• Title/Summary/Keyword: Flame retardance

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Synergistic effect of clay and polypropylene short fibers in epoxy based ternary composite hybrids

  • Prabhu, T. Niranjana;Demappa, T.;Harish, V.;Prashantha, K.
    • Advances in materials Research
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    • v.4 no.2
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    • pp.97-111
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    • 2015
  • Polypropylene short fiber (PP)-clay particulate-epoxy ternary composites were prepared by reinforcing PP short fiber and clay particles in the range of 0.1 phr to 0.7 phr into epoxy resin. Prepared hybrid composites were characterized for their mechanical, thermal and flame retardant properties. The obtained results indicated an increase in impact resistance, tensile strength, flexural strength and Young's modulus to an extent (up to 0.5 phr clay and 0.5 phr PP short fiber) and then decreases as the reinforcing phases are further increased. The thermal stability of these materials are found to increase up to 0.2 phr clay and 0.2 phr PP addition, beyond which it is decreased. Addition of clay is found to have the negative effect on epoxy-PP short fiber composites, which is evident from the comparison of mechanical and thermal properties of epoxy-0.5 phr PP short fiber composite and epoxy-0.5 phr PP short fiber-0.5 phr clay composite hybrid. UL-94 tests conducted on the composite hybrids have showed a reduction in the burning rate. Morphological observations indicated a greater fiber pull with the addition of clay. The performed tests in the present study indicated that materials under investigation have promising applications in construction, agriculture and decorative purposes.

A Study on the Physical Properties of MgO Board for Wall System (경량 벽체용 MgO 보드의 물리적 특성에 관한 실험적 연구)

  • Kim, Soon-Ho;Kim, Hong-Yong
    • KIEAE Journal
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    • v.7 no.4
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    • pp.135-140
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    • 2007
  • In this study we settled the trouble of the MgO board of existence by this research. We changed the wooden one of the main ingredient of a board to a perlite and a mineral particle in the aluminum hydroxide group and proceeded with a study to physical character and fire resistance efficiency improvement. The result yellowing phenomenon could be improved and it was possible to reduce size decrease of pin hole and the frequency of occurrence. We found out that the in case of absorbed amount added 5~8% corresponding to the weight decreases the acrylic group emulsion suddenly. So this product is improved with the bending strength and water-resistance. After behavior stop time measurement of a mouse for experiments was measured at the time of a gas harmful effect test, an improved MgO board appeared more highly for an average of 138 seconds compared with a board of existence.

Synthesis and Characterization of a Novel Silicon-Containing Epoxy Resin

  • Park Soo-Jin;Jin Fan-Long;Lee Jae-Rock
    • Macromolecular Research
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    • v.13 no.1
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    • pp.8-13
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    • 2005
  • A novel silicon-containing epoxy resin, the diglycidylether of bisphenol A-silicon (DGEBA-Si), was synthesized and characterized. The properties of the DGEBA-Si epoxy resin cured with 4,4-diaminodiphenyl methane (DDM), including its cure behavior, glass transition temperature, thermal stability, and mechanical strength were investigated. The char yield of the DGEBA-Si/DDM system was higher than that of a commercial DGEBA/DDM system, indicating that the DGEBA-Si epoxy resin showed good flame-retardance. The cured DGEBA-Si/DDM specimens possessed lower glass transition temperatures and higher mechanical properties than DGEBA/DDM specimens. These features were attributed to the introduction of siloxane groups into the main chain of the epoxy resin, which resulted in the improved flexibility of the cured DGEBA-Si/DDM system.

Preparation and Characterizations of Wood Plastic Composite Panel Fabricated with Chamaecyparis obtusa Wood Flour (편백나무 목분을 첨가한 합성목재 패널의 제조 및 특성 평가)

  • Kim, Soo-Jong
    • Journal of Convergence for Information Technology
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    • v.12 no.5
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    • pp.126-132
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    • 2022
  • Wood Plastic Composite(WPC) has been mostly used for outdoor purposes such as deck materials and trails so far. In this study, WPC panels with improved antibacterial properties, total volatile organic compound emissions (TVOC), and flame retardant were manufactured to use Wood Plastic Compound as interior materials for indoor use. WPC compound was prepared by mixing Chamaecyparis obtusa wood flour with high density polyethylene(HDPE). The prepared WPC compound exhibited excellent antibacterial and antifungal properties, and the total volatile organic compound emission(TVOC) was 0.062 mg/m2·h. The WPC panel(303mm×606mm×10mm) manufactured by a twin screw extruder with the manufactured compound achieved the flame retardant grade 2 standard of KS F 2271.

Synthesis and Characterization of Phosphorus Polyurethanes Using Phosphorus Polyols (인계 폴리올을 이용한 난연성 폴리우레탄의 합성 및 특성 분석)

  • Kim, Taeyoon;Kim, Yong Gap;Lim, Chung-Sun;Seo, Bongkuk;Lee, Wonjoo
    • Journal of Adhesion and Interface
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    • v.20 no.2
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    • pp.61-65
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    • 2019
  • In this study, phosphorus polyols, having a molecular weight of 880 to 1,560 g/mol, were synthesized by reacting phenylphosphonic dichloride (PPDC), allylphosphonic dichloride (APDC), and ethylene glycol (EG) in solvent, to enhance flame retardance of polyurethane. Phosphorus polyurethanes were polymerized using the synthesized phosphorus polyols, polycarbonate diol (PCD), and 4,4'-diphenylmethane diisocyanate (MDI) by a melt polymerization method. As increasing phosphorus contents of the phosphorus polyurethanes, we observed that the remaining char amount increased. This tendency was also confirmed in the following UL-94V test. We found that when the synthesized phosphorus polyols were applied, the resulting phosphorus polyurethanes show UL-94V0 grade at above 0.5 wt% phosphorus contents.

Dyeing and Fastness Properties of Oak Veneer Dyed with Vinyl Sulfone Type Reactive Dyes (비닐술폰형 반응성 염료를 이용한 오크 무늬목의 염색성 및 견뢰도 특성)

  • Cho, Hang Sung;Shim, Euijin
    • Textile Coloration and Finishing
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    • v.34 no.4
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    • pp.234-240
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    • 2022
  • Use of processed timber can help reduce environmental damage and the economic burden of resources (important problems with use of raw timber) and can meet the needs of various fields where the sensibility of raw timber is required. Veneer wood is positioned as a high-value-added product due to its luxury and beauty, and it is used in various fields as a building-related material, such as interior decoration, furniture, flooring, building interior materials, and lumber. Dyeing is necessary to enhance the aesthetic appearance of this pattern and to expand its use. Therefore, in this study, we compared and analyzed the dye ability of oak-patterned materials with reactive dyes, and evaluated their performance as interior materials. As a result, the oak pattern was dyed with 9 kinds of reactive dyes and a comparative analysis was performed. The most suitable conditions are 50℃, 2 hours, and 0.5% o.w.f. In addition, evaluating resilience to daylight, resilience to rubbing, fire resistance, and flame retardance, yielded results suitable for use as an interior material. In this study, the dyeability of veneer dyed under various conditions using reactive dyes was compared and analyzed the performance as an interior material was evaluated.

Development of Organic-Inorganic Hybrid Insulating Materials with Semi-Non-Combustible Using by Recycling Gypsum (재활용 석고 부산물을 이용한 준불연 유무기 융합 단열재 개발 연구)

  • Ha, Joo-Yeon;Shin, Hyun-Gyoo;Song, Tae-Hyeob
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.4
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    • pp.431-437
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    • 2019
  • The purpose of this study is to develop an organic-inorganic hybrid insulation materials which has an economic feasibility of organic level and excellent adiabatic performance and fire stability by impregnating organic materials with inorganic binder solutions. The organic base was commercial polyurethane sponge, and the inorganic binder slurry was prepared by mixing water and additives into recycled gypsum byproducts. As a result of evaluation of the developed materials, it was confirmed that it not only has excellent insulation performance of a thermal conductivity of 0.051 W/mK or less but also it is a semi-non-combustible materials specified in the Ministry of Land, Infrastructure and Transport Notice No. 2015-744. The developed materials can also be controlled for thermal conductivity and flame retardance according to density control during manufacturing process, and thus it can be applied to various insulation materials.

A Study on the Flame Retardance and Electrical Properties of Silicone Composites (실리콘 복합체의 내화 및 전기 특성에 관한 연구)

  • Lee, Sung-Ill;Lee, Hae-Joon
    • Elastomers and Composites
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    • v.38 no.3
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    • pp.227-234
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    • 2003
  • Silicone composites for high voltage insulator (HVI SC) were prepared by adding aluminum trihydrate(ATH) treated by surface treatment agent to base silicone compound at the ratio oi 100:20, 100:40, 100:60, 100:80, and 100:100, respectively And also, ATH was treated by various surface treatment agents, such as stearic arid, acryl silane, and vinyl silane under compounding process. Mechanical properties and electrical properties were investigated for the various contents of ATH and surface-treatment agents. Mechanical properties such as tensile strength, elongation, and tear strength decreased as the load of ATH increased. Volume resistivity, AC break down strength, and tracking resistance for HVI SC containing ATH treated by vinyl silane were better than those for HVI SC containing ATH treated by other surface treatment agents, such as stearic acid and acryl silane. Polymer-filler interaction of silicone composites according to surface treatment agents was studied by measuring bound rubber contend(BR). From the experimental results, BR of silicone composite containing ATH treated with vinyl silane was higher than that of the others. The degree of rule for silicone composite was investigated using Rheometer. Maximum torque of silicone composites contaning ATH treated with vinyl silane was higher than that of silicone composite contaning ATH treated with other surface agents.

A Evaluation of Fire Behavior According to Member Thickness of Precast Prestressed Hollow Core Slab of Fire Resistance Section (프리캐스트 프리스트레스트 내화단면 중공슬래브의 부재두께에 따른 화재거동평가 )

  • Yoon-Seob Boo;Kyu-Woong Bae;Sang-Min Shin
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.27 no.1
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    • pp.1-8
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    • 2023
  • At construction sites, interest in the production of precast materials is increasing due to off-site conditions due to changes in construction site conditions due to increased labor costs and the Act on the Punishment of Serious Accidents. In particular, the precast prestressed hollow slab has a hollow shape in the cross section, so structural performance is secured by reducing weight and controlling deflection through stranded wires. With the application of structural standards, the urgency of securing fire resistance performance is emerging. In this study, a fire-resistance cross section was developed by reducing the concrete filling rate in the cross section and improving the upper and lower flange shapes by optimizing the hollow shape in the cross section of the slab to have the same or better structural performance and economic efficiency compared to the existing hollow slab. The PC hollow slab to which this was applied was subjected to a two-hour fire resistance test using the cross-sectional thickness as a variable, and as a result of the test, fire resistance performance (load bearing capacity, heat shielding property, flame retardance property) was secured. Based on the experimental results, it is determined that fire resistance modeling can be established through numerical analysis simulation, and prediction of fire resistance analysis is possible according to the change of the cross-sectional shape in the future.