident angle of $60^{\circ}$. Compositional and structural modification of $SiO_2$ induced by low-energy $Ar^+$ ion irradiation has been characterized by Atomic Force Microscopy (AFM) and X-ray Photoelectron Spectroscopy (XPS). It has been found that as the ion energy is increased, the number of structural defect is also increased and non-stoichiometric condition of $SiO_x({\le}2)$ is enhanced.

• Fire Science and Engineering
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• v.20 no.2 s.62
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• pp.14-20
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• 2006

The aim of this study is to predict the ignition times and the HRR(heat release rate) for building interior materials. By using the literature data and RSM(response surface methodology), the new equations for predicting the ignition time and the HRR of building interior materials are proposed. The A.A.P.E.(average absolute percent error) and the A.A.D.(average absolute deviation) of the reported and the calculated ignition times by means of the thickness and the density were 4.35 sec and 1.57 sec, and the correlation coefficient was 0.987. The correlation coefficient of the reported and the calculated the net HRR by means of burner width and power was 0.983. Also the correlation coefficient of the reported and the calculated the total HHR by means of burner width and power was 0.999. The correlation coefficient of the reported and the calculated the maximum flame height by means of burner width and power was 0.999. The values calculated by the proposed equations were in good agreement with the literature data.

• Proceedings of the KSR Conference
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• 2005.05a
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• pp.132-137
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• 2005

In this study we investigated the materials which locate in the subway station and train cars. We checked the flammability of the materials such as the signboard, newspaper, wide color film etc. We reported some kind of the data such as oxygen index, optical smoke density, surface flame spread speed for that materials. We hope this data will be help to decide the guideline for such materials.

• Proceedings of the KSR Conference
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• 2002.10b
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• pp.962-968
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• 2002

In this study we reported the Smoke Density, the Toxicity, the Flame Spread Characteristics and the Oxygen Index of the FRP composite interior panels for raicars. Also investigated the test codes of the concerning items of other countries. We made some samples to the variance of resin types, surface finishing methods and panel shapes. It's not the really used ones but may help us effectively to guess the fire safety characteristics of railcars.

• Fire Science and Engineering
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• v.22 no.2
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• pp.30-37
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• 2008

We have performed the inflammability test for various flooring materials through a radiant heat panel tester by using the specification KSISO 9239-1 (an examination method of flooring materials) that has been set as an international standard for the fire prevention means of interior flooring materials. We have measured the flame spread distance, critical heat flux and smoke density generated by the fire of various flooring materials while using the radiant heat panel tester. The measurement result has shown the burning characteristics different from each other by the respective flooring materials and we could see that the surface materials and construction elements influence greatly on the heat release and smoke generation. We could see that the evaluation method above is an important test method in evaluating the critical heat flux, smoke generation and flame spread distance that are Important factors in studying for fire risks and it is judged that setting and applying a fire evaluation method of flooring materials suitable for the domestic construction use would be relevant.

• Journal of the Korea Safety Management & Science
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• v.6 no.1
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• pp.301-309
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• 2004

An inorganic filling agent, ATH (alumina trihydrate) was used to induce inorganic-organic coupling by mixing with stearic acid, acryl silane, vinyl silane as surface treatment agents in order to apply as a high voltage insulating material. Volumetric resistivity was shown to vary with surface treatment agents, and the highest value was obtained in case of the mixture with vinyl silane. The dielectric breakdown intensity was shown to decrease gradually and saturate to a stable value, possibly due to the increase of cross link density in the vinyl radicals introduced to silica surface, resulting in stable dielectric breakdown intensity in the final stages. Tracking and flame retardant properties were also shown to be the best among the samples investigated in this study.

• Proceedings of the Polymer Society of Korea Conference
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• 2006.10a
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• pp.129-129
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• 2006

Conventional solvent-based polyurethane (PU) is well established for wide applications, such as textile treatments, surface coating, adhesive and so on. Due to the demands of safety, economic, and environmental protection, the solvent-based PU is restricted and has been phasing out and aqueous-based PU is becoming the world market trend, which is an environmental friendly product. The chemical resistance, physical and mechanical properties of aqueous-based PU are still not competible with solvent-based PU. Because of aqueous-based PU is a linear thermoplastic polymer with lower average molecular weight. Their improvements are normally performed by a post-curing reaction or a polymer hybridization to enhance the polymer cross-linking density. Hybridization of PU with aqueous-based epoxy resin or acrylate emulsion and then cured by a curing agent for improving the performance properties and reducing the cost of aqueous-based PU.Furthermore, a special function is added to aqueous-based PU increasing the application value, for examples, flame retardation, polymeric dyes, hydrophilic and etc.

• Proceedings of the KSR Conference
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• 2003.10c
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• pp.327-332
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• 2003

We investigated the fire characteristics of the subway electric car's interior materials and evaluated the safety of it. The testing methods are ISO 4589-2 for Limited Oxygen Index, ISO 5658-2 for surface flame spread, ISO 5660-1 for Heat Release Rate, ASTM E 662 for smoke density and BS 6852 Annex B.2 for gas toxicity. The materials of seven organization including KNR were tested. Most of the materials are under the levels of the foreign country's demand. We also reported the test methods of other countries and compared it to ours.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.7 no.4
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• pp.738-742
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• 2006

In this study we developed the electrical heating mold core by applying three different heating methods. In order to find out the optimal heating method, we observed the temperature profiles with time. We also injection-molded the parts by the heating methods and investigated the shrinkage ratio, density, surface roughness and weld-lines. The temperature rise time and cycle time showed the promising results for commercial applications(the rise time is $130^{\circ}C$/14sec, the cycle time is 55sec). By comparing with the conventional and gas flame heating method, the parts by this method were proven to have good qualities. The shrinkage ratio reduced by 5.1%, the density increase by 2.66%, the smoothness increased about 3 times, and the weld-line did not observed by naked eyes.