• Proceedings of the Korean Fiber Society Conference
• /
• 2007.11a
• /
• pp.445-446
• /
• 2007

• Polymer(Korea)
• /
• v.38 no.1
• /
• pp.74-79
• /
• 2014

Microfibrillated cellulose (MFC) was chemically modified with two different silane coupling agents (3-aminopropyltriethoxysilane and 3-mercaptopropyltriethoxysilane) and lauroyl chloride. The surface modification of MFC was confirmed by infrared spectroscopy (FTIR), energy dispersive X-ray spectroscopy (EDX), and contact angle measurements. Composite paper was successfully prepared with surface modified MFC and polyamide (PA) fiber. The surface modification of MFC not only prevented aggregation of MFC but also improved adhesive property between PA fiber and surface modified MFC. It was impossible to prepare papers of only PA fiber because there is no binder to connect PA fibers. That is, surface modified MFC as a binder in PA fiber played a crucial role in making composite paper. Composite paper with silane modified MFC showed higher tensile strength and modulus than composite paper with lauroyl moiety modified MFC. The structure, morphology, and mechanical properties of composite paper were analyzed by scanning electron microscope (SEM) and universal testing machine (UTM).

• Textile Coloration and Finishing
• /
• v.22 no.4
• /
• pp.325-331
• /
• 2010

The alkaline dissolution behavior of sea-island type ultrafine nylon fiber were dependent on the concentration of NaOH and treatment time, and the most appropriate condition for alkaline dissolution was to treat with 20g/l NaOH for 30 min at $80^{\circ}C$. The dyeing properties of sea-island type ultrafine nylon fiber and regular nylon fiber were examined with 3 different types of acid dyes in this study. The dye uptakes of ultrafine nylon fiber were higher than regular nylon fiber because of large surface area per unit mass, which increased as the dye bath pH decreased. The dyeing rates on ultrafine nylon fiber were faster and dye exhaustions were higher than regular nylon fiber, however color strength and rating of wash fastness were lower. It was also found that levelling type acid dye showed fast dyeing rate on both nylon fibers than metal-complex and milling type acid dyes.

• Journal of Korea Technical Association of The Pulp and Paper Industry
• /
• v.41 no.5
• /
• pp.59-65
• /
• 2009

Adsorption of an oil-proof agent (OPA）onto cellulose fibers during the papermaking process was investigated using UV-Vis spectrophotometry by measuring the OPA concentration decrease in the solution. From the calibration curve, the spectrum were converted to chemical concentrations in solution, from which the amount adsorbed onto the fiber surface could be determined. Thus, it was possible to determine the total amount adsorbed onto the fibers and in solution. Using this approach, we studied the adsorption behavior of the OPA onto the fiber surface and derived its, ${\Gamma}^s_t={\Gamma}^s_{\infty}(1-e^{-k_{\alpha}t})$. The values of the parameters kaand ${\Gamma}^s_{\infty}$ were determined using a mathematic model based on a mass transfer equation. Ultimately, a complete was derived: $Q={\alpha}{\cdot}\sum\limits_{i-1}^m{\pi}d_il_i{\cdot}M_A{\cdot}(1-e^{-k_{\alpha}t})/A_N$.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.16 no.11
• /
• pp.7878-7884
• /
• 2015

Marine sea water pump with impeller using carbon fiber block was developed to prevent the impeller corrosion by the salinity. A numerical analysis was carried out in order to optimize the impeller and volute design for marine sea water pump and to investigate the sensitivity of the related parameters(impeller thickness, surface roughness) using CFD commercial code. The impeller thickness is limited because of the weight. Since the impeller using the carbon fiber lights, the thickness which has a maximum efficiency can be used. The results show that the surface roughness leads to an 7% reduction in pump efficiency.

• Journal of the Korean Solar Energy Society
• /
• v.22 no.3
• /
• pp.57-65
• /
• 2002

The photocatalytic degradation of TCE using solar energy in POFR was studied. The use of solar energy was investigated in plastic optica fiber photocatalytic reactor (POFR). In POFR, the main parameters of photocatalytic degradation of TCE were lihgt intensity, thickness of $TiO_2$-coated film on plastic fiber core, the same of total $TiO_2$-coated surface area with changed length. We studied the apparent photonic efficiency and photocatalytic degradation rate of TCE in POFR. The apparent photonic efficiency of various light intensities was decreased by an incresed intensities. The photocatalytic activities of $TiO_2$-coated optical fiber reactor system depended on the coating thickness, and total clad-stripped surface area of POF. Photocatalytic degradation of trichloroethylene ($C_2HCl_3$, TCE) in the gas-phase was elucidated by using $TiO_2$-coated plastic optical fiber reactor. In TCE degradation, in-situ FTIR measurement resulted in mineralization into $CO_2$.

• Journal of the Korean Society for Precision Engineering
• /
• v.30 no.10
• /
• pp.1017-1022
• /
• 2013

Currently, various optical fiber tips are used to deliver laser beam for endoscopic surgery. In this paper, we demonstrated multidirectional (forward and side) firing optical fiber tip using a femtosecond micromachining and $CO_2$ laser polishing technology. We controlled the edge width of optical fiber tip, by modulating the condition of $CO_2$ laser, to regulate the amount of side and forward emission. The distal end of the optical fiber with core/clad diameter of $400/440{\mu}m$ was microstructured with cone shape by using a femtosecond laser. And then the microstructured optical fiber tip was polished by $CO_2$ laser beam result in smoothing and specular reflection at the surface of the cone structure. Finally, we operated the LightTools simulation and good agreement was generally found between the proposed model and experimental simulation.

• Korean Chemical Engineering Research
• /
• v.49 no.4
• /
• pp.443-448
• /
• 2011

The propellant has a short shelf-life because of nitrogen oxides that were released from nitrocellulose decomposition. As-received and surface-modified ACFs were applied to remove the nitrogen oxides with intend to extend the shelf-life of propellant. The specific surface area of modified ACFs was slightly decreased but nitrogen function groups such as pyridine, pyridone and pyrrol were created on the surface of ACFs. As a result, the NO removal capacity of the surface-modified ACF by propellant waste increased about twice than that of the as-received ACF. The shelf-life of propellant was extended about 1.25 times by accompanying surface-modified ACF.

• Bulletin of the Korean Chemical Society
• /
• v.34 no.11
• /
• pp.3307-3311
• /
• 2013

A new fiber optical sensor was developed for the determination of 2,4-dichlorophenol (DCP). The sensor was based on DCP oxidation by oxygen with the catalysis of iron(III) tetrasulfophthalocyanine (Fe(III)PcTs). The optical oxygen sensing film with $Ru(bpy)_3Cl_2$ as the fluorescence indicator was used to determine the consumption of oxygen in solution. A lock-in amplifier was used for detecting the lifetime of the oxygen sensing film by measuring the phase delay change of the sensor head. The different variables affecting the sensor performance were evaluated and optimized. Under the optimal conditions (i.e. pH 6.0, $25^{\circ}C$, Fe(III)PcTs concentration of 0.62 mg/mL), the linear detection range and response time of the sensor are $1.0{\times}10^{-6}-9.0{\times}10^{-6}$ mol/L and 250 s, respectively. The sensor displays high selectivity, good repeatability and stability, and can be used as an effective tool in analyzing DCP concentration in practical samples.

• Steel and Composite Structures
• /
• v.39 no.3
• /
• pp.307-318
• /
• 2021

Utilizing fibers is an effective way to avoid the brittle behavior of the conventional concrete and can enhance its ductility. In particular, propylene fibers can improve concrete properties, including energy absorption, physical and mechanical properties, controlling shrinkage cracks. The increase of fiber density leads to an increase of the overlapping surface of the fiber of concrete and, in turn, a decrease of cracks developed in the concrete. However, the workability of fiber reinforced concrete tends to be lower than the conventional concrete owing mainly to the hairline thickness and excessive concentration of fibers. The low slump of concrete impedes the construction of reinforced concrete members. In this research, we study if the utilization of magnetic water can alleviate the workability issue of young fiber reinforced concrete. To this end, the compressive and flexural strength of four types of concrete (conventional concrete, fiber reinforced concrete, magnetic concrete, magnetic fiber-reinforced concrete) is studied and compared at three different ages of 7, 14, and 28 days. In order to study the influence of the fiber density and length, a study on specimens with three different fiber density (1, 2, 5 kg of fiber in each cubic meter of concrete) and fiber length (6, 12, 18 mm) is undertaken. The result shows the magnetic fiber concrete can result in an increase of the flexural and compressive strength of concrete at higher ages.