• Composites Research
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• v.35 no.5
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• pp.309-316
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• 2022

The demand for cold-resistant cable material is increasing due to the rapid increase in the development of devices that operate in a low temperature environment. Cold tolerance of a thermoplastic polymer largely depends on the type and content of about 20 or more additives used to make the polymer. The phenomenon of polymer hardening at low temperature can be classified into hardening by simple temperature effect, embrittlement at the glass transition temperature, and hardening by crystallization of polymers that tend to crystallize. In this study, a thermoplastic polymer having a low glass transition temperature, a flame retardant, and an additive were mixed to evaluate the mechanical properties of a thermoplastic polymer composite material for electric wires. It has been confirmed that mechanical properties and processability are determined depending on the additives and compatibilizers added, and this study is considered to be useful as basic data for optimization to meet the performance requirements of wires developed for low-temperature use.

• Elastomers and Composites
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• v.54 no.1
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• pp.35-39
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• 2019

Four different polymer compounds were prepared from four kinds of plasticizers, viz. di-2-ethylhexyl azelate (DOZ), di-2-ethylhexyl adipate (DOA), di-2-ethylhexyl sebacate (DOS), and di-2-butyl sebacate (DBS), for making cable sheaths for ships. Ethylene-vinyl acetate and ethylene-propylene-diene-copolymer as matrix polymers and ethylene-vinyl acetate grafted maleic anhydride as a coupling agent were compounded with a flame retardant, crosslinking agent, filler, and other additives, besides the plasticizer to obtain the polymer compounds. The polymer containing DOZ showed the highest MH and ${\Delta}T$ in the rheology test, while that containing DBS was found to have the lowest tensile strength and highest elongation because of low ${\Delta}T$. The four polymers showed similar values (31.7-31.9) for flame resistance, while the polymer containing DOZ showed the highest value for cold resistance.

• Nuclear Engineering and Technology
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• v.13 no.4
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• pp.245-253
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• 1981

The properties of polyethylene materials exhibit good insulation and radiation resistance, but exhibit poor flame resistance. Flame retardant properties of the polyethylene were improved by the radiation induced grafting or crosslinking. When the various flame retardants were fixed onto polyethylene, the amount of fixation in grafting was increased with the increase of radiation dosages. In the case of grafting, it is necessary for high grafting yield that the polyethylene films were swelled before irradiation with ${\gamma}$-rays or electron beams. It is the suitable method for the fixation of flame retardant that polyethylene samples were blended with various flame retardants at 1$25^{\circ}C$ and then blended polymers were crosslinked by the electron beams at room temperature.

• Journal of the Korea Convergence Society
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• v.12 no.1
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• pp.193-198
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• 2021

In this study, a nano-convergence material technology that can satisfy the superior impact resistance and electrical properties of the semiconducting flame retardant compound used in the Oversheath layer of Extra-high voltage cables was studied. When some of the carbon black used in the semiconducting flame-retardant compound was replaced with CNT (carbon nano tube), the change in physical properties was analyzed. Through the application of carbon nanotubes with remarkably excellent electrical properties, even a small amount of conductive filler formulations can provide superior electrical properties. In addition, as the total filler amount is reduced based on the compound, the workability is improved, and in particular, flexibility and impact resistance are improved, which is expected to contribute to the improvement of the durability of the cable.

• Proceedings of the KIEE Conference
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• 2002.07c
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• pp.1460-1462
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• 2002

The test methods on materials of electrical power cable are used in accordance with 25 specifications of IEC, ASTM, ICEA, KS and KEPCO Spec. The validation of test methods were checked and stablished by solving the problems occurred during the test. These tests are flammability, degree of acidity of gases, amount of halogen acid gas, smoke density, oxygen index, amount of ion in semiconductor, void, amber, contaminant and water tree, crosslinked density. Then the performance of power cable made by A, B, C and D company were evaluated and compared.

• Proceedings of the KIEE Conference
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• 1993.07b
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• pp.609-611
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• 1993

Because the Nuclear power plant needs for the specific high stability and the confidence, it is required that cable shall be flame retardant at fire and endure to be exposed by radiation, chemical fluid, steam and high temperature at sudden accident condition and be maintained its capability on nomal operation up to 40 years as same as it's service life for Nuclear Power Plant. Consequently, In this report, we describe the terms of Environmental Qualification Test for cable and properties required for cable which developed for Nuclear Power Plant.

• Journal of the Korean Society of Safety
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• v.32 no.1
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• pp.140-144
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• 2017

Fire protection for nuclear power plants should be designed according to the concept of "Defense in Depth" to achieve the reactor safety shutdown. This concept focuses on fire prevention, fire suppression and safe shutdown. Fire prevention is the first line of "Defense in Depth" and the licensee should establish administrative measures to minimize the potential for fire to occur. Administrative measures should include procedures to control handling and use of combustibles. Electrical cables is the major contributor of fire loads in nuclear power plants, therefore electrical cables should be fire retardant. Electrical cables installed in nuclear power plants should pass the flame test in IEEE-383 standard in accordance with NUREG-0800, "Standard Review Plan for the Review of Safety Analysis Reports for Nuclear Power Plants". To assure the fire retardant of electrical cables during design life, both aged and unaged cable specimens should be tested in accordance with IEEE-383. It can be generally thought that the flammability of electrical cables has been increased by wearing as time passed, however the results from fire retardant tests performed in U.S.A and Korea indicate the inconsistent tendency of aging and consequential decrease in flammability. In this study, it is expected that the effective methodology for validation of fire retardant performance would be identified through the review of the results from fire retardant tests.

• Proceedings of the KIEE Conference
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• 1998.11c
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• pp.864-865
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• 1998

Permeation of $Ca^{2+}$ ions in PVC and flame-retardant polyolefin (FR) compounds for the sheath of medium voltage underground cables was studied. At $70^{\circ}C$ ion permeation increases fast at times of up to a few tens of hour and then at a relatively slow rate. The first fast increase was attributed to the diffusion of ions in the samples while the second slow increase of ion permeation was attributed to the permeation of $Ca^{2+}$ ions through the samples. It was also found that the diffusivity of $Ca^{2+}$ ions in FR compounds is much higher than that in PVC compounds.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2001.11b
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• pp.251-254
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• 2001

In this paper, we analyzed the properties change of electric wire when the thermal stress was applied to NFR-8 and FR-PVC 600[V] wire. Messurement is made of the attenuation of a light beam by smoke accumulating with in a closed chamber due to nonflaming pyrolytic decomposition and flaming combustion. Results are expressed in terms of specific optical density which is derived from a geometrical factor and the measured optical density a measurement characteristic of the concentration of smoke. Referenced documents were ASTM E662 standard test method for specific Ds genalated by solid materials. The furnace control system shall maintain the required irradiance level under steady-state condition with the chamber door closed of $2.5{\pm}0.04[w/cm^{2}]$ for 20 min. According to the results of the smoke density analysis of NFR-8 and FR-PVC the highest decomposition flaming smoke density range of NFR-8 and FR-PVC were 25.2 to 37.5 and 51.1 respectively. Nonflaming smoke density range of NFR-8 and FR-PVC were 100.4 to 112.2 and 126.5 to 398.8. The amount of carbon monoxide generated was found to be much higher in FR-PVC decomposition than in NFR-8 due to incomplete combustion of FR-PVC which has high content of carbon in compound.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2001.11a
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• pp.251-254
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• 2001

In this paper, we analysed the properties change of electric wire when the thermal stress was applied to NFR-8 and FR-PVC [600] wire. Measurement is made of the attenuation of a light beam by smoke accumulating with in a closed chamber due to nonflamining pyrolytic decomposition and flaming combustion. Results are expressed in terms of specific optical density which is derived from a geometrical factor and the measured optical density a measurement characteristic of the concentration of smoke. Referenced documents were ASTM E662 standard test method for specific Ds generated by solid materials. The furnace control system shall maintain the required irradiance level under steady-state condition with the chamber door closed of 2.5${\pm}$0.04[w/$\textrm{cm}^2$] for 20 min. According to the results of the smoke density analysis of NFR-8 and FR-PVC the highest decomposition flaming smoke density range of NFR-8 and FR-PVC were 7.2 to 77.5 and 51.1 respectively. Nonflaming smoke density range of NFR-8 and FR-PVC were 100.4 to 112.2 and 126.5 to 398.8. The amount of carbon monoxide generated was found to be much higher in FR-PVC decomposition than in NFR-8 due to incomp1ete combustion of FR-PVC which has high content of carbon in compound.