• Title/Summary/Keyword: First order decay model

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Finite Difference Modeling for Scale-Dependent Dispersivity in a Fractured Medium

  • Han, Choongyong;Kang, Joe M.;Choe, Jonggeun
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.04a
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    • pp.102-105
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    • 2002
  • A new finite difference model is developed for solute transport in a fractured medium that can consider advection, adsorption, first-order decay, and scale-dependent dispersivity of individual fractures. In the model, the dispersivity of individual fractures is employed as a variable increasing with travel distance from a source. The model is verified using an analytical solution for a single fracture. A solution from the new model is independent of the outlet boundary condition of fractures, and has little numerical dispersion error.

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First-Order Mass Transfer in a Diffusion-Dominated (Immobile) Zone of an Axisymmetric Pore: Semi-Analytic Solution and Its Limitations (대칭형 다공성 매질의 확산주도 영역에 관한 1차 물질이동 방정식)

  • Kim, Young-Woo;Kang, Ki-jun;Cho, Jung-ho;Kabala, Zbigniew
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.11
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    • pp.4664-4670
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    • 2010
  • Comparison of the classical mobile-immobile zone (MIM) model to the derived model led to several conclusions. If the MIM model is to be applied, the initial concentration in the immobile zone has to be down-scaled by a correction factor that is a function of pore geometry. The MIM model was valid only after sufficiently long time has passed, i.e., only after the diffusion front reaches the deepest pore wall in the immobile zone. The MIM mass-transfer coefficient $\alpha$, was inversely proportional to the square of the pore depth. Also it did not depend on the mobile-zone flow velocity, contrary to the number of laboratory and field observations. The classical MIM model displayed a rapid exponential decay of immobile-zone concentration. Meanwhile at large times, the newly derived model displayed similar exponential decay. This was contrary to the mounting evidence of power-law BTC tails observed in laboratory and field settings.

Methane emission from municipal solid waste dumpsites: A case study of Chennai city in India

  • Srinivasan, Pavithrapriya;Andimuthu, Ramachandran;S.N., Ahamed Ibrahim;Ramachandran, Prasannavenkatesh;Rajkumar, Easwari;Kandasamy, Palanivelu
    • Advances in environmental research
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    • v.9 no.2
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    • pp.97-107
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    • 2020
  • The indiscriminate growth in global population poses a threat to the world in handling and disposal of Municipal solid waste. Rapid urban growth increases the production, consumption and generation of Municipal solid waste which leads to a drastic change in the environment. The methane produced from the Municipal Solid waste accounts for up to 11% global anthropogenic emissions, which is a major cause for global warming. This study reports the methane emission estimation using IPCC default, TNO, LandGEM, EPER and close flux chamber from open dump yards at Perungudi and Kodungaiyur in Chennai, India. The result reveals that the methane emission using close flux chamber was in the range of 8.8 Gg/yr-11.3 Gg/yr and 6.1Gg/yr to 9.1 Gg/yr at Kodungaiyur and Perungudi dump yard respectively. The per capita waste generation was estimated based on waste generation and population. The waste generation potential was projected using linear regression model for the period 2017-2050. The trend of CH4 emission in the actual field measurement were increased every year, similarly the emission trend also increased in IPCC default method (mass balance approach), EPER Germany (zero order decay model) where as TNO and Land GEM (first order decay model) were decreased. The present study reveals that Kodungaiyur dump yard is more vulnerable to methane emission compared to Perungudi dump yard and has more potential in waste to energy conversion mechanisms than compare to Perungudi dump yard.

Oxygen Release from Peroxide Injected into Soil/Sediment (토양/퇴적물에 주입한 과산화물에서 발생되는 산소 배출)

  • Han, Kyungmin;Kim, Geonha
    • Journal of Korean Society on Water Environment
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    • v.26 no.1
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    • pp.156-159
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    • 2010
  • Peroxide is used frequently to provide electron acceptors to aerobes for the purpose of in situ bioremediation of contaminated soil/sediment. In this study, oxygen release rate of peroxides and factors affecting on dissolution and diffusion of oxygen into pore water were evaluated. Peroxides studied in this study were magnesium peroxide ($MgO_2$), calcium peroxide ($CaO_2$), and sodium percarbonate ($Na_2CO_3{\cdot}1.5H_2O_2$). $Na_2CO_3{\cdot}1.5H_2O_2$ showed the highest oxygen release rate per unit mass and the shortest release duration time among three peroxides. A simple first-order decay model for predicting the release rate of oxygen from peroxide into pore water was presented and used to fit the experimental data. The first order oxygen release rate constants k for $MgO_2$, $CaO_2$ and $Na_2CO_3{\cdot}1.5H_2O_2$ were 0.45 /hr, 3.22 /hr and 134 /hr, respectively. If $MgO_2$ was mixed with clay, oxygen release rate was lowered significantly mainly due to limitation of contact area and diffusion, implying that oxygen can be provided to the indigenous aerobes for the extended period of time.

Global performances of a semi-submersible 5MW wind-turbine including second-order wave-diffraction effects

  • Kim, H.C.;Kim, M.H.
    • Ocean Systems Engineering
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    • v.5 no.3
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    • pp.139-160
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    • 2015
  • The global performance of the 5MW OC4 semisubmersible floating wind turbine in random waves was numerically simulated by using the turbine-floater-mooring fully coupled and time-domain dynamic analysis program FAST-CHARM3D. There have been many papers regarding floating offshore wind turbines but the effects of second-order wave-body interactions on their global performance have rarely been studied. The second-order wave forces are actually small compared to the first-order wave forces, but its effect cannot be ignored when the natural frequencies of a floating system are outside the wave-frequency range. In the case of semi-submersible platform, second-order difference-frequency wave-diffraction forces and moments become important since surge/sway and pitch/roll natural frequencies are lower than those of typical incident waves. The computational effort related to the full second-order diffraction calculation is typically very heavy, so in many cases, the simplified approach called Newman's approximation or first-order-wave-force-only are used. However, it needs to be justified against more complete solutions with full QTF (quadratic transfer function), which is a main subject of the present study. The numerically simulated results for the 5MW OC4 semisubmersible floating wind turbine by FAST-CHARM3D are also extensively compared with the DeepCWind model test results by Technip/NREL/UMaine. The predicted motions and mooring tensions for two white-noise input-wave spectra agree well against the measure values. In this paper, the numerical static-offset and free-decay tests are also conducted to verify the system stiffness, damping, and natural frequencies against the experimental results. They also agree well to verify that the dynamic system modeling is correct to the details. The performance of the simplified approaches instead of using the full QTF are also tested.

A Study on the Ozone Consumption Rate for Drinking Water Treatment Process with Ozone Application (오존의 정수처리 적용을 위한 오존소비인자에 관한 연구)

  • Kang, Tae-Hee;Oh, Byung-Soo;Kwon, Soon-Buhm;Sohn, Byeong-Yong;Kang, Joon-Wun
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.6
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    • pp.663-669
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    • 2005
  • The aim of this study was to investigate the ozone decay pattern for the effective application of ozone in drinking water treatment. In order to measure the ozone decomposition in water, ozone measuring instrument was developed with flow injection analysis (FIA) method. From the result of continuous residual ozone concentration in water, it was confirmed that the ozone decay pattern was divided with instantaneous ozone demand(I.D) and pseudo first-order rate($k_c$) phases, which were influenced by the variation of ozone dose. The empirical model obtained from I.D and $k_c$ values enabled us to predict the residual ozone concentration according to the reaction time, showing the high correlation between model and experimental values. The concentration of OH radical and $R__{ct}$ could be indirectly measured by OH radical probe compound. In both I.D and $k_c$ phases, the production pattern of OH radical could be observed, which was also affected by the variation of ozone dose. Finally, it was confirmed that the ozone consumption rate was varied according to the each drinking water treatment process and seasoning. Therefore, the optimum position and dosage of ozone have to be selected by considering various factors.

Effect of Landfill Site Characteristics on Siloxane Production in Landfill Gas (매립지 특성이 매립가스 내 siloxane 발생에 미치는 영향)

  • Nam, Sangchul;Kang, Jeong-Hee;Hur, Kwang-Beom;Lee, Nam-Hoon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.19 no.3
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    • pp.44-53
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    • 2011
  • Siloxane, organo-silicon compound, is used in the various forms of products such as cosmetics and detergents due to its quality physical chemistry attributes. Siloxane included in landfill gas which is caused in the process of decomposing of such products after landfill has imposed negative impacts on the operation of landfill gas utility facilities. The objective of this study was to investigate the siloxane production characteristics depending on the features of various landfill site in Korea so that the analysis was made on the landfilling age and landfill waste by in terms of its concentration, structure and composition. As for the concentration of siloxane depending on time passage, 12 landfill sites were reviewed by landfilling age. As for production attributes change of siloxane by landfill wastes, the source of wastes, physical production ration and siloxane concentration were compared in 6 landfills. The average concentration of total-siloxane within LFG is $6.75mg/m^3$ and cyclic-siloxane out of it occupies over 93%. By element, D4 and D5 in order take the highest proportion regardless of total-siloxane concentration and landfilling age. Even though this study is not able to verify the different impact of each kind of wastes on the generation of siloxane, it is confirmed that total-siloxane and cyclic-siloxane decrease in line with the increase of landfilling age as it does in the first order decay model for landfill gas.

Study of Selected IPCC Methodologies for the Estimation of Greenhouse Gas Emissions from a Landfill (매립지 온실 가스 배출량 산정을 위한 IPCC 선정방법별 특성 연구)

  • Jung, Sung Hoon;Hwang, Hyeon Uk;Kim, Myung Gyun;Yan, Cao Zheng;Nzioka, Antony Mutua;Tinega, Joseph Nyamoko;Kim, Young Ju
    • Resources Recycling
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    • v.25 no.5
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    • pp.28-35
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    • 2016
  • The purpose of this study was to estimate greenhouse gas emissions using IPCC 1996 Guideline Tier 1, Good Practice Guidance 2000 Tier 2 and IPCC 2006 Guideline First Order Decay methods from landfill disposal facility. In addition, a comparative analysis evaluating the pros and cons of each method based on assumptions and default factors was considered for each method. The greenhouse gas emission computed using IPCC 1996 Guideline Tier 1 method (2,760 ton/yr) was higher than the estimation of GPG 2000 Tier 2 and IPCC 2006 Guideline First Order Decay Model which showed 1500 and 880 ton/yr respectively between 2000 and 2013.

Aero-elastic wind tunnel test of a high lighting pole

  • Luo, Yaozhi;Wang, Yucheng;Xie, Jiming;Yang, Chao;Zheng, Yanfeng
    • Wind and Structures
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    • v.25 no.1
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    • pp.1-24
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    • 2017
  • This paper presents a 1:25 multi-freedom aero-elastic model for a high lighting pole at the Zhoushan stadium. To validate the similarity characteristics of the model, a free vibration test was performed before the formal test. Beat phenomenon was found and eliminated by synthesis of vibration in the X and Y directions, and the damping ratio of the model was identified by the free decay method. The dynamic characteristics of the model were examined and compared with the real structure; the similarity results were favorable. From the test results, the major along-wind dynamic response was the first vibration component. The along-wind wind vibration coefficient was calculated by the China code and Eurocode. When the peak factor equaled 3.5, the coefficient calculated by the China code was close to the experimental result while Eurocode had a slight overestimation of the coefficient. The wind vibration coefficient during typhoon flow was analyzed, and a magnification factor was suggested in typhoon-prone areas. By analyzing the power spectrum of the dynamic cross-wind base shear force, it was found that a second-order vortex-excited resonance existed. The cross-wind response in the test was smaller than Eurocode estimation. The aerodynamic damping ratio was calculated by random decrement technique and the results showed that aerodynamic damping ratios were mostly positive at the design wind speed, which means that the wind-induced galloping phenomenon is predicted not to occur at design wind speeds.

THE LORENTZ FORCE IN ATMOSPHERES OF CP STARS: θ AUR

  • VALYAVIN G.;KOCHUKHOV O.;SHULYAK D.;LEE B.-C.;GALAZUTDINOV G.;KIM K.-M.;HAN I.
    • Journal of The Korean Astronomical Society
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    • v.38 no.2
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    • pp.283-287
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    • 2005
  • The slow evolution of global magnetic fields and other dynamical processes in atmospheres of CP magnetic stars lead to the development of induced electric currents in all conductive atmospheric layers. The Lorentz force, which results from the interaction between a magnetic field and the induced currents, may modify the atmospheric structure and provide insight into the formation and evolution of stellar magnetic fields. This modification of the pressure-temperature structure influences the formation of absorption spectral features producing characteristic rotational variability of some spectral lines, especially the Balmer lines (Valyavin et al., 2004 and references therein). In order to study these theoretical predictions we began systematic spectroscopic survey of Balmer line variability in spectra of brightest CP magnetic stars. Here we present the first results of the program. A0p star $\Theta$ Aur revealed significant variability of the Balmer profiles during the star's rotation. Character of this variablity corresponds to that classified by Kroll (1989) as a result of an impact of significant Lorentz force. From the obtained data we estimate that amplitudes of the variation at H$\alpha$, H$\beta$, H$\gamma$ and H$\delta$ profiles reach up to $2.4\%$during full rotation cycle of the star. Using computation of our model atmospheres (Valyavin et al., 2004) we interpret these data within the framework of the simplest model of the evolution of global magnetic fields in chemically peculiar stars. Assuming that the field is represented by a dipole, we estimate the characteristic e.m.f. induced by the field decay electric current (and the Lorentz force as the result) on the order of $E {\~} 10^{-11}$ cgs units, which may indicate very fast (< < $10^{10}$ years) evolution rate of the field. This result strongly contradicts the theoretical point of view that global stellar magnetic fields of CP stars are fossil and their the characteristic decay time of about $10^{10}$ yr. Alternatively, we briefly discuss concurring effects (like the ambipolar diffusion) which may also lead to significant atmospheric currents producing the observable Lorentz force.