• Title/Summary/Keyword: Flame retardant treatment

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A Study on the Flame Retardant Performance of MDF Wood According to Flame Retardant Treatment Method (방염처리 방법에 따른 MDF 목재의 방염성능에 관한 연구)

  • Cha, Jung-Min;Hyun, Seong-Ho;Kim, In-Beom;Yoon, Myung-O
    • Fire Science and Engineering
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    • v.25 no.6
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    • pp.146-155
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    • 2011
  • In the study, test was carried out to compare the flame retardant performance for the specimen of MDF wood to which field flame retardant treatment (post processing flame retardant) is applied, which is coated with flame retardant film of 5 companies, locally distributed, and MDF wood (nontreated, flame retardant film non-coated) to which aqueous or oil-based fire-retardant paint is applied. As a result of combustion test of MDF wood which was coated with flame retardant film of 5 companies, 2 products showed suitable values in 4 criteria, but other 3 products showed 10~40 % disqualification rate. In regard of characteristics of fire-retardant paint, oil-based fire-retardant paint is better than aqueous fire-retardant paint in flame retardant performance criteria, but MDF wood to which oilbase fire-retardant paint was applied was shown to have higher toxicity index grade than MDF wood to which aqueous fire-retardant paint was applied relatively.

Performance on Flame-Retardant Polyurethane Coatings for Wood and Wood-based Materials (목재 및 목질재료용 난연성 폴리우레탄수지 도막의 난연성능)

  • Kim, Jong-In;Park, Jong-Young;Kong, Young-To;Lee, Byoung-Hoo;Kim, Hyun-Joong;Roh, Jeang-Kwan
    • Journal of the Korean Wood Science and Technology
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    • v.30 no.2
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    • pp.172-179
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    • 2002
  • In this study, two materials treated with a flame retardant were examined for their fire resistance. The first, MDF (medium density fiberboard) was overlaid by an oak sliced veneer, which was either treated by soaking in a 6wt.% solution of flame retardant chemicals (pentabromine-chlorinated paraffin) or non-treated and then was coated with either a flame retardant polyurethane coating or with a common polyurethane coating. The second material, Pinus koraiensis penal was either treated by a spray treatment using a flame retardant solution or non-treated and then was coated with either a flame retardant polyurethane coating or with a common polyurethane coating. Pentabromine-chorinated paraffin chemicals were added (6 part of urethane resin) as the flame retardant chemicals in the polyurethane coatings. In the fire resistance test, the th𝜃(℃·min) decreased with the flame retardant treatment or/and the flame retardant coatings, compared to the untreated sample Weight loss (%) decreased with the flame retardant treatment or/and the flame retardant coatings. The ignition time (sec.) increased and the residual flame time (sec.) decreased with the flame retardant treatment or/and flame retardant coatings. Therefore, the flame retardant treatment or/and flame retardant polyurethane coatings have excellent incombustibility.

Study on the Improvement of Flame Retardancy of Bamboo Fiber Using Eco-Friendly Liquid Flame Retardant (친환경 액상 난연제를 이용한 대나무섬유의 난연화 연구)

  • Dong-Woo, Lee;Maksym, Li;Jung-il, Song
    • Composites Research
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    • v.35 no.6
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    • pp.456-462
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    • 2022
  • Since natural fibers are highly flammable, it is not easy to make them flame retardant. In this study, a liquid flame retardant based on phytic acid, APTES, and Thiourea, which are flame retardant candidates derived from nature, was prepared and its performance was verified through flame retardant treatment and flame retardancy evaluation of bamboo fibers. When a liquid flame retardant is used, it is possible to treat a large amount of natural fibers with flame retardant treatment. Nine types of flame-retardant treated bamboo fibers were prepared according to the Taguchi design of experiment method. Thereafter, vertical burning test and microcalorimeter test were performed for flame retardancy evaluation, and the surface of natural fibers before and after flame-retardant treatment was compared using scanning electron microscope. The results show that phytic acid has a significant effect on improving the flame retardancy of natural fibers. Through microstructure analysis, it was assumed that the phytic acid helps flame retardant to uniformly adhere to the surface of natural fibers. If such research results are utilized, it is possible to make a large amount of natural fibers high flammability in an eco-friendly way, which is expected to be advantageous for the application of prototypes.

Comparative Analysis of Flame Retardant Performance of Japanese Cypress Plywood Based on the Main Ingredients of Fire Retardant Paint (도료의 주성분에 따른 편백 합판의 방염성능 비교 분석)

  • Soo-Hee Lim;Ha-Sung Kong
    • Journal of the Korea Safety Management & Science
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    • v.25 no.1
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    • pp.61-66
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    • 2023
  • The purpose of this study is to compare and analyze the flame retardant performance of Japanese cypress(Chamaecyparis obtusa) plywood, commonly used in indoor decoration, furniture, and tableware, by treating it with three different fire retardants with different primary ingredients. The experiment was conducted in compliance with Article 31, Paragraph 2 of the Enforcement Decree of the Fire Facilities Installation and Management Act and Articles 4 and 7-2 of the Flame Retardant Performance Standards. After flame time, after glow time, char length, and char area were measured. As a result, first, after flame time was measured at 0 seconds regardless of whether the flame retardant treatment was applied. Second, after glow time was relatively long, measuring 22.7 seconds without treatment, which is likely due to the weak fire resistance and high concentration of carbon monoxide generated by the chemical characteristics of the Japanese cypress itself. Third, it was confirmed that the effects of the primary ingredient, phosphorus, in the flame retardant treatment varied depending on the technological development of the manufacturers of the same species of Japanese cypress plywood. In the future, it is expected that the results of this study will provide fundamental data to select flame retardant treatments that show high flame retardant performance according to the botanical characteristics of the wood.

A Study on the Flame Retardant Performance and Toxicity of the Painting Wood Painted with Flame Retardant Solution (방염처리된 단청목재의 방염성능 및 유독성에 관한 연구)

  • Kim, In-Beom;Hyun, Seong-Ho
    • Fire Science and Engineering
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    • v.23 no.5
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    • pp.66-71
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    • 2009
  • In this study, I evaluated toxicity that analyze performance of flame-retardant about flame-retardant painting wood and combustion gas that is based on the toxicity index. Processing condition of flame retardant solution and treatment method of samples didn't affect greatly to performance of flame retardant. Occurrence of combustion gas showed a almost similar result from the sample which spraying flame retardant solution and toxicity corresponds to high level, Hazard Class III, and the flame retardant solution saturation sample which makes put out Hazard Class II which is a low toxicity relatively.

Effect of Treatments with Flame-retardant on Flame-resistance and Tensile Strength of Paper (난연 처리가 종이의 난연성 및 인장강도에 미치는 영향)

  • Song, Han-Kyu;Lee, Myoung-Ku
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.38 no.4 s.117
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    • pp.61-67
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    • 2006
  • The effect of several inorganic flame-retardants such as ammonium phosphate, ammonium sulfate, aluminum hydroxide and antimony trioxide on the flame-retardant property and tensile strength of paper has been investigated. Flame-retardants were used preferably as a dry powdered mixture and added to the furnish. Both dipping and coating treatments were employed to apply flame-retardants to paper Flame-retardant paper was manufactured by treatment of $5{\sim}30%$ flame-retardants by weight of the paper on a dry weight. Paper's flame-retardant property and tensile strength were examined by comparison of char length and tensile index. As dosages of flame-retardant chemicals increased, flame-retardant property was improved but tensile index was decreased.

A Study on the Treatment of Suitable Flame Retardant to the Fibers for Welding Blanket Development (용접 불티 차단막 개발을 위한 섬유류의 적정 방염처리 방안 연구)

  • 이근원;김관응;이두형
    • Fire Science and Engineering
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    • v.16 no.3
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    • pp.48-55
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    • 2002
  • This study presents a treatment of suitable flame retardant through evaluating fire performance after treating flame retardant of fibers for development of welding blanket. The experimental samples used were commercial fibers and we are treated fibers with the flame retardant liquid and the flame retardant paint. The fire performance of the sample was carried out according to the Korea and Japan Standard. As the results of the fire performance experiment, the treated fiber in samples had enough in the performance of flame and fire retardant and the grade of their was from grade A to grade C according to flame and fire retardant standard. The lower oxygen index indicated that all treated samples with the resist are satisfied with international standard. We con-sider that the welding blanket treated with grade A, B and C performance prevents fire spread regardless of the height of work stairs in the case of installation horizontally. Also, it is considered that the welding blanket treated with grade C performance prevents fire spread regardless of the height of work stairs in the case of installation vertically.

Improved flame retardant performance of cellulose fibers following fluorine gas treatment

  • Kim, Jong Gu;Lee, Young-Seak;In, Se Jin
    • Carbon letters
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    • v.28
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    • pp.66-71
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    • 2018
  • To improve the flame retardant performance of cellulose fibers, fluorine functional groups were introduced under various controlled fluorination conditions. The properties of the fluorinated cellulose fibers were analyzed by X-ray photoelectron spectroscopy and a thermogravimetric analysis. The fluorine functional group content in the fluorinated cellulose fibers increased with an increase in the fluorination temperature. However, the fluorination reaction increased the char yield and decreased the rate of degradation of the cellulose fibers by introducing donors, enabling the formation of a thick and compact char layer. Therefore, the flame retardant properties of cellulose fibers were improved following the fluorination treatment.

Non-durable Flame Retardant Finish of Cotton Fabric by Borax and Boric Acid (Borax 및 Boric Acid에 의한 면직물의 일시적 방염 가공)

  • 남상우
    • Journal of the Korean Home Economics Association
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    • v.25 no.1
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    • pp.43-50
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    • 1987
  • Non-durable flame retardant finish, borax/boric acid mixed solution, was applied to cotton fabric with pad-dry method. The LOI(limited oxygen index) was measured as the measare of the flame retardant effect. The TGA was investigated to know the thermal behavior of the samples. In addition, the solubility of the solutions was investigated. The results were as follows: 1) There was a synergism of flame retardant effect in the borax/boric acid mixed solution treatment and the maximum synergism was shown around the ratio of 7 : 3 2) After the borax/boric acid solution treatment, the degradation temperature was lowered and degraded at the larger temp range with slower rate. The residual char length also increased. 3) The solubility of borax/boric acid become higher when the ratio of borax/boric acid became similar. Compositions from 80/20 to 40/60 borax/boric acid mixtures were solubilized well in room temperatuare or warmwater therefor there was no problem for home use.

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Changes of Flame Retardant and Physical Properties of Cotton Knitted Fabrics after Flame Resistant Treatment (면편성물의 방염처리에 의한 방염성과 물성변화)

  • Jee, Ju-Won;Song, Kyung-Geun
    • Fashion & Textile Research Journal
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    • v.5 no.3
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    • pp.273-282
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    • 2003
  • Effect of fixation methods and relaxation treatment on the flame retardant(FR) and physical properties of MDPP/HMM treated cotton weft-knitted fabrics were studied. Combination of four different fixation methods - relaxation, swelling agent treatment, pad dry cure fixation, and wet fixation - were applied to flame retardant finish of cotton weft-knitted fabric with MDPP/HMM. As the results, 1. Swelling agent and wet fixation method helps FR agent penetrate the fiber efficiently. Interlock showed relatively higher values of LOI than single jersey. 2. Interlock showed relatively higher values of bending rigidity(B), shear rigidity(G) and coefficient of friction(MIU) than those of single jersey before and after flame resistant treatment. 3. An increase in internal volume of cotton fiber by relaxation treatment increased the bending rigidity(B), shear rigidity(G) and compressional energy(WC). 4. The cotton weft-knitted fabric treated wet fixation, which crossliked FR agent efficiently, showed higher bending rigidity, shear rigidity(G) and lower compressional energy(WC). Retention of swelling ability of cotton weft-knitted fabrics treated with MDPP/HMM, which increased the internal volume of cotton weft-knitted fabric, showed lower bending rigidity.