• Title/Summary/Keyword: Fire-resistance

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Manufacture of Cement-Bonded Particleboards from Korean Pine and Larch by Curing of Supercritical CO2 Fluid

  • Suh, Jin-Suk;Hermawan, Dede;Kawai, Shuichi
    • Journal of the Korean Wood Science and Technology
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    • v.28 no.4
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    • pp.41-50
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    • 2000
  • Cement-bonded particleboard is being used as outdoor siding material all over the world, because this composite particularly bears a light weight, high resistance against fire, decay, and crack by cyclic freezing and thawing, anti-shock property, and strength enhancement. Construction systems are currently changing into a frame-building style and wooden houses are being constructed with prefabrication type. Therefore, they require a more durability at outdoor-exposed sides. In this study, the cement hydration property for Korean pine particle, Japanese larch particle and face- and middle layer particles (designated as PB particle below) used in Korean particleboard-manufacturing company was investigated, and the rapid manufacturing characteristics of cement-bonded particleboard by supercritical $CO_2$ curing was evaluated. Korean pine flour showed a good hydration property, however, larch flour showed a bad one. PB particle had a better hydration property than larch flour. The addition of $Na_2SiO_3$ indicated a negative effect on hydration, however, $MgCl_2$ had a positive one. Curing by supercritical $CO_2$ fluid gave a conspicuous enhancement in the performances of cement-bonded particleboards compared to conventional curing. $MgCl_2$ 3%-added PB particle had the highest properties, and $MgCl_2$ 1%-added Korean pine particle had the second class with the conditions of cement/wood ratio of 2.7, a small fraction-screened particle and supercritical curing. On the contrary, the composition of non-hammermilled or large fraction-screened particle at cement/wood ratio of 2.2 was poorer. Also, the feasibility for actual use of 3%-added, small PB particle-screened fraction was greatest of all the conventional curing treatments. Relative superiority of supercritical curing vs. conventional curing at dimensional stability was not so apparent as in strength properties. Through the thermogravimetric analysis, it was ascertained that the peak of a component $CaCO_3$ was highest, and the two weak peaks of calcium silicate hydrate and ettringite and $Ca(OH)_2$ were present in supercritical treatment. Accordingly, it was inferred that the increased formation of carbonates in board contributes to strength enhancement.

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Fabrication and Characteristics of Resin-Type Neutron Shielding Materials for Spent Fuel Shipping Cask (사용후핵연료 수송용기에 사용될 수지계 중성자 차폐재 제조 및 특성)

  • Cho, Soo-Haeng;Do, Jae-Bum;Ro, Seung-Gy;Do, Chun-Ho
    • Applied Chemistry for Engineering
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    • v.7 no.3
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    • pp.597-604
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    • 1996
  • Resin-type neutron shielding materials, KNS-115A, 115B and 115C have been fabricated to be used for spent fuel shipping cask. The base material is epoxy resin, and polypropylene, aluminium hydroxide and boron carbide are added. These shielding materials offer good fluidity at processing, which makes it possible to apply this resin shield to complicated geometric shapes such as shipping cask. Several measurements were made for the shielding materials to evaluate the shielding property, combustion characteristics, fire resistance, thermal and mechanical properties. The neutron shielding ability of the shielding materials is estimated to be better than that of foreign's shielding material, NS-4-FR, due to higher hydrogen atomic density. Other properties of the shielding materials are as follows: Onset temperatures; $267{\sim}270^{\circ}C$, thermal conductivities; $0.62{\sim}0.72W/m{\cdot}K$, combustion characteristics; <$800^{\circ}C$, ATB(average time of burning); <5sec, AEB(average extent of burning) ; <5mm, tensile strengths; $2.3{\sim}3.0kg/mm^2$, compressive strengths; $5.3{\sim}13.3kg/mm^2$, flexural strengths; $4.4{\sim}5.4kg/mm^2$.

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Analysis of Monitored Insulation Data Using Standard Deviation of Leakage Current Data in High-Power Cables at a Thermoelectric Power Station (화력발전소 고전력 케이블의 누설 전류 측정 데이터의 표준 편차값을 사용한 절연감시 데이터 분석)

  • Kim, Bo-Kyeong;Um, Kee-Hong
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.17 no.2
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    • pp.245-250
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    • 2017
  • From the instant of installation and operation, power cables start deteriorating. Cable systems can be maintained not only by monitoring the insulation status of the insulation layer and oversheath, but also the insulation status of the terminal and junction in high-voltage power cables. When the cable system (the cable itself and cable junctions combined) deteriorates, fire accidents happen due to dielectric breakdowns. We have invented a device to monitor the deteriorating status of cables, and installed it at Korea Western Power Co. Ltd. located in Taean, Chungcheongnam-do Province. In this paper, we present the results obtained using our device, through analysing and calculating the standard deviation of leakage current from cable insulators attached to the cables. When the standard deviation of analysed leakage current falls below a critical value, a cable system is deemed to be operating safely. But when the standard deviation of analysed leakage current is larger than the critical value, the insulation status of the terminal and junction in the cable system is considered to have seriously deteriorated. The terminal and junction in the relevant system should then be replaced preemptively in order to prevent blackout accidents of cables caused by the suspension of power supply.

Effect of Powder Hardening Accelerator on the Physical Properties of Precast Concrete (분말형 경화촉진제를 혼입한 PC부재용 콘크리트의 기초특성에 관한 실험적 연구)

  • Jun, Woo-Chul;Seo, Hwi-Wan;Bae, Yeoun-Ki;Park, Hee-Gon;Min, Tae-Beom;Kwon, Yeong-Ho
    • Journal of the Korea Institute of Building Construction
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    • v.15 no.3
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    • pp.265-271
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    • 2015
  • This study is intended to produce a PC (Precast Concrete) member without a steam curing process in developing the high early strength concrete satisfying the condition of 10MPa in compressive strength at the age of 6 hours, and is intended to ensure economic feasibility by increasing the turnover rate of concrete form. Hence, high early strength cement with high $C_3S$ content and the hardening accelerator of powder type accelerating the hydration of $C_3S$ was used. And the properties of concrete were evaluated according to the hardening accelerator mixing ratio (0, 1.2, 1.6, 2.0). No big difference was found from the tests of both slump and air content. When 1.6 % or higher amounts of the hardening accelerator were mixed, the compressive strength of 10MPa was achieved at the age of 6 hours. From the test results of autogenous (drying) shrinkage and plastic shrinkage, it can be seen that there was a difference according to hydration reaction rate due to the addition of the hardening accelerator. However, it was shown that no problem arose with crack and durability. And it was shown that resistance to freezing-thawing, carbonation, and penetration were excellent.

Step-down Piezoelectric Transformer Using PZT PMNS Ceramics

  • Lim Kee-Joe;Park Seong-Hee;Kwon Oh-Deok;Kang Seong-Hwa
    • KIEE International Transactions on Electrophysics and Applications
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    • v.5C no.3
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    • pp.102-110
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    • 2005
  • Piezoelectric transformers(PT) are expected to be small, thin and highly efficient, and which are attractive as a transformer with high power density for step down voltage. For these reasons, we have attempted to develop a step-down PT for the miniaturized adaptor. We propose a PT, operating in thickness extensional vibration mode for step-down voltage. This PT consists of a multi-layered construction in the thickness direction. In order to develop the step-down PT of 10 W class and turn ratio of 0.1 with high efficiency and miniaturization, the piezoelectric ceramics and PT designs are estimated with a variety of characteristics. The basic composition of piezoelectric ceramics consists of ternary yPb(Zr$_{x}$Ti$_{1-x}$)O$_{3}$-(1-y)Pb(Mn$_{1/3}$Nb1$_{1/3}$Sb$_{1/3}$)O$_{3}$. In the piezoelectric characteristics evaluations, at y=0.95 and x=0.505, the electromechanical coupling factor(K$_{p}$) is 58$\%$, piezoelectric strain constant(d$_{33}$) is 270 pC/N, mechanical quality factor(Qr$_{m}$) is 1520, permittivity($\varepsilon$/ 0) is 1500, and Curie temperature is 350 $^{\circ}C$. At y = 0.90 and x = 0.500, kp is 56$\%$, d33 is 250 pC/N, Q$_{m}$ is 1820, $\varepsilon$$_{33}$$^{T}$/$\varepsilon$$_{0}$ is 1120, and Curie temperature is 290 $^{\circ}C$. It shows the excellent properties at morphotropic phase boundary regions. PZT-PMNS ceramic may be available for high power piezoelectric devices such as PTs. The design of step-down PTs for adaptor proposes a multi-layer structure to overcome some structural defects of conventional PTs. In order to design PTs and analyze their performances, the finite element analysis and equivalent circuit analysis method are applied. The maximum peak of gain G as a first mode for thickness extensional vibration occurs near 0.85 MHz at load resistance of 10 .The peak of second mode at 1.7 MHz is 0.12 and the efficiency is 92$\%$.

Electrical Properties of BaTiO3-based 0603/0.1µF/0.3mm Ceramics Decoupling Capacitor for Embedding in the PCB of 10G RF Transceiver Module

  • Park, Hwa-sun;Na, Youngil;Choi, Ho Joon;Suh, Su-jeong;Baek, Dong-Hyun;Yoon, Jung-Rag
    • Journal of Electrical Engineering and Technology
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    • v.13 no.4
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    • pp.1638-1643
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    • 2018
  • Multi-layer ceramic capacitors as decoupling capacitor were fabricated by dielectric composition with a high dielectric constant. The fabricated decoupling capacitors were embedded in the PCB of the 10G RF transceiver module and evaluated for the characteristics of electrical noise by the level of AC input voltage. In order to further improve the electrical properties of the $BaTiO_3$ based composite, glass frit, MgO, $Y_2O_3$, $Mn_3O$, $V_2O_5$, $BaCO_3$, $SiO_2$, and $Al_2O_3$ were used as additives. The electrical properties of the composites were determined by various amounts of additives and optimum sintering temperature. As a result of the optimized composite, it was possible to obtain a density of $5.77g/cm^3$, a dielectric constant of 1994, and an insulation resistance of $2.91{\times}10^{12}{\Omega}$ at an additive content of 5wt% and a sintering temperature of $1250^{\circ}C$. After forming a $2.5{\mu}m$ green sheet using the doctor blade method, a total of 77 layers were laminated and sintered at $1180^{\circ}C$. A decoupling capacitor with a size of $0.6mm(W){\times}0.3mm(L){\times}0.3mm(T)$ (width, length and thickness, respectively) and a capacitance of 100 nF was embedded using a PCB process for the 10G RF Transceiver modules. In the range of AC input voltage 400mmV @ 500kHz to 2200mV @ 900kHz, the embedded 10G RF Transceiver modules evaluated that it has better electrical performance than the non-embedded modules.

Design and Verification of Housing and Memory Board for Downsizing for Crash Protected Memory Module (충돌보호메모리모듈의 소형화를 위한 하우징 및 메모리 보드 설계와 검증)

  • Kim, Jun-Hyoung;Kim, Jung-Pil;Kim, Jeong-Yeol;Kim, Tae-Won
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.48 no.1
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    • pp.81-88
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    • 2020
  • Flight data recorder is a equipment that records data required for investigation of aircraft accidents and should be developed in compliance with the ED-112A standard. Unlike general data storage device, flight data recorder must be able to recover data after an aircraft accident, requiring a housing and a memory board to protect data in extreme environments. To attain this performance, we designed a housing that can withstand the test by analyzing the physical environment of the impact, shear/tensile, penetration resistance and static crush test of the crash survival test and minimized the size and weight compared to the existing one in consideration of the installation of the aircraft in this paper. Insulation material and thermal block material were applied to endure high and low temperature fire so that the internal temperature does not rise above 150℃ even in 260℃, 10 hour environment. In addition, the memory board is designed to minimize the size and we devise a hoping programming method to prevent continuous data loss of more than 16 seconds. Through this, Crash protected memory module that satisfies ED-112A was completed.

A Study on the Characterization of Anthracite Fly Ash for the Fabrication of Calcinated Brick (소성블릭 제조를 위한 무연탄 석탄회의 특성 연구)

  • Yu Yeon-Tae;Kim Byoung-Gyu;Choi Young-Yoon;Nam Chul-Woo;Lee Yeng-Seok;Kim Cheon-Sun
    • Resources Recycling
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    • v.13 no.2
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    • pp.16-23
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    • 2004
  • To increase the recycling rate of anthracite fly ash, the properties of anthracite fly ash were compared to that of bituminous fly ash. Especially, the high temperature properties of the fly ash are investigated by using thermal analysis, high temperature microscope and X-ray diffraction analysis for utilizing anthracite fly ash to prepare the calcinated bricks. The average ratio of $A1_2$$O_3$/$SiO_2$ for anthracite is 0.62 and the ratio for bituminous is 0.34. The content of $SiO_2$ in anthracite fly ash was higher than that of bituminous fly ash. The $A1_2$$O_3$ of anthracite fly ash reacted with the $A1_2$$O_3$ in the fly ash and formed new mullite crystal at over $1000^{\circ}C$, so anthracite fly ash showed high fire resistance. And, the fly ash mixtures having kaolin were prepared, and then extruded in vacuum to evaluate the extruding property of anthracite fly ash mixture. The extruding velocity was decrease with increasing the addition amount of fly ash in the mixture, and the maximum addition amount of fly ash that could be extruded was 60 wt%.

Effect of Fillers on High Temperature Shrinkage Reduction of Geopolymers (충전재에 의한 지오폴리머의 고온수축 감소효과)

  • Cho, Young-Hoon;An, Eung-Mo;Chon, Chul-Min;Lee, Sujeong
    • Resources Recycling
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    • v.25 no.6
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    • pp.73-81
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    • 2016
  • Geopolymers produced from aluminosilicate materials such as metakaolin and coal ash react with alkali activators and show higher fire resistance than portland cement, due to amorphous inorganic polymer. The percentage of thermal shrinkage of geopolymers ranges from less than 0.5 % to about 3 % until $600^{\circ}C$, and reaches about 5 ~ 7 % before melting. In this study, geopolymers paste having Si/Al = 1.5 and being mixed with carbon nanofibers, silicon carbide, pyrex glass, and vermiculite, and ISO sand were studied in order to understand the compressive strength and the effects of thermal shrinkage of geopolymers. The compressive strength of geopolymers mixed by carbon nanofibers, silicon carbide, pyrex glass, or vermiculite was similar in the range from 35 to 40 MPa. The average compressive strength of a geopolymers mixed with 30 wt.% of ISO sand was lowest of 28 MPa. Thermal shrinkage of geopolymers mixed with ISO sand decreased to about 25 % of paste. This is because the aggregate particles expanded on firing and to compensate the shrinkage of paste. The densification of the geopolymer matrix and the increase of porosity by sintering at $900^{\circ}C$ were observed regardless of fillers.

A Study on the Modification of NH4+Y-zeolite for Improving Adsorption/Desorption Performance of Benzene (NH4+Y-zeolite의 개질을 통한 벤젠 흡·탈착 성능 증진 연구)

  • Jang, Young Hee;Noh, Young Il;Lee, Sang Moon;Kim, Sung Su
    • Clean Technology
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    • v.25 no.1
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    • pp.33-39
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    • 2019
  • A.C (activated carbon) is mainly used to remove VOCs (volatile organic compounds), however, it has many problems such as fire risk due to increasing of adsorbent surface temperature during VOCs ad/desorption, increased cost by frequent replacement cycles requirement and performance degradation when containing moisture. In order to solve these problems, many researches, hydrophobic zeolite adsorbents, have been reported. In this study, $NH_4{^+}Y$-zeolite was synthesized with Y-zeolite through steam treatment and acid treatment, which is one of the hydrophobic modification methods, to secure high surface area, thermal stability and humidity resistance. The Y, Y-550-HN, Y-600-HN and Y-650-HN had adsorption capacities of $23mg\;g^{-1}$, $38mg\;g^{-1}$, $77mg\;g^{-1}$, $61mg\;g^{-1}$. The change of Si/Al ratio, which is an index to confirm the degree of modification, was confirmed by XRF (X-ray fluorescence spectrometer) analysis. As a result, the adsorbtion performance was improved when Y-zeolite modified, and the Si/Al ratio of Y, Y-550-HN, Y-600-HN, Y-650-HN were increased to 3.1765, 6.6706, 7.3079, and 7.4635, respectively. Whereas it was confirmed that structural crystallization due to high heat treatment temperature affected performance degradation. Therefore, there is an optimal heat treatment temperature of Y-zeolite, optimum modification condition study could be a substitute for activated carbon as a condition for producing an adsorbent having high durability and stability.