• Title/Summary/Keyword: Field Assisted Sintering

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Binder-free Tungsten Carbide Fabricated by Pulsed Electric Current Sintering

  • Shimojima, K.;Hosokawa, H.;Nakajima, T.;Mizukami, M.;Yamamoto, Y.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.621-622
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    • 2006
  • In this paper, we show some experimental results of binder-free WC sintered by Pulsed Electric Current Sintering (PECS) also known as Field Assisted Sintering Technology (FAST). These binder-free WC have extremely hardness and stiffness. However, these mechanical properties are dependent on the sintering condition, e.g., maximum temperature, applied pressure, etc. We show some relationship between mechanical properties and sintering condition to improve to sinter the binder-free WC.

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Nanostructured Bulk Ceramics (Part I)

  • Han, Young-Hwan;Mukherjee, Amiya K.
    • Journal of the Korean Ceramic Society
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    • v.46 no.3
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    • pp.225-228
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    • 2009
  • The processing and characterization of ceramic nanocomposites, which produce bulk nanostructures with attractive mechanical properties, have been emphasized and introduced at Prof. Mukherjee's Lab at UC Davis. The following subjects will be introduced in detail in Part II, III, and IV. In Part II, the paper will describe a three-phase alumina-based nanoceramic composite demonstrating superplasticity at a surprisingly lower temperature and higher strain rate. The next part will show that an alumina-carbon nanotube-niobium nanocomposite produced fracture toughness values that are three times higher than that of pure nanocrystalline alumina. It was possible to take advantage of both fiber-toughening and ductile-metal toughening in this investigation. In the fourth section, discussed will be a silicon-nitride/silicon-carbide nanocomposite, produced by pyrolysis of liquid polymer precursors, demonstrating one of the lowest creep rates reported so far in ceramics at the comparable temperature of $1400^{\circ}C$. This was first achieved by avoiding the oxynitride glass phase at the intergrain boundaries. One important factor in the processing of these nanocomposites was the use of the electrical field assisted sintering method. This allowed the sintering to be completed at significantly lower temperatures and during much shorter times. These improvements in mechanical properties will be discussed in the context of the results from the microstructural investigations.

Nanostructured Bulk Ceramics (Part IV. Polymer Precursor Derived Nanoceramics)

  • Han, Young-Hwan;Mukherjee, Amiya K.
    • Journal of the Korean Ceramic Society
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    • v.47 no.3
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    • pp.205-209
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    • 2010
  • In the last (fourth) section, the discussion will entail a silicon-nitride/silicon-carbide nanocomposite, produced by pyrolysis of liquid polymer precursors, demonstrating one of the lowest creep rates reported so far in ceramics at the comparable temperature of $1400^{\circ}C$. This was first achieved by avoiding the oxynitride glass phase at the intergrain boundaries. One important factor in the processing of these nanocomposites was the use of the electrical field assisted sintering method.

Nanostructured Bulk Ceramics (Part II. Superplasticity and High Strain Rate Superplasticity)

  • Han, Young-Hwan;Mukherjee, Amiya K.
    • Journal of the Korean Ceramic Society
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    • v.46 no.4
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    • pp.345-349
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    • 2009
  • In Part II, the paper will describe a three-phase alumina-based nanoceramic composite demonstrating superplasticity at a surprisingly lower temperature and higher strain rate. One important factor in the processing of these nanocomposites was the use of the electrical field assisted sintering method, SPS. These improvements in mechanical properties were briefly discussed in the context of the results from the microstructural investigations. SPS forming approach provides a new route for low temperature and high-strain-rate superplasticity for nanostructured materials and should impact and interest a broad range of scientists in materials research and superplastic forming technology.

Improvement of surface quality of Tungsten-carbide core for glass micro molding (미세 유리 광부품 성형용 초경합금 코어의 표면거칠기 향상에 관한 연구)

  • Lee J.;Kim W.;Min B.;Kang S.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2004.10a
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    • pp.36-39
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    • 2004
  • Glass molding is an advantageous method to manufacture glass micro optical components. However, it is difficult to make Tungsten Carbide core for glass microlens array. We have developed novel method to fabricate Tungsten Carbide core for micro glass components using pressure forming. Silicon masters were fabricated by micro machining. Tungsten Carbide core was fabricated by pressure forming and sintering. And we made high quality surface of Tungsten Carbide core by using the magnetic-field-assisted polishing process.

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Low-Temperature Sintering and Piezoelectric Properties of $(Na_{0.5}K_{0.5})NbO_3$ Lead-Free Piezoelectric Ceramics

  • Seo, In-Tae;Park, Hwi-Yeol;Choi, Jae-Hong;Nahm, Sahn
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.03a
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    • pp.5-5
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    • 2010
  • $(Na_{0.5}K_{0.5})NbO_3$ (NKN) ceramic with 1.5 mol% CuO added (NKNC) was well sintered even at a low temperature of $900^{\circ}C$ with the addition of ZnO. Most of the ZnO reacted with the CuO and formed the liquid phase that assisted the densification of the specimens at $900^{\circ}C$. A few $Zn^{2+}$ ions entered the matrix of the specimens and increased the coercive field ($E_c$) and $Q_m$ values of the specimens. High-piezoelectric properties of $k_p=0.37$, $Q_m=755$, and ${\varepsilon}_3\;^T/{\varepsilon}_0=327$ were obtained from the NKNC ceramics containing 1.0 mol% ZnO sintered at $900^{\circ}C$ for 2 h.

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Facile Synthesis of g-C3N4 Modified Bi2MoO6 Nanocomposite with Improved Photoelectronic Behaviors

  • Zhu, Lei;Tang, Jia-Yao;Fan, Jia-Yi;Sun, Chen;Meng, Ze-Da;Oh, Won-Chun
    • Korean Journal of Materials Research
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    • v.31 no.11
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    • pp.593-600
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    • 2021
  • Herein, a series of g-C3N4 modified Bi2MoO6 nanocomposites using Bi2MoO6 and melamine as original materials are fabricated via sintering process. For presynthesis of Bi2MoO6 an ultrasonic-assisted hydrothermal technique is researched. The structure and composition of the nanocomposites are characterized by Raman spectroscopy, X-ray diffraction (XRD), and high-resolution field emission scanning electron microscopy (SEM). The improved photoelectrochemical properties are studied by photocurrent density, EIS, and amperometric i-t curve analysis. It is found that the structure of Bi2MoO6 nanoparticles remains intact, with good dispersion status. The as-prepared g-C3N4/Bi2MoO6 nanocomposites (BMC 5-9) are selected and investigated by SEM analysis, which inhibits special morphology consisting of Bi2MoO6 nanoparticles and some g-C3N4 nanosheets. The introduction of small sized g-C3N4 nanosheets in sample BMC 9 is effective to improve the charge separation and transfer efficiency, resulting in enhancing of the photoelectric behavior of Bi2MoO6. The improved photoelectronic behavior of g-C3N4/Bi2MoO6 may be attributed to enhanced charge separation efficiency, photocurrent stability, and fast electron transport pathways for some energy applications.