• Journal of the Korean Institute of Gas
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• v.19 no.4
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• pp.8-14
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• 2015

For the safe handling of 2-methyl-1-butanol being used in various ways in the chemical industry, the flash point and the autoignition temperature(AIT) of 2-methyl-1-butanol was experimented. And, the lower explosion limit of 2-methyl-1-butanol was calculated by using the lower flash point obtained in the experiment. The flash points of 2-methyl-1-butanol by using the Setaflash and Pensky-Martens closed-cup testers measured $40^{\circ}C$ and $44^{\circ}C$, respectively. The flash points of 2-methyl-1-butanol by using the Tag and Cleveland open cup testers are measured $49^{\circ}C$ and $47^{\circ}C$. The AIT of 2-methyl-1-butanol by ASTM 659E tester was measured as $335^{\circ}C$. The lower explosion limit by the measured flash point $40^{\circ}C$ was calculated as 1.30 Vol.%. It was possible to predict lower explosion limit by using the experimental flash point or flash point in the literature.

• Journal of the Korean Institute of Gas
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• v.19 no.6
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• pp.54-61
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• 2015

A series of CFD calculation has been conducted to investigate the effect of facility confinement on explosion power for process plant facility. The level of confinement of a facility was simplified with VBR(volume blockage ratio) and averaged size of obstacles. FLACS which is 3D CFD code of gas dispersion and the explosion was used for simulating the explosion phenomena in the idealized domain with different confinement level. The CFD results showed a tendency that the overpressure increases with increasing VBR and number of obstacles. The effect of VBR on the overpressure was relatively small for the case of number of obstacle less than 25. The results of this study can be used to provide a safety guideline considering the facility confinement in case of leakage accident of flammable gas and vapor in process plants.

• Journal of the Korean Institute of Gas
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• v.2 no.3
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• pp.25-36
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• 1998

Explosion and fires can occur in all segments of chemical and petroleum industries because of complexity of process, usage and storage of flammable and reactive chemicals, and operating conditions of high pressure and temperatures. Especially chemical plants have high possibility of the occurrence of BLEVE(Boiling Liquid Expanding Vapor Explosion)and Fireball. In this study, a computer program was developed for the effect assessment of BLEVE and Fireball. BLEVE was analysed by three explosion models of physical explosion model, isothermal expansion model and adiabatic expansion model and Fireball using solid model. The parametric sensitivity analysis has been done for the models of BLEVE and Fireball. The damage by BLEVE and Fireball of Benzene and Toluene and m-Xylene were estimated.

• Journal of the Society of Naval Architects of Korea
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• v.57 no.6
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• pp.322-330
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• 2020

This study deals with underwater explosion (UNDEX) characteristics of various non-explosive underwater shock sources for the development of non-explosive underwater shock testing devices. UNDEX can neutralize ships' structure and the equipment onboard causing serious damage to combat and survivability. The shock proof performance of naval ships has been for a long time studied through simulations, but full-scale Live Fire Test and Evaluation (LFT&E) using real explosives have been limited due to the high risk and cost. For this reason, many researches have been tried to develop full scale ship shock tests without using actual explosives. In this study, experiments were conducted to find the characteristics of the underwater shock waves from actual explosive and non-explosive shock sources such as the airbag inflators and Vaporizing Foil Actuator (VFA). In order to derive the empirical equation for the maximum pressure value of the underwater shock wave generated by the non-explosive impact source, repeated experiments were conducted according to the number and distance. In addition, a Shock Response Spectrum (SRS) technique, which is a frequency-based function, was used to compare the response of floating bodies generated by underwater shock waves from each explosion source. In order to compare the magnitude of the underwater shock waves generated by each explosion source, Keel Shock Factor (KSF), which is a measure for estimating the amount of shock experienced by a naval ship from an underwater explosionan, was used.

• Journal of the Korean Institute of Gas
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• v.25 no.1
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• pp.40-47
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• 2021

In this study, hazards of decomposition and explosion for tert-butylperoxymaleate(TBPM), an organic peroxide, were evaluated by using various equipment to determine the cause of a fire explosion accident. As a result of DSC analysis, the instantaneous power density of TBPM was 26,401 kW/ml, and the NFPA reactive index(Nr) was classified as 4. And the positive value of EP(explosive propagation) and SS(shock sensitivity) showed that the TBPM had a potential hazard of explosion. From the experimental results, the shock sensitivity and friction sensitivity was rated as class 4 and 5, respectively. In the pressure vessel test, TBPM was ranked USA-PVT No.4 and evaluated as a self-reactive substance. In the combustion rate test, TBPM had the combustion rate of 167 mm/sec and was evaluated as the flammable solid classification 2 in GHS.

• Journal of the Korean Institute of Gas
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• v.27 no.3
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• pp.134-140
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• 2023

Activated carbon is a carbonaceous material mainly used as a gaseous or liquid adsorbent. As fire-related accidents occur consistently due to the accumulation of heat of adsorption and oxidation of volatile organic compounds, the explosive characteristics and thermal stability of powdered and granular activated carbon made from coal and coconut shells were evaluated. As a result of the particle size analysis, the powdered activated carbon was in the particle size range (0.4~3) ㎛, and thermal properties such as exothermic onset temperature and decomposition behavior were analyzed using a differential scanning calorimetry and a thermogravimetric analysis. As a result of the evaluation of the explosion hazards for dust, both coal-based and coconut-based powdered activated carbon are classified as St1 class with weak explosion, but this is a relative and does not mean that the explosion hazards is absolutely low. Therefore, it is necessary to establish countermeasures for reducing the damage.

• Fire Science and Engineering
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• v.10 no.1
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• pp.3-9
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• 1996

Electrostatic charge is generated in large scale or high speed processes dealing with materials with large resistance, or under complicated condition. Fire and explosion often occur due to electrostatic charge accumulated in flammable gases, vapor, liquids and powder. It is usually very difficult to verify the cause of accidents as well as the prevention. In this study, it is shown that the needle electrode needs the electrode gap from 1.8mm to 3.8mm, sphere electrode and plate electrodes need the electrode gap of 1.9mmfor the minimum ignition energy. The sphere electrode and the plate electrode requires 12.8mJ and 3.2mJ of minimum ignition energy respectively with the electrode gap of 1.1mm. The ignition voltage rises to very large value as the ground resistance increases.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 2011.04a
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• pp.116-119
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• 2011

분진의 입경과 농도의 변화에 의한 분진의 폭발압력과 압력상승속도 및 그에 따른 분진폭발지수(Kst), 최소점화에너지(MIE) 및 폭발범위 등 분진폭발에 관한 많은 연구가 진행되고 있다. 폭발 메커니즘의 이해와 이를 통한 예방을 위해서는 분진폭발의 폭발효율과 열방출률(Heat Release Rate)에 관한 연구도 필요하다. 본 연구에서는 산소소모열량계를 이용하여 분진폭발 전후의 열방출률의 차이를 통하여 폭발효율과 폭발의 에너지를 정량화하고, 이를 통해 분진폭발 위험도의 정량적 평가기준을 제시하였다.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 2011.11a
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• pp.526-528
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• 2011

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 2011.11a
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• pp.364-368
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• 2011

최근 급속히 발전하고 있는 과학기술과 산업발달에 따라 화학물질, 위험물의 사용, 저장 및 운송물이 날로 증가하고 있다. 이러한 물질들은 우리의 일상생활과 인류문화 발전에 크게 기여하고 있지만 인화성, 폭발성 등의 잠재위험성을 가지고 있다. 세계 각국은 물질의 분류와 표시가 달라 국제무역에서 많은 사고가 증가하고 있는 실정이다. 이 연구의 목적은 자기반응성물질의 화재 폭발 위험성을 평가하고, 국제적인 시험방법과 국내 시험방법으로 시험하여 연관성 및 상관관계를 알아보고 선진화된 시험방법을 국내실정에 적합하게 제시하는데 있다.