• Title/Summary/Keyword: Fiber electrode

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Electrosorption and Separation of $Co^{2+}$ and $Sr^{2+}$ Ions from Decontaminated Liquid Wastes

  • Kim, Jun-Soo;Jung, Chong-Hun;Oh, Won-Zin;Ryu, Seung-Kon
    • Carbon letters
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    • v.3 no.1
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    • pp.6-12
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    • 2002
  • A study on the electrosorption of $Co^{2+}$ and $Sr^{2+}$ ions onto a porous activated carbon fiber (ACF) was performed to treat radioactive liquid wastes resulting from chemical or electrochemical decontamination and to regenerate the spent carbon electrode. The result of batch electrosorption experiments showed that applied negative potential increased adsorption kinetics and capacity in comparison with open-circuit potential (OCP) adsorption for $Co^{2+}$ and $Sr^{2+}$ ions. The adsorbed $Co^{2+}$ and $Sr^{2+}$ ions are released from the carbon fiber by applying a positive potential on the electrode, showing the reversibility of the sorption process. The possibility of application of the electrosorption technique to the separation of radionuclides was examined. The result of a selective removal experiments of a single component from a mixed solution showed that perfect separation of $Co^{2+}$ and $Sr^{2+}$ ions was possible by the electrosorption process.

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A Study on Enhancement of Np Extraction by TBP Through the Electrochemical Adjustment of Np Oxidation State by Using a Glassy Carbon Fiber Column Electrode

  • Kim, Kwang-Wook;Song, Kee-Chan;Lee, Eil-Hee;Park, In-Kyu;Yoo, Jae-Hyung
    • Nuclear Engineering and Technology
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    • v.32 no.4
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    • pp.309-315
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    • 2000
  • The changes of Np oxidation state in nitric acid and the effect of nitrous acid on the oxidation state were analyzed by spectrophotometry, solvent extraction, and electrochemical methods. An enhancement of Np extraction to 30 vol.% TBP was carried out through adjustment of Np oxidation state by using a glassy carbon fiber column electrode system. The information of electrolytic behavior of nitric acid was important because the nitrous acid affecting the Np redox reaction was generated during the electrolytic adjustment of the Np oxidation state. The Np solution used in this work consisted of Np(V) and Np(Ⅵ)without (IV). The composition of Np(V) in the range of 0.5M -5.5 M nitric acid was 32% ~ 19%. The electrolytic oxidation of Np(V) to Np(Ⅵ)in the solution enhanced Np extraction efficiency about five times higher than the case without the electrolytic oxidation. It was confirmed that the nitrous acid of less than about 10-5 M acted as a catalyst to accelerate the chemical oxidation reaction of Np(V) to Np(Ⅵ).

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Crack Detection of Carbon Fiber Reinforced Composites by Electric Potential Method with Bridge Circuit Concept (브리지 회로 개념이 적용된 전기 전위법을 이용한 탄소섬유복합재료의 균열검출)

  • Hwang, Hui-Yun
    • Composites Research
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    • v.22 no.1
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    • pp.9-14
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    • 2009
  • This paper suggested the electric potential method with a bridge circuit concept for the detection of the location and crack growth of carbon fiber reinforced composites to reduce the measurement numbers. 2 pairs of electrodes were fabricated on the center cracked thin composite plates, and potential changes at one pair of adjacent electrodes were observed while external voltage input was applied to the other pair of adjacent electrodes. The effects of the size and interval of electrodes, location and propagating direction of center cracks were investigated by experiments and finite element analyses. Detectable crack size was influenced by the electrode interval rather than the electrode size, and crack detection was enhanced as the size and interval of electrodes were smaller. Besides, output potential changes were larger as the crack grew and was nearer the voltage input electrodes.

Continuous Photonic RF True-time Delay Using a Side-polished Fiber Bragg Grating with Heating Electrode (측면 연마된 광섬유 브래그 격자를 이용한 연속적인 광학적 RF 실시간 지연)

  • Chae, Ho-Dong;Kim, Do-Hwan;Kim, Hyoung-Jun;Lee, Sang-Shin;Kim, Hyo-Kyeom;Lee, Kyu-Hyo;Kim, Kwang-Taek
    • Korean Journal of Optics and Photonics
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    • v.15 no.6
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    • pp.591-596
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    • 2004
  • In this paper, a photonic RF true-time delay based on a partially side-polished fiber Bragg grating with heating electrode has been proposed and fabricated. It features continuous voltage-controlled operation, requiring no mechanical perturbation and no moving parts. For an RF signal carried over an optical signal, the time delay has been obtained by controlling the voltage applied to the electrode and thus adjusting its reflection positions from the fiber grating via the thermooptic effect. The achieved time delay is about 100 ps with the electrical power consumption of 280 mW.

The Electrochemical Characteristics of Mesopore Active Carbon Fiber for EDLC Electrode (EDLC 전극용 메조기공 활성탄소 섬유의 전기화학적 특성)

  • Kang, Chae-Yoen;Shin, Yun-Sung;Lee, Jong-Dae
    • Korean Chemical Engineering Research
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    • v.49 no.1
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    • pp.10-14
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    • 2011
  • The electrode material performances of electric double layer capacitor(EDLC) were investigated using mesopous active carbon fiber(ACF), which was prepared by the iron exchange method. The mesoporous ACF had pore characteristics of specific surface area around 1249, 664 $m^2$/g, mesoporous fraction around 70.6-81.3% and meanpore size around 2.78-4.14 nm. The results showed that as HNO3 treatment time decreased, the specific surface area increased and mesoporous fraction decreased. To investigate electrochemical performance of EDLC, unit cell was manufactured using mesoporus ACF, conducting material and binder; organic elctrolyte was used on this experiment. The specific capacitance of ACF treated with HNO3 for 2 hours turned out to be 0.47 $F/cm^2$and the results of the cyclic charge-discharge tests were stable. Thus, the electrochemical performance of EDLC was mainly dependent on specific surface area of ACF electrode and the diffusion resistance of charge decreased as the mesopore increased.

Electrosorption of U(VI) by Surface-Modified Activated Carbon Fiber (표면처리 활성탄소섬유에 의한 U(VI)의 전기흡착)

  • Lee, Yu Ri;Jung, Chong Hun;Ryu, Seung Kon;Oh, Won Zin
    • Korean Chemical Engineering Research
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    • v.43 no.1
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    • pp.60-65
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    • 2005
  • The electrosorption of U(VI) from waste water was carried out by using activated carbon fiber(ACF) felt electrode in a continuous electrosorption cell. In order to enhance the electrosorption capacity at lower potential, ACF felt was chemically modified in acidic, basic and neutral solution. Pore structure and functional groups of chemically modified ACF were examined, and the effect of treatment conditions was studied for the adsorption of U(VI). Specific surface area of all ACFs decreases by this treatment. The amount of acidic functional groups decreases with basic and neutral salt treatment, while the amount increases a lot with acidic treatment. The electrosorption capacity of U(VI) decreases on using the acid treated electrode due to the shielding effect of acidic functional groups. Base treated electrode enhances the capacity due to the reduction of acidic functional groups. The electrosorption amount of U(VI) on the base treated electrode at -0.3 V corresponds to that of ACF electrode at -0.9 V. Such a good adsorption capacity was not only due to the reduction of shielding effect but also the increase of $OH^-$ in the electric double layer on ACF surface by the application of negative potential.

Preparation and Characterization of transparent electrode based on polymer/metal oxide composite via electrospinning (전기 방사를 이용한 고분자/금속산화물 복합소재 기반의 투명전극 제조 및 특성 분석)

  • Kang, Hye Ju;Jeong, Hyeon Taek
    • Journal of the Korean Applied Science and Technology
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    • v.38 no.6
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    • pp.1553-1560
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    • 2021
  • We have confirmed that optimized transmittance and surface resistance by electrospinning time, also the fabricated transparent electrode composed of silver nanofiber with excellent electrical, optical and mechanical performances is showed applicability to next generation flexible displays such as solar cells, displays, and touch screens. → We have confirmed the optimized transmittance and surface resistance by electrospinning time Also the fabricated transparent electrode composed of silver nanofiber with excellent electrical, optical and mechanical performances showed applicability to next generation flexible displays such as solar cells, displays, and touch screens.

Development of 5Gbps Ti:LiNbO$_3$ Mach-Zehnder Interferometric Optical Modulator for High-speed Optical Communications (초고속 광통신용 5Gbps 급 Ti:LiNbO$_3$ Mach-Zehnder interferometric 광변조기 개발)

  • 김성구;윤형도;윤대원;유용택
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.11a
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    • pp.477-479
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    • 1997
  • The preparation of mach-zehnder inteferometric optical modulator and the properties of electrode and modulation bandwidth for high speed optical communications were described. The results of fabricated optical modulator was that optical 3-dB bandwidth 4.7GHz, driving voltage 6V and fiber-waveguide-fiber insertion loss 4.5dB for TM mode respectively.

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Effect of carbonization temperature of AC/C composite electrode on electro double layer capacitor (탄화온도가 상이한 활성탄소 복합제 전극이 전기이중층 케페시터의 층방전 특성에 미치는 영향)

  • Jo, Young-Keun;Jung, Doo-Hwan;Kim, Chang-Soo;Park, So-Jin
    • Proceedings of the KIEE Conference
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    • 1999.07d
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    • pp.1821-1823
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    • 1999
  • Carbon is an attractive material on electro double capacitor which depend on charge storage in the electrode/electrolyte interfacial double layer. Carbonaceous material for double layer capacitor can be obtained from carbon powder, fiber, film and porous carbon sheet. The capacitance of electrodes using an activated carbon was influenced by a filling density of the carbon, thickness and internal resistance of the electrode. In this study. to reduce internal resistance and increase electric conductivity of the electrode. activated carbon/carbon(AC/C) composite electrode was fabricated. The capacitors which have energy densities of 68F/g(at $30^{\circ}C$), 109F/g(at $60^{\circ}C$) and $68F/cm^3$(at $30^{\circ}C$), $111F/cm^3$(at $60^{\circ}C$) were fabricated by using AC/C composite electrodes.

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