• Composites Research
• /
• v.31 no.5
• /
• pp.186-191
• /
• 2018

Condition and properties of composites with different chemical structure of epoxy matrix were observed after saline solution treatment. Epoxy was used as matrix and the flexibility was controlled by using 2 typed-epoxies and 3 types hardeners (amine, acid anhydride and amide). Saline water treatment was conducted with 6 wt% NaCl solution at $60^{\circ}C$ for 0, 15, and 30 days. Cross section was observed and interfacial and mechanical and properties was evaluated. Amine type exhibited the highest crosslinking density and mechanical and interfacial properties whereas water absorbance was lowest. It is because that the water molecules can be hardly penetrate into the epoxy matrix or the interface between epoxy and glass fiber and it leads to saline water resistance of composites.

• Journal of Adhesion and Interface
• /
• v.13 no.1
• /
• pp.45-50
• /
• 2012

Recently developed polyketone fiber has various applications in the mechanical rubber goods as reinforcement because of its good mechanical properties. However, its surface is not suitable for good adhesion with the rubber matrix. Thus, a surface modification is essential to obtain the good interfacial adhesion. Plasma treatment, in this study, has been conducted to modify the surface of the polyketone fiber. The morphological changes of the fibers by oxygen plasma treatment were observed by using SEM and AFM. The chemical composition changes of PK fiber surface treated with oxygen plasma were investigated using an XPS (X-ray photoelectron spectroscopy). Finally, the effect of these changes on the interfacial adhesion between fiber and rubber was analyzed by using a microdroplet debonding test. By the plasma treatment, oxygen moieties on the fiber surface increased with processing time and power. The surface RMS roughness increases until the proper processing condition, but a long plasma processing time resulted in a rather reduced roughness because of surface degradation. When the treatment time and power were 60 s and 80 W, respectively, the highest interfacial shear strength (IFSS) was obtained between the PK fiber and natural rubber. However, as the treatment time and power were higher than 60 s and 80 W, respectively, the IFSS decreased because of degradation of the PK fiber surface by severe plasma treatment.

• Journal of Adhesion and Interface
• /
• v.10 no.4
• /
• pp.162-168
• /
• 2009

As a preliminary study of optimum composite properties under cryogenic temperature, the comparison of interfacial properties of carbon or glass fibers reinforced epoxy composites was evaluated at ambient and intermediate low temperature, i.e., 25 and $-10^{\circ}C$ by using micromechanical techniques. Under tensile and compressive loading conditions, their mechanical modulus at low temperature was higher than that atambient temperature. Interfacial shear strength (IFSS) at ambient and low temperatures was compared to each other, depending on epoxy matrix toughness and apparent modulus at the interface. The IFSS was much higher at low temperature than that at room temperature because of the increased epoxy matrix modulus. Statistical distributions of tensile strengths of glass and carbon fibers were evaluated for different temperature ranges, which is dependent upon fiber's inherent flaws and rigidity.

• Composites Research
• /
• v.23 no.1
• /
• pp.44-50
• /
• 2010

In this paper, two different experiments, namely, salt water spray and salt water immersion, were performed to reproduce the contact of composites with the seawater for three kinds of woven fabric composite material systems which would be used for the WIG(wing in ground effect)craft. After aging 140 days in the salt water environment, material properties of carbon/epoxy and glass/epoxy composite such as tensile, compressive and shear stiffness and strength, and inter-laminar shear strength (ILSS) were measured. By comparing baseline material properties with degraded ones, the effects of the salt water environment on the composite mechanical properties were evaluated. From the experiments, it was confirmed that the difference in aging conditions had very small influence on composite properties. And it was found that tensile strength of carbon/epoxy composites showed little degradation, but much more degradation was observed in glass/epoxy composites. And large degradations on matrix dominant properties were observed. The salt water could damage the fiber-matrix interface, matrix properties and the glass fiber.

• Journal of Adhesion and Interface
• /
• v.9 no.2
• /
• pp.16-23
• /
• 2008

In this study, novel waste wool/polypropylene NFRPs (natural fiber reinforced polymer composites), which are constituted with waste wool discarded as industrial scrap during manufacturing processes of woven fabrics and general purpose thermoplastic polypropylene (PP), were fabricated by means of compressionmolding and their mechanical and thermal properties were characterized. The mechanical properties of PP resin were significantly improved by an introduction of waste wool to PP. In particular, as the loading of waste wool was 50 vol% in the NFRP, the flexural strength of the NFRP was increased about 20%, the flexural modulus about 143%, the tensile strength about 76%, and the tensile modulus about 90% in comparison with each of PP control. In addition, the maximum value of the heat deflection temperature (HDT) obtained with the NFRP was $138^{\circ}C$ at a 50 vol% loading of waste wool. This is $21^{\circ}C$ higher than the HDT of PP control. The result here suggests that waste wool be a potential candidate for a reinforcing material of thermoplastic matrix resins.

• Journal of Adhesion and Interface
• /
• v.9 no.4
• /
• pp.1-11
• /
• 2008

In the present study, kenaf fibers were treated with sodium hydroxide using soaking and ultrasonic methods prior to biocomposite processing, respectively. The effect of alkali treatment on the kenaf-PLA interfacial adhesion and mechanical and thermal characteristics of kenaf/poly(lactic acid) biocomposites was investigated in terms of their interfacial shear strength, flexural properties, dynamic mechanical properties and thermal stability and also microscopic observations of kenaf fibers and the composite fracture surfaces. As a result, use of both soaking and ultrasonic methods for treating kenaf fiber surfaces played a role in increasing the fiber-matrix adhesion and the mechanical properties of the biocomposites. Their characteristics depended not only on the fiber surface treatment method but also on the treatment condition like alkali concentration and treatment time.

• The Journal of Advanced Prosthodontics
• /
• v.4 no.2
• /
• pp.103-108
• /
• 2012

PURPOSE. Debonding of a composite resin core of the fiber post often occurs at the interface between these two materials. The aim of this study was to evaluate the effects of different surface treatment methods on bond strength between fiber posts and composite core. MATERIALS AND METHODS. Sixty-four fiber posts were picked in two groups (Hetco and Exacto). Each group was further divided into four subgroups using different surface treatments: 1) silanization; 2) sandblasting; 3) Treatment with 24% $H_2O_2$, and 4) no treatment (control group). A cylindrical plexiglass matrix was placed around the post and filled with the core resin composite. Specimens were stored in 5000 thermal cycles between $5^{\circ}C$ and $55^{\circ}C$. Tensile bond strength (TBS) test and evaluation using stereomicroscope were performed on the specimen and the data were analyzed using two-way ANOVA, Post Hoc Scheffe tests and Fisher's Exact Test (${\alpha}$=.05). RESULTS. There was a significant difference between the effect of different surface treatments on TBS ($P$ <.001) but different brands of post ($P$=.743) and interaction between the brand of post and surface treatment ($P$=.922) had no significant effect on TBS. Both silanization and sandblasting improved the bonding strength of fiber posts to composite resin core, but there were not any significant differences between these groups and control group. CONCLUSION. There was not any significant difference between two brands of fiber posts that had been used in this study. Although silanization and sandblasting can improve the TBS, there was not any significant differences between surface treatments used.

• Journal of the Korea Concrete Institute
• /
• v.17 no.5 s.89
• /
• pp.709-716
• /
• 2005

The objective of this study is to develop a high ductile fiber reinforced mortar, ECC(Engineered Cementitious Composite) with using raw material commercially available in Korea. A single fiber pullout test and a wedge splitting test were employed to measure the bond properties in a matrix and the fracture toughness of mortar matrix respectively, which are used for designing mix proportion suitable for achieving strain-hardening behavior at a composite level. Test results showed that the properties tended to increase with decreasing water-cement ratio. A high ductile fiber reinforced mortar has been developed by employing micromechanics-based design procedure. Micromechanical analysis was initially peformed to properly select water-cement ratio, and then basic mixture proportion range was determined based on workability considerations, including desirable fiber dispersion without segregation. Subsequent direct tensile tests were performed on the composites with W/C's of 47.5% and 60% at 28 days that the fiber reinforced mortar exhibited high ductile uniaxial tension property, represented by a maximum strain capacity of 2.2%, which is around 100 times the strain capacity of normal concrete. Also, compressive tests were performed to examine high ductile fiber reinforced mortar under the compression. The test results showed that the measured value of compressive strength was from 26MPa to 34 MPa which comes under the strength of normal concrete at 28 days.

• Composites Research
• /
• v.36 no.1
• /
• pp.1-15
• /
• 2023

Demand for energy consumption reduction is increasing according to the development expectations of future mobility. Lightweight structural materials are known as a method to reduce greenhouse gas emissions and improve energy efficiency. In particular, fiber reinforced polymer composite (FRP) is attracting attention as a material that can replace existing metal alloys due to its excellent mechanical properties and light weight. In this paper, industrial applications and research trends of carbon fiber reinforced composites (CFRP, carbon FRP) and self-reinforced composites (SRC) were reviewed based on the reinforcement, polymer matrix, and manufacturing process. In order to overcome the expensive process cost and long manufacturing time of the epoxy resin-based autoclave method, which is mainly used in the aircraft field, mass production of CFRP-applied electric vehicles has been reported using a high-pressure resin transfer molding process including fast-curing epoxy. In addition, thermoplastic resin-based CFRP and interface enhancement methods to solve the recycling issue of carbon fiber composites were reviewed in terms of materials and processes. To form a perfect matrix-reinforcement interface, which is known as the major factor inducing the excellent mechanical properties of FRP, studies on SRC impregnated with the same matrix in polymer fibers have been reported. The physical and mechanical properties of SRC based on various thermoplastic polymers were reviewed in terms of polymer orientation and composite structure. In addition, a copolymer matrix strategy for extending the processing window of highly drawn polypropylene fiber-based SRC was discussed. The application of CFRP and SRC as lightweight structural materials can provide potential options for improving the energy efficiency of future mobility.

• Journal of Adhesion and Interface
• /
• v.13 no.2
• /
• pp.58-63
• /
• 2012

CFRP chip is the byproduct from carbon fiber reinforced plastic (CFRP) processing. CFRP chip is not simply a waste mainly composed of fine carbon fiber and epoxy resin. CFRP chip keeps matrix to maximize their reinforcing effect. To obtain a uniform length of carbon fiber in CFRP chip, chip was chopped ina mortar. CFRP chip should be purified to get better interface adhesion. Epoxy resin on the carbon fiber was removed by $H_2O_2$ surface etching treatment. Optimal dispersion and fabrication conditions of CFRP chip embedded in phenolic resin were determined by thermal stability for fire retardant applications. CFRP chip-phenolic composite exhibits better mechanical and thermal properties than neat phenolic resin. Surface condition of CFRP chip-phenolic composite was evaluated by static contact angle measurement. Contact angle of CFRP chip-phenolic composite was greater than neat phenolic due to heterogeneous condition of fine carbon fibers. From the evaluation for fire retardant (ASTM D635-06) test, thermal stability of CFRP chip-phenolic composite was found to be improved with higher concentration of CFRP chip.