• Title/Summary/Keyword: Film Condensation

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Fabrication of Solid Oxide Fuel Cells via Physical Vapor Deposition with Electron Beam: II. Unit Cell Performance (전자빔 물리증착을 이용한 고체 산화물 연료전지의 제조: II. 단전지 성능)

  • Kim, Hyoung-Chul;Park, Jong-Ku;Jung, Hwa-Young;Son, Ji-Won;Kim, Joo-Sun;Lee, Hae-Weon;Lee, Jong-Ho
    • Journal of the Korean Ceramic Society
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    • v.43 no.5 s.288
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    • pp.299-303
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    • 2006
  • In this paper, anode supported SOFC with columnar structured YSZ electrolyte was fabricated via Electron Beam Physical Vapor Deposition (EBPVD) method. Liquid condensation process was employed for the preparation of NiO-YSZ substrate and the high power electron beam deposition method was used for the deposition of YSZ electrolyte film. Double layered cathode with LSM-YSZ and LSM was printed on electrolyte via screen-printing method and fired at $1150^{\circ}C$ in air atmosphere for 3 h. The electrochemical performance and the long-term stability of $5{\times}5cm^2$ single cell were investigated with DC current-voltage characteristics and AC-impedance spectroscopy. According to the investigation, $5{\times}5cm^2$ sized unit cell showed the maximum power density of around $0.76W/cm^2$ at $800^{\circ}C$ and maintained the stable performance over 400 h.

Synthesis and Characterization of Acrylic-Modified Water-Reducible Alkyd Resin 2. Modification by MA and TMPTA Graft Copolymerization (수용성 아크릴 변성 알키드 수지의 합성과 물성 2. MA 및 TMPTA 공중합체에 의한 변성)

  • Cho, Young-Ho;Kang, Ki-Joon;Noh, Si-Tae
    • Applied Chemistry for Engineering
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    • v.5 no.4
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    • pp.698-705
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    • 1994
  • The basic medium oil modified alkyd resin was synthesized from linseed oil fatty acid(LOFA), phthalic anhydride(PAA), maleic anhydride(MA) and trimethylol propane(TMP) by condensation polymerization at $230^{\circ}C$. MA/TMPTA modified water-reducible alkyd resins were synthesized with TMPTA graft copolymerization onto the basic resin at $180^{\circ}C$. Acid value of the resin was controlled by the addition amount of MA and N,N-dimethylethanol amine(DMEA) was used as a neutralizing agent to prepare of the water-reducible alkyd resin. The effect of TMPTA on the graft copolymerization of the resin was studied by measuring molecular weight glass transition temperature(Tg), viscosity, graft efficiency, and gel contents of melanin cured film. Heat resistance, UV resistance and water resistance of cured film of MA/TMPTA modified resin was compared to those of TMA/TMPTA modified alkyd resin. The molecular weight, viscosity gel contents and graft efficiency of water reducible alkyd resin were increased according to the TMPTA graft copolymerization, but Tg was decreased. The viscosity was lower when the solid contents reached 40% than that of 30% content and also and also became lower with the extent of neutralization ratio, The heat resistance, UV resistance and water resistance of the MA/TMPTA modified alkyd resis were better than those of TMA/TMPTA modified alkyd resin but the storage stability of the TMA/TMPTA alkyd resis was better than that of MA/TMPTA modified alkyd resin.

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Novel Thin Film Composite Forward Osmosis Membranes of Highly Enhanced Water Flux with Interlayer Polysiloxane Between Polysulfone and Polyamide (폴리술폰과 폴리아미드 경계층에 형성된 폴리실록산을 이용한 정삼투 복합 박막의 유량 향상)

  • Jung, Boram;Kim, Nowon
    • Membrane Journal
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    • v.26 no.5
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    • pp.391-400
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    • 2016
  • In this work, novel thin film composite (TFC) forward osmosis (FO) membranes are developed via interfacial polymerization on the polysulfone (PS) substrate, using TEOS as the a sol-gel reagent to form hydrophilic interlayer polymer between PS and polyamide (PA). The PS substrate was cast on a very thin polyester nonwoven to reduce membrane resistance. With the incorporation of TEOS (tetraethoxy silane) polymer in the interface between PS and PA, the formed TFC FO membrane exhibits better hydrophilicity and improved water flux, and therefore superior membrane performance. By changing the polymerization sequence of PA interfacial polymerization and TEOS sol-gel condensation, the surface properties and performance of FO membranes are changed significantly. The permeability of FO membranes were estimated using the bench-scale FO test equipment. The distribution of the polysiloxane on composite membrane and morphology are also studied with FE-SEM and EDAX. The PS_PA_TEOS membrane showed highly enhanced water flux (79.2 LMH) but reverse salt flux (RSF) value (7.10 GMH) also increased. However, the flux of PS_TEOS_PA membrane increased moderately (54.1 LMH) without increasing RSF value (1.60 GMH) compare with PS_PA membrane.

Genetic Analyses of Heading and Maturing Dates and Their Relationship to Freezing Resistance in Barley (보리 출수기와 성숙기의 유전분석 및 내동성과의 관계)

  • 천종은;강석원
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.47 no.6
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    • pp.395-401
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    • 2002
  • The combination of early heading time, maturing time and short grain-filling period is very important to develop early varieties in winter barley. The 4 parental half diallel crosses (parents, $F_1$s, $F_2$s) were cultivated at the field. The heading date was from April 3 to 26, maturing date from May 15 to 27 and grain-filling period from 31 days to 42 days, showing that the varietal differences about the 3 traits were remarkable. According to half diallel cross analyses, Dongbori 1 for heading time (late heading) was dominant, but Oweolbori (early heading) was recessive, showing partial dominance with high additive component of genetic variance. Dongbori 1 for maturing time was dominant, but Oweolbori was recessive, showing partial dominance with high additive variance. Reno for grain-filling period (short grain-filling period) was dominant, but Oweolbori (long grain-filling period) was recessive with additive, and partial dominance. There were highly significant mean squares for both GCA and SCA effects on the heading and maturing times, and GCA/SCA ratios for all traits were high, showing the additive gene effects more important. Sacheon 6 and Oweolbori had greater GCA effects for early heading and maturing times, and Dongbori 1 and Reno had greater GCA effects for late times. GCA effects were highly significant in $F_1$ and $F_2$ generations, showing high GCA/SCA ratios (7.02). The heading and maturing times in field were positively correlated with antifreeze proteins concentrations, accumulation, resistance to photoinhibition and winter survival, respectively) but the grain-filling period did negatively correlated with the trails.

Effects of Salt Treatment on Yield and Physiological Characteristics of Flag Leaf at Heading Stage in Winter Barley (보리 출수기 염처리가 수량 및 지잎의 생리적 특성에 미치는 영향)

  • 최원열;김영민;박종환
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.47 no.6
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    • pp.409-412
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    • 2002
  • This research was conducted to obtain the fundamental data on salt injury and different responses among cultivars in winter barley (Hordeum vulgare L.). Salts did not affect yield components including number of panicles, stem length, grain number per ear and grain yield while reduced stem dry weight and thousand seed weight significantly with increasing concentrations of salt from 60 to 180 mM. NaCl had less injury effect on barley straw dry weight and thousand seed weight than did $MgSO_4$. Chlorophyll content and relative turgidity in flag leaf were reduced when treated with both salts, while free proline in the salt-treated leaf was increased. Content of proline in salt-treated barley was about 10 folds compared to the control. Based on yield components and physiological traits of flag leaf, the tolerance to salt injury was the greatest in Baegdong, followed by Dongbori#1, Mogpo#55, and Gangbori. The results suggested that salt- stressed barley at reproductive stage had higher free proline content, and that special management in this stage must be considered because salt stress at heading stage affect flag leaf growth as well as yield components Harmfully.

Variation of Photosynthetic Photon Flux in Commercial Plastic Greenhouses (상업용 플라스틱 온실의 광합성유효광량자속 변화)

  • Lee, Hyun-Woo;Kim, Young-Shik
    • Current Research on Agriculture and Life Sciences
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    • v.30 no.1
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    • pp.27-33
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    • 2012
  • This study was conducted to provide data necessary for clearing up the way to be able to improve covering and management method of covering material in commercial plastic greenhouse. The photosynthetic photon flux(PPF) in representative 4 different commercial tomato greenhouses was measured and analyzed. The variation trend of daily integral PPF was in agreement with that of the duration of sunshine. Each of daily integral PPF for 4 different experimental greenhouses was quite dissimilar, and was less than the amount of PPF necessary to grow tomato. October to November of beginning of winter was a good season to replace covering material in order to secure more PPF during insufficient winter season in greenhouse. The main inside factors to interrupt PPF incidence were thermal screen, inside covering material, condensation receiver in greenhouse. The single wide span greenhouse covered with PO film was superior to the other experimental greenhouses in the aspect of PPF transmittance.

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Separate type heat pipe performance comparison by the heat exchanger shapes (열교환기 형상에 따른 분리형 히트파이프 성능 비교)

  • Jeon, Sung-Taek;Cho, Jin-Pyo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.12
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    • pp.723-729
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    • 2016
  • This study compared fin-tube and parallel-flow heat pipes for their sensible heat exchange rate, heat recovery amount, and air-side pressure drop. Tests were done with different refrigerant charging rates of 40-60% vol. and air flow rates of 300-1,400. The sensible heat exchange rate was highest for both types of heat pipes at a working fluid charge of 40% vol. and low flow rate. For the parallel-flow heat pipe, the 60% vol. charge is too high and results in a low sensible heat exchange rate. The reason is that the thicker liquid film of the tube wall deteriorates the heat transfer effect. Hence, the optimal charging rate is 40 to 50% vol. The evaporator heat pipe has a larger air-side pressure drop than the condenser section heat pipe. The reason is considered to be condensation water arising from the evaporator surface. Compared to the fin-tube heat pipe, the parallel-flow heat pipe showed better performance with a working fluid charging rate of 48%, volume of 41%, and an air-side pressure drop about 37%.

Characteristics of Temperature, Humidity and PPF Distribution by Covering Method and Environmental Control in Double Covering Greenhouse (이중피복 온실의 피복방법과 환경조절에 따른 온습도 및 광합성유효광량자속 분포 특성)

  • Lee, Hyun-Woo;Sim, Sang-Youn;Kim, Young-Shik
    • Journal of Bio-Environment Control
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    • v.21 no.1
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    • pp.1-11
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    • 2012
  • The objective of the present study is to provide data needed to find double covering method to be able to improve environment of temperature, humidity and PPF in tomato greenhouse. The distribution charts of temperature, humidity and PPF which were measured in environment control conditions such as thermal insulation, air heating, roof ventilation and air fog cooling in conventional and air inflated double layers greenhouses were drawn and analysed. The thermal insulation effect of the air inflated greenhouse was the same as that of conventional greenhouse because the temperature between insulation curtain and roof covering material was equal in heating season. The ventilation effect of the air inflated greenhouse was superior to the conventional greenhouse. The temperature distribution in the fog cooled greenhouse was uniform and the cooling effect was about $3.5^{\circ}C$. The condensation on the roof covering surface could be controlled by removing the moisture between insulation curtain and roof covering by using humidifier. The PPF of conventional greenhouse was more decreased than the air inflated greenhouse as time went by because the transmittance of conventional greenhouse declined by dust collected on the inside plastic film owing to rolling up and down operation for ventilation.

Study on the Improvement of Gill Nets and Trap Nets Fishing for the Resource Management at the Coastal Area of Yellow Sea - On the Entrapping Behavior of Fishes into Trap Nets in the Water Tank Experiment - (서해구 자원관리형 자망ㆍ통발 어구어법 기술개발에 관한 연구 - 수조에서의 통발에 대한 어군의 입롱행동 -)

  • 장호영;조봉곤;고광수;한민숙
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.39 no.1
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    • pp.56-62
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    • 2003
  • To investigate the entrapping behavior of blue crab, rock shell and green ling, which are mainly caught with the other trap nets in the coastal area of Yellow Sea, by the using duration of trap nets through the water tank experiment. We select the three kinds of trap nets which have different using duration such as new, 6 months and 12 months used one, and observe the entrapping ratio into the trap nets, respectively. In the mean while, in order to obtain the basic data for the estimate of mesh selectivity of the other trap nets, the entrapping behavior into the trap nets for green ling which has high activity compared to blue crab and rock shell, are examined to the three kinds of mesh size (35mm, 50mm and 65mm). The results are as follows ; 1. The mean entrapping ratio of blue crab by the using duration of trap nets in high with 4.4 fishes (44.0%) in the 6 months used one, become lower with 2.9 fishes (28.0%) in the new one, and with 2.0 fishes (20.0%) in the 12 months used one. 2. The mean entrapping ratio of rock shell by the using duration of trap nets in high with 7.3 fishes (36.7%) in the new one, and become lower with 7.2 fishes (35.8%) in the 6 months used one, and with 5.7 fishes (28.3%) in the 12 months used one. 3. The mean entrapping ratio of green ling by the using duration of trap nets in high with 3.4 fishes (34.0%) in the 6 months used one, and become lower with 3.0 fishes (30.0%) in the new one, and with 2.8 fishes (28.0%) in the 12 months used one. 4. The mean residual ratio of green ling by the mesh size of trap nets is high with 2.4 fishes (24.0%) in the 35mm mesh size, and become lower with 2.2 fishes (22.0%) in the 50mm mesh size and 2.0 fishes (20.0%) in the 65mm mesh size.

The Effect of Cold Shock on Function and Morphology of Dog Epididymal Spermatozoa (개에서 cold shock이 정소상체유래의 정자의 기능과 형태에 미치는 영향)

  • Yu Il-jeoung
    • Journal of Veterinary Clinics
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    • v.21 no.4
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    • pp.329-335
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    • 2004
  • Dog spermatozoa were recovered from the caudae epididymides of 23 domestic dogs which were 11 pure breed and 12 mix-breed dogs ranging in age from 0.6 to 3 years. The experimental designs were as follows: 1) the effect of chilling to 0. 10 or 37$^{\circ}C$. 2) the kinetics of chilling injury at 0 or 4$^{\circ}C$, and 3) the effect of sugars at $0^{\circ}C$. Viable spermatozoa were recovered by percoll gradient separation and adjusted to 5${\times}$10$^{7}$ spermatozoa/ml. In experiment 1, spermatozoa were diluted with 0.33 M glucose supplemented with 3% BSA (G-BSA) at 1:2 dilution. Spermatozoa were loaded into straws and exposed at 0, 10 or 37$^{\circ}C$ for 30 min. In experiment 2, spermatozoa were prepared as the experiment 1 and exposed for 0.5, 5, 15, or 30 min at 0 or 4$^{\circ}C$. In experiment 3, spermatozoa were diluted with different sugars (0.33 M galactose, glucose, fructose, mannitol, lactose, sucrose, raffinose) and cooled to $0^{\circ}C$ for 30 min. Sperm membrane integrity, motility and acrosome integrity were assayed after rewarming at 37$^{\circ}C$ for 5 min. Sperm motility and membrane integrity abruptly decreased with decreasing temperature but acrosome integrity gradually decreased (P<0.05). Sperm motility was more sensitive to cold shock than membrane integrity and acrosome integrity. Spermatozoa cooled to $0^{\circ}C$ were more damaged than those at 4$^{\circ}C$. Sperm motility was not different among exposed times at both. 0 and 4$^{\circ}C$. However, membrane integrity of spermatozoa exposed for 30 min at both 0 and 4$^{\circ}C$ was significantly lower (P<0.05). Spermatozoa diluted in 0.33 M fructose or galactose showed lower motility and higher morphological abnormality with coiled tail at $0^{\circ}C$. These sperm characteristics were strongly related. These results indicate that dog epididymal spermatozoa are relatively sensitive to rapid cooling and higher morphological abnormality at $0^{\circ}C$ was shown in spermatozoa diluted in fructose and galactose.