• Title/Summary/Keyword: Flame Area

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Preparation of CeO2 Nanoparticles using Flame Spray Pyrolysis (화염분무열분해법을 이용한 이산화세륨 나노분말 제조)

  • Kim, Sun Kyung;Park, Su-Ryeon;Chang, Hankwon;Jang, Hee Dong
    • Particle and aerosol research
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    • v.12 no.2
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    • pp.37-42
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    • 2016
  • $CeO_2$ nanoparticles were prepared by a flame spray pyrolysis from aqueous solution of cerium nitrate. The morphology, structure crystallinity and specific surface area of as-prepared nanoparticles were characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), and Brunauer-Emmett-Telle (BET). The $CeO_2$ nanoparticles about 5 nm in diameter showed a cubic fluorite structure and polyhedral morphology. The average particle size increased as the cerium nitrate concentration increased. UV absorption performance of the as-prepared nanoparticles was measured by UV-visible spectroscopy. UV absorption of $CeO_2$ nanoparticles was more effective than that of commercial $TiO_2$ nanoparticles. Effect of dopants such as Ti and Zn to $CeO_2$ nanoparticles on UV absorption properties was also investigated. In case of $Ti/CeO_2$, and $Zn/CeO_2$ nanoparticles, they showed a little higher UV absorption values compared with $CeO_2$ nanoparticles. The as-prepared nanoparticles can be promising materials with high UV absorption value.

Examination of validation for equivalent gas to replace natural gas (천연가스를 모사하는 등가가스의 유효성 검토)

  • Kim, Jong-Min;Lee, Seungro;Lee, Chang-Eon
    • Journal of Energy Engineering
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    • v.22 no.2
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    • pp.128-135
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    • 2013
  • In order to estimate the combustion characteristics and the gas interchangeability for natural gas with various compositions per each production area, equivalent gas are using to replace natural gas. It is known that an equivalent gas has the same the heating value, the compression factor, the relative density, CO emission and the burning velocity as the original natural gas. However, it is not reported that the flame shape and thermal efficiency and NOx emission by real gas appliance. In this study, equivalent gas was examined the validation to replace natural gas. The CO emission the burning velocity and the flame temperature were reconfirmed, and the flame shape, the NOx emission and the thermal efficiency were numerically and experimentally investigated. As results, there was not a large difference between natural gas and equivalent gas. This result demonstrated that there was no problem using equivalent gas to replace natural gas.

Photo-degradation of Phenol and Toluene by Using the TiO2-coated Polyethylene Particles (TiO2가 코팅된 Polyethylene 입자를 이용한 페놀과 톨루엔의 광분해)

  • Kim, Dong-Joo;Choi, Sang-Keun;Cho, Jun-Hyung;Kim, Kyo-Seon
    • Journal of Industrial Technology
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    • v.24 no.B
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    • pp.133-138
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    • 2004
  • The photodegradation of phenol and toluene with the $TiO_2$-coated polyethylene (PE) particles were investigated in the slurry type photocatalytic reactor, changing the $TiO_2$ particle sizes, initial phenol and toluene concentrations, and the oxygen flow rate. The nano-sized $TiO_2$ photocatalyst particles were prepared by the diffusion flame reactor and they were coated onto PE particles by using the hybridization system for the efficient recollection of $TiO_2$-coated particles after photodegradation experiments. The degradation efficiencies of phenol and toluene with the $TiO_2$-coated PE particles were more than 90% after photodegradation of 80 minutes for most cases. The efficiencies of photodegradation with the $TiO_2$-coated PE particles were found to be lower than those by the pure $TiO_2$ particles by 50%, because of the decrease in specific surface area of $TiO_2$ particles in PE particles.

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Effects of transition metal-doping on the properties of ZnO nanoparticles and the photocatalytic degradation of methylene blue (전이금속 도핑이 ZnO 나노분말의 특성 및 메틸렌블루 광촉매 분해 특성에 미치는 영향)

  • Chang, Han Kwon;Oh, Kyung Jun;Jang, Hee Dong;Cho, Kuk;Kim, Dong-Jin;Choi, Jin Hoon
    • Particle and aerosol research
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    • v.6 no.1
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    • pp.29-35
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    • 2010
  • Transition metals such as V, Fe, and Ni were used to synthesize doped zinc oxide nanoparticles from mixed liquid precursors by using the flame spray pyrolysis (FSP). The effects of dopants on the powder properties such as morphology, specific surface area, crystal structure, and light adsorption were analyzed by TEM, BET, XRD, and UV-Vis diffuse reflection spectrum (DRS), respectively. The results showed that hexagonal wurtzite structured ZnO:M (M = V, Fe, Ni) nanoparticles were successfully synthesized by the FSP. The transition metal-doping resulted in the decrease in its particle size and crystallite size. The UV-vis absorption spectra of ZnO:M nanoparticles were also red-shifted. ZnO:V showed the highest MB degradation of 99.4% under the UV irradiation after 3 hrs.

An Investigation of Radiation Heat Transfer on The Horizontal Fin of An External Fuel Tank by Flame of a Flying Flare (날아가는 섬광탄이 연료탱크 수평핀에 미치는 복사열전달 연구)

  • Jung, Daehan;Kang, Chihang;Kim, Sitae
    • Journal of the Korea Institute of Military Science and Technology
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    • v.17 no.2
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    • pp.197-203
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    • 2014
  • In this paper, the effect of unsteady radiation on the horizontal fin of an external fuel tank by flame of a flying flare was analysed to see the temperature increase of the fin and the thermal impact on the fin. Radiation between two surfaces was calculated using the concept of radiation resistance of surface and space including radiation, irradiation and shape factor for two flying trajectories of a flare, maximum temperature of 2200 K, emissivity of 0.95, flying velocity of 30 m/s, and thermal surface area of $0.01m^2$. The result shows that the temperature increase of the fin is 0.236 K, and the thermal effect on the fin is ignorable. And it was found that temperature is increased a little because small amount of heat energy can be radiated due to the short exposure time to the heat source.

Effect of Non-uniform Concentration on Gas Explosion (불균일 농도가 가스 폭발에 미치는 영향)

  • Kim Sang Sub;Jang Gi Hyun
    • Journal of the Korean Institute of Gas
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    • v.7 no.4 s.21
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    • pp.14-19
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    • 2003
  • Generally the accident by gas explosion in the working place is occurred at the condition of non-uniform mixture rather than uniform one. This study could predict the explosion phenomenon of non-uniform mixture with model explosion chamber which realize various practical conditions As a result, the mixing level of gas in the chamber depends on discharge area and velocity when there is gas discharge in certain space. In addition, as non-uniform increases, explosion pressure and its increasing rate decrease. However, firing risk after the explosion flame by infrared heat increase due to the increase of residence time of flame.

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Combustion Characteristics of Landfill Gas in Constant Volume Combustion Chamber for Large Displacement Volume Engine (II) - Combustion Analysis - (대형기관 모사 정적연소실에서 매립지 가스의 연소특성에 대한 연구 (II) - 연소 분석 -)

  • Kwon, Soon Tae;Park, Chanjun;Ohm, Inyong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.37 no.8
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    • pp.743-752
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    • 2013
  • This is the second paper on the combustion characteristics of landfill gas in a constant volume combustion chamber for a large displacement volume commercial engine, and it discusses the combustion process on the basis of pressure measurements. The results show that the bimodal peak pressure phenomenon, which is caused by the interaction of the heat release and the heat transfer, is more apparent as the mixtures are more favorable to combustion, and the magnitudes of the pressures depend on the unburned fraction. In addition, there exist four main inflection points during heat release owing to variations in the heat transfer area related to flame propagation from the ignition point. Furthermore, the number of inflection points increases as the mixture quality worsens because of the extended burn duration. Consequently, the sophisticated interactions between the heat transfer area changing pattern due to flame propagation and transfer duration might cause very peculiar heat release patterns.

A Numerical Study on Effects of an Air Inflow Velocity on NOx emission from a Swirl Premixed Burner (스월 예혼합 버너의 공기유입 속도가 NO 배출특성에 미치는 영향에 관한 수치해석)

  • Park, Junho;Cho, Cheon Hyeon;Sohn, Chae Hoon;Cho, Ju Hyeong;Kim, Han Seok
    • 한국연소학회:학술대회논문집
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    • 2014.11a
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    • pp.237-238
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    • 2014
  • A correlation between an air inflow velocity and $NO_x$ emission is investigated numerically. The area of a swirl premixed burner is controlled geometrically to increase or decrease an air inflow velocity. When an air velocity increases, mixedness at the burner exit is improved and NO emission at the liner exit is reduced. Although the area of an air slit is the same, NO emission shows discrepancy due to difference of air slit shapes.

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Nanotechnology in elastomers- Myth or reality

  • Shanmugharaj, A.M.;Ryu, Sung-Hun
    • Rubber Technology
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    • v.12 no.1
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    • pp.1-7
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    • 2011
  • Nanotechnology is the fast becoming key technology of the $21^{st}$ century. Due to its fascinating size-dependent properties, it has gained significant important in various sectors. Myths are being formed on the proverbal nanotechnology market, but the reality is the nanotechnology is not a market but a value chain. The chain comprises of - nanomaterials (nanoparticles) and nanointermediates (coatings, compounds, smart fabrics). Elastomer based nanocomposites reinforced with low volume fraction of nanofillers is the first generation nanotechnology products and it has attracted great interest due to their fascinating properties. The incorporation of nanofillers such as nanolayered silicates, carbon nanotubes, nanofibers, metal oxides or silica nanoparticles into elastomers improves significantly their mechanical, thermal, barrier properties, flame retardency etc., Extremely small particle size, high aspect ratio and large interface area yield an excellent improvement of the properties in a wide variety of the materials. Uniform dispersion of the nanofillers is a general prerequisite for achieving desired properties. In this paper, current developments in the area of elastomer based nanocomposites reinforced with layered silicate and carbon nanotube fillers are highlighted.

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A Study on the Characterization of Fire Plume Ejected from an Opening according to the Opening Form and the Balcony of Apartment in Korea (국내 공동주택의 개구부형태 및 발코니 유·무에 따른 분출화염 성상에 관한 연구)

  • Lee, Kyu-Min;Koo, Tae-Yoon;Hwang, Eu-Cheong;Kwon, Young-Jin
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2017.05a
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    • pp.37-38
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    • 2017
  • This study identified the effects of flame on the upper by fire plume ejected. we implemented model experiment according to investigation of housing area effect, window aspect ratio and balcony availability. we confirmed that opening ratio was increased according to housing area larger. the square window confirmed that is progressing fire plume ejected of free space. According to the value of an opening aspect ratio 'n' getting higher, the horizontal widow is getting that increased the risk as the fire spread an external to the top of opening. it is determined to the fundamental solution about fire safety in the extended balcony of apartment.

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