• Title/Summary/Keyword: Fixed carbon content

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Statistically estimated storage potential of organic carbon by its association with clay content for Korean upland subsoil

  • Han, Kyung-Hwa;Zhang, Yong-Seon;Jung, Kang-Ho;Cho, Hee-Rae;Seo, Mi-Jin;Sonn, Yeon-Kyu
    • 농업과학연구
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    • 제43권3호
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    • pp.353-359
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    • 2016
  • Soil organic carbon (SOC) retention has gradually gotten attention due to the need for mitigation of increased atmospheric carbon dioxide and the simultaneous increase in crop productivity. We estimated the statistical maximum value of soil organic carbon (SOC) fixed by clay content using the Korean detailed soil map database. Clay content is a major factor determining SOC of subsoil because it influences the vertical mobility and adsorption capacity of dissolved organic matter. We selected 1,912 soil data of B and C horizons from 13 soil series, Sangju, Jigog, Jungdong, Bonryang, Anryong, Banho, Baegsan, Daegog, Yeongog, Bugog, Weongog, Gopyeong, and Bancheon, mainly distributed in Korean upland. The ranges of SOC and clay content were $0-40g\;kg^{-1}$ and 0 - 60%, respectively. Soils having more than 25% clay content had much lower SOC in subsoil than topsoil, probably due to low vertical mobility of dissolved organic carbon. The statistical analysis of SOC storage potential of upland subsoil, performed using 90%, 95%, and 99% maximum values in cumulative SOC frequency distribution in a range of clay content, revealed that these results could be applicable to soils with 1% - 25% of clay content. The 90% SOC maximum values, closest to the inflection point, at 5%, 10%, 15%, and 25% of clay contents were $7g\;kg^{-1}$, $10g\;kg^{-1}$, $12g\;kg^{-1}$, and $13g\;kg^{-1}$, respectively. We expect that the statistical analysis of SOC maximum values for different clay contents could contribute to quantifying the soil carbon sink capacity of Korean upland soils.

석유 코크스의 에너지 전환 : CO2 가스화 (Energy conversion of petroleum coke : CO2 gasification)

  • 국진우;곽인섭;이시훈
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2014년도 제49회 KOSCO SYMPOSIUM 초록집
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    • pp.255-257
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    • 2014
  • The installation of light oil facilities or delayed cokers seems to be inevitable in the oil refinery industry due to the heavy crude oil reserves and the increased use of light fuels as petroleum products. Petroleum coke is a byproduct of oil refineries and it has higher fixed carbon content, higher calorific value, and lower ash content than coal. However, its sulfur content and heavy metal content are higher than coal. In spite of disadvantages, petroleum coke might be one of promising resources due to gasification processes. The gasification of petroleum coke can improve economic value of oil refinery industries by handling cheap, toxic wastes in an environment-friendly way. In this study, $CO_2$ gasification reaction kinetics of petroleum coke, various coals and mixing coal with petroleum coke have investigated and been compared by using TGA. The kinetics of $CO_2$ gasification has been performed with petroleum coke, 3 kinds of bituminous coal [BENGALLA, White Haven, TALDINSKY], and 3 kinds of sub-bituminous coal [KPU, LG, MSJ] at various temperature[$1100-1400^{\circ}C$].

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졸가시나무 탄화물 분석 (Analysis of Charcoal from Quercus phillyraeoides)

  • 신수정;김병로
    • Journal of the Korean Wood Science and Technology
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    • 제41권3호
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    • pp.181-186
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    • 2013
  • 졸가시나무 탄화물에 대해 주요 기능 특성을 규명하였다. 졸가시나무 탄화물을 지금까지 보고된 탄화물들과 비교해 보면, 고정탄소율 85% 이상이었고, 비중은 1.0 이상으로 다른 상업용 흑탄이나 백탄보다 높은 경향을 나타냈다. MBA (0.73 mg/g), 흡습성 및 수소이온농도는 낮은 경향이었으며, 발열량은 비슷한 경향을 보였고, 원적외선 방사율은 높은 경향을 나타냈다. 따라서 졸가시나무 탄화물의 기능성을 이용한 사용 시는 기능 성질에 따른 선택적 사용이 필요할 것으로 생각한다.

Effects of Carbon and Nitrogen Sources on Fatty Acid Contents and Composition in the Green Microalga, Chlorella sp. 227

  • Cho, Sun-Ja;Lee, Duk-Haeng;Luong, Thao Thanh;Park, So-Ra;Oh, You-Kwan;Lee, Tae-Ho
    • Journal of Microbiology and Biotechnology
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    • 제21권10호
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    • pp.1073-1080
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    • 2011
  • In order to investigate and generalize the effects of carbon and nitrogen sources on the growth of and lipid production in Chlorella sp. 227, several nutritional combinations consisting of different carbon and nitrogen sources and concentrations were given to the media for cultivation of Chlorella sp. 227, respectively. The growth rate and lipid content were affected largely by concentration rather than by sources. The maximum specific growth was negatively affected by low concentrations of carbon and nitrogen. There is a maximum allowable inorganic carbon concentration (less than 500~1,000 mM bicarbonate) in autotrophic culture, but the maximum lipid content per gram dry cell weight (g DCW) was little affected by the concentration of inorganic carbon within the concentration. The lipid content per g DCW was increased when the microalga was cultured with the addition of glucose and bicarbonate (mixotrophic) at a fixed nitrogen concentration and with the lowest nitrogen concentration (0.2 mM), relatively. Considering that lipid contents per g DCW increased in those conditions, it suggests that a high ratio of carbon to nitrogen in culture media promotes lipid accumulation in the cells. Interestingly, a significant increase of the oleic acid amount to total fatty acids was observed in those conditions. These results showed the possibility to induce lipid production of high quality and content per g DCW by modifying the cultivation conditions.

베어링용 흑연재 Bushing 개발 (Development of Graphite Bushing for Bearing)

  • 김경자;조광연;정윤중;임연수
    • 한국세라믹학회지
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    • 제34권8호
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    • pp.797-802
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    • 1997
  • The use of carbon materials in mechanical components such as bearings, seals, and bushings that do not require lubricants is increasing rapidly. This paper reports on establishing the optimal condition for resin-bonded carbon materials. We fixed the content ratio of materials, which include graphite powder and diatomite as a lubricant modifier and a friction modifier, respectably, with resin used as a bonding material. We then produced bushings using hot-pressing within the temperature range of resin curing. The properties of bushing, the friction coefficient, wear rate and the mechanical strengths are discussed in relation to the content of respective materials, with correlation of friction coefficient and sliding distance. Finally, we examined the friction coefficient changes according to the applied load on bushing and the friction coefficient changes according to contact speed of bushing.

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Bridge effect of carbon nanotubes on the electrical properties of expanded graphite/poly(ethylene terephthalate) nanocomposites

  • Kim, Ki-Seok;Park, Soo-Jin
    • Carbon letters
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    • 제13권1호
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    • pp.51-55
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    • 2012
  • In this work, expanded graphite (EG)-reinforced poly(ethylene terephthalate) (PET) nanocomposites were prepared by the melt mixing method and the content of the EG was fixed as 2 wt%. The effect of multi-walled carbon nanotubes (MWCNTs) as a co-carbon filler on the electrical and mechanical properties of the EG/PET was investigated. The results showed that the electrical and mechanical properties of the EG/PET were significantly increased with the addition of MWCNTs, showing an improvement over those of PET prepared with EG alone. This was most likely caused by the interconnections in the MWCNTs between the EG layers in the PET matrix. It was found that the addition of the MWCNTs into EG/PET led to dense conductive networks for easy electron transfers, indicating a bridge effect of the MWCNTs.

탄소와 질소 함량에 따른 탄질소 복합첨가강의 내마멸 특성 변화 (Wear-characteristics variation of Fe-C-N alloy with changing content of carbon and nitrogen)

  • 박준기;이슬기;김성준;김용석
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2009년도 춘계학술대회 논문집
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    • pp.385-388
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    • 2009
  • Dry-sliding-wear behavior of Fe-18Cr-l0Mn steel with various carbon and nitrogen contents was characterized, and the effect of carbon and nitrogen contents on the wear was investigated. Dry sliding wear tests of the steel were carried out at room temperature against an AISI 52100 bearing steel ball using a pin-on-disk wear tester. Applied wear loads were varied from 10 N to 100 N, and the sliding distance was fixed as 720 m. Worn surfaces and the wear debris of the steel were examined using an SEM to find out the wear mechanism. It was found that the Fe-18Cr-10Mn with both carbon and nitrogen exhibited superior wear resistance to the steel with only nitrogen. The wear resistance of the Fe-18Cr-10Mn-xC-yN alloy increased with the increase of the carbon content. The excellent wear resistance of the Fe-18Cr-10Mn-xC-yN alloy was explained by the increased strain-hardening capability with the interstitial atoms.

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흔합 및 합금고속도강 소결체의 치밀화에 미치는 구성성분의 역할 (Role of Alloyed Components on Densification of Mixed and Prealloyed High Speed Steel Powder Compacts)

  • 임태환
    • 한국분말재료학회지
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    • 제1권2호
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    • pp.153-158
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    • 1994
  • The effect of the role of alloyed components on the densification of two kind of high speed steel (mixed and prealloyed powder), which were sintered at 1403~ 1573 K for 7.2 ks in vacuum, was investigated. The results obtained were as follows. (1) Without the presence of Vanadium (V), the relative density of sintered compacts (Ds) could not reached the density of 100% regardless of the. elements in the compacts. (2) The addition of V up to 2 mass% did not result In the complete densification when the carbon content was fixed at 2% in the compact. (3) With the fixed amount of V of 7%, Ds decreased with the increase of the carbon content. (4) The addition of mixed fine powder to the prealloyed powder in the range of 20 to 40% provided the complete densification and carbide panicles of 1~2 $\mu\textrm{m}$ through the solid phase sintering. (5) The V element played important role in controlling the complete or incomplete densification of the sintered compacts in the alloyed component because of its formation of stable oxide and carbide as well as the low equilibrium pressure of CO gas.

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Effect of physicochemical properties and feed mix ratios on the carbothermic reductions of iron ore with coke

  • S.R.R. Munusamy;S. Manogaran;F. Abdullah;N.A.M. Ya'akob;K. Narayanan
    • Advances in materials Research
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    • 제13권3호
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    • pp.161-171
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    • 2024
  • This study aimed to investigate the effect of physicochemical properties and mix ratios of iron ore (oxide feed): coke (reductant) on the carbothermic reductions of iron ore. Coke size was fixed at ≤63 ㎛ while iron ore size varied between 150-63 ㎛ and ≤63 ㎛ respectively. Mix ratios were changed from 100:0 (reference) to 80:20 and 60:40 while the temperature, heating rate and soaking duration in muffle furnace were fixed at 1100 ℃, 10 ℃/min and 1 hour. Particle size analyzer, XRF, CHNS and XRD analyses were used for determination of raw feed characteristics. The occurrence of phase transformations from various forms of iron oxides to iron during the carbothermal reductions were identified through XRD profiles and supported with weight loss (%). XRF analysis proved that iron ore is of high grade with 93.4% of Fe2O3 content. Other oxides present in minor amounts are 2% Al2O3 and 1.8% SiO2 with negligible amounts of other compounds such as MnO, K2O and CuO. Composite pellet with finer size iron particles (≤63 ㎛) and higher carbon content of 60:40 exhibited 45.13% weight lost compared to 32.30% and 3.88% respectively for 80:20 and 100:0 ratios. It is evident that reduction reactions can only occur with the presence of coke, the carbon supply. The small weight loss of 3.88% at 100:0 ratio occurs due to the removal of moisture and volatiles and oxidations of iron ore. Higher carbon supply at 60:40 leads into better heat and mass transfer and diffusivity during carbothermic reductions. Overall, finer particle size and higher carbon supply improves reactivity and gas-solid interactions resulting in increased reductions and phase transformations.

Comparison study between recovered carbon black and commercial carbon black filled epoxy conductive materials

  • Huai M. Ooi;Pei L. Teh;Cheow K. Yeoh;Wee C. Wong;Chong H. Yew;Xue Y. Lim;Kai K. Yeoh;Nor A. Abdul Rahim;Chun H. Voon
    • Advances in materials Research
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    • 제13권3호
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    • pp.221-232
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    • 2024
  • Waste tire management and recycling have grown to be significant issues because they bring up a global environmental concern. Thus, turning recycled waste tires into useful products may help tackle the environmental issue. This research aims to study and compare the effect of recycled carbon black (rCB) and commercial carbon black (CB) at certain 15 vol. % of filler loading on the mechanical, thermal, morphology and electrical properties of epoxy/CB composites. For this project, epoxy resin, diethyltoluenediamine (DETDA), recovered carbon black (rCB) and commercial carbon black (CB) graded N330, N550, N660 and N774 were mixed and compared accordingly to the formulation determined. The CB content was dispersed in the epoxy matrix using the mechanical mixing technique. The distribution and dispersion of CB in the epoxy matrix affect the characteristics of the conductive composites. rCB content at 15 vol% was selected at fixed content for comparison purposes due to the optimum value in electrical conductivity results. The flexural strength results followed the sequence of rCB>N774>N660>N550>N330. As for electrical conductivity results, epoxy/N330 exhibited the highest conductivity value, while the others achieved a magnitude of X10-3 due to the highest external surface area of N330. In terms of thermal stability, epoxy/N330 and epoxy/N774 were slightly more stable than epoxy/rCB.