• 제목/요약/키워드: Fiber Degradation

검색결과 460건 처리시간 0.042초

Effect of Carbon Fiber Layer on Electrochemical Properties of Activated Carbon Electrode

  • Jong kyu Back;Jihyeon Ryu;Yong-Ho Park;Ick-Jun Kim;Sunhye Yang
    • Journal of Electrochemical Science and Technology
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    • 제14권2호
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    • pp.184-193
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    • 2023
  • This study investigates the effects of a carbon fiber layer formed on the surface of an etched aluminum current collector on the electrochemical properties of the activated carbon electrodes for an electric double layer capacitor. A particle size analyzer, field-emission SEM, and nitrogen adsorption/desorption isotherm analyzer are employed to analyze the structure of the carbon fiber layer. The electric and electrochemical properties of the activated carbon electrodes using a carbon fiber layer are evaluated using an electrode resistance meter and a charge-discharge tester, respectively. To uniformly coat the surface with carbon fiber, we applied a planetary mill process, adjusted the particle size, and prepared the carbon paste by dispersing in a binder. Subsequently, the carbon paste was coated on the surface of the etched aluminum current collector to form the carbon under layer, after which an activated carbon slurry was coated to form the electrodes. Based on the results, the interface resistance of the EDLC cell made of the current collector with the carbon fiber layer was reduced compared to the cell using the pristine current collector. The interfacial resistance decreased from 0.0143 Ω·cm2 to a maximum of 0.0077 Ω·cm2. And degradation reactions of the activated carbon electrodes are suppressed in the 3.3 V floating test. We infer that it is because the improved electric network of the carbon fiber layer coated on the current collector surface enhanced the electron collection and interfacial diffusion while protecting the surface of the cathode etched aluminum; thereby suppressing the formation of Al-F compounds.

Effect of Electrochemical Oxidation Potential on Biofilter for Bacteriological Oxidation of VOCs to $CO_2$

  • Kang Hye-Sun;Lee Jong-Kwang;Kim Moo-Hoon;Park Doo-Hyun
    • Journal of Microbiology and Biotechnology
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    • 제16권3호
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    • pp.399-407
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    • 2006
  • In this study, an electrical conductive carbon fiber was used as a biofilter matrix to electrochemically improve the biofilter function. A bioreactor system was composed of carbon fiber (anode), titanium ring, porcelain ring, inorganic nutrient reservoir, and VOC reservoir. Electric DC power of 1.5 volt was charged to the carbon fiber anode (CFA) to induce the electrochemical oxidation potential on the biofilter matrix, but not to the carbon fiber (CF). We tested the effects of electrochemical oxidation potential charged to the CFA on the biofilm structure, the bacterial growth, and the activity for metabolic oxidation of VOCs to $CO_2$, According to the SEM image, the biofilm structure developed in the CFA appeared to be greatly different from that in the CF. The bacterial growth, VOCs degradation, and metabolic oxidation of VOCs to $CO_2$ in the CFA were more activated than those in the CF. On the basis of these results, we propose that the biofilm structure can be improved, and the bacterial growth and the bacterial oxidation activity of VOCs can be activated by the electrochemical oxidation potential charged to a biofilter matrix.

THE INFLUENCE OF SELECTED CHEMICAL TREATMENTS ON THE RUMINAL DEGRADATION AND SUBSEQUENT INTESTINAL DIGESTION OF CEREAL STRAW

  • Wanapat, M.;Varvikko, T.;Vanhatalo, A.
    • Asian-Australasian Journal of Animal Sciences
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    • 제3권2호
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    • pp.75-83
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    • 1990
  • An experiment was conducted with three ruminally and intestinally cannulated non-lactating cows of Finnish Ayrshire breed, to assess the ruminal degradation characteristics of oat (Avena sativa), rye (Secale cereale) and rice (Oryza sativa) straw by the nylon bag technique, and the subsequent post-ruminal degradation of their rumen-undegraded residues by using the mobile bag technique, respectively. The straw samples were untreated or treated with aqueous $NH_3$ or with urea solution in cold or hot water. The untreated straw samples were milled or chopped, and the treated straw samples were chopped. The constant values a, b, and c were computed according to the exponential equation, where a = intercept of degradation curve at time 0, b = potentially degradable material, c = rate of degradation of band (a+b) = maximum potential degradability (asymptote). It was found that nitrogen contents of chemically treated straw were markedly increased by both $NH_3$ and urea treatments. Milling the samples attributed to a remarkable loss at 0 h incubation time as compared to chopping of the respective samples. However, chemical treatment markedly improved the b value and the subsequent (a+b) values for dry matter, organic matter, neutral-detergent fiber, and acid-detergent fiber of the samples. Furthermore, temperature of the water used in the urea solutions was considered essential, since urea in hot water rather than in cold water seemed to enhance the overall degradability. The disappearance of rumen-incubated straw residues from the mobile bags ranged from 4.5 to 9.6% for the parameters measured. On average, the OM disappearance from bags was clearly higher for the residues of urea treated straw compared to those of ammonia treated straw, but the disappearance of NDF tended, however, to be higher on the ammonia treatment.

Poly(vinyl alcohol)/ Sodium Alginate 블렌드의 제조 및 특성 (Preparation and Characterization of Poly(vinyl alcohol)/ Sodium Alginate Blend)

  • Koo, Won-Mi;Jung, Du-Kam;Lee, Young-Hee;Kim, Han-Do
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 2001년도 가을 학술발표회 논문집
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    • pp.25-28
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    • 2001
  • Polymer blending constitutes a most useful method for the improvement or modification of the physicochemical properties of polymeric materials. Some of the polymer blends exhibit unusual properties, unexpected from homopolymers. An important property of a polymer blend is the miscibility of its component, because it affects the mechanical properties, the morphology, its permeability and degradation [1, 2]. (omitted)

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Self compacting reinforced concrete beams strengthened with natural fiber under cyclic loading

  • Prasad, M.L.V;saha, Prasenjit;Kumar, P.R.
    • Computers and Concrete
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    • 제17권5호
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    • pp.597-612
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    • 2016
  • The present work focuses on the use of coconut fiber in self compacting concrete. Self-Compacting Concrete (SCC) is a highly flowable, stable concrete which flows readily into place, filling formwork without any consolidation and without undergoing any significant segregation. Use of fibers in SCC bridge the cracks and enhance the performance of concrete by not allowing cracks to propagate. They contribute to an increased energy absorption compared to plain concrete. Coconut fiber has the highest toughness among all natural fibers. It is known that structures in the seismic prone areas are always under the influence of cyclic loading. To justify the importance of strengthening SCC beams with coir fiber, the present work has been undertaken. A comparison is made between cyclic and static loading of coconut fiber reinforced self compacting concrete (FRSCC) members. Using the test data obtained from the experiment, hysteresis loops were drawn and comparison of envelope curve, energy dissipation, stiffness degradation were made and important conclusions were draw to justify the use of coconut fiber in SCC.

Effect of Fiber Dispersion and Self-phase Modulation in Multi-channel Subcarrier Multiplexed Optical Signal Transmission

  • Kim, Kyoung-Soo;Jeong, Ji-Chai;Lee, Jae-Hoon
    • Journal of the Optical Society of Korea
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    • 제14권4호
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    • pp.351-356
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    • 2010
  • We investigated the combined effect of fiber chromatic dispersion and self-phase modulation (SPM) in multi-channel subcarrier multiplexed (SCM) optical transmission systems. We theoretically analyzed the transmission characteristics of the SCM signals with the effect of SPM and chromatic dispersion in a single-mode optical fiber by numerical simulations based on the nonlinear Schrodinger equation. The numerical simulation results revealed that the effect of fiber dispersion and SPM could occur independently between subcarrier channels in two-channel SCM systems for small optical modulation index (OMI) and large channel spacing. However, for large OMI, small channel spacing, and large fiber launching power, we found a performance degradation of the two-channel system compared to that of a single-channel system. These parameters are therefore important for the optimization of multi-channel SCM systems applicable to radio over fiber networks.

핫프레스 공정 기반 CF-PEKK 복합재의 근적외선 고속가열에 의한 열적 열화 반응의 메커니즘 분석 (Analysis of Thermal Degradation Mechanism by Infrared High-speed Heating of CF-PEKK Composites in Hot Press Forming)

  • 이교문;박수정;박예림;박성재;김윤해
    • Composites Research
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    • 제35권2호
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    • pp.93-97
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    • 2022
  • 열가소성 복합재의 핫프레스 성형공정에서 근적외선 가열의 적용은 소재를 성형온도까지 고속가열함으로써 공정 전체의 생산성을 확보할 수 있으나, 고에너지, 높은 성형온도, 고속가열에 의해 소재의 열화가 발생하여 재용융 성능 등의 소재 특성이 저하될 수 있다. 이에 본 연구는 고성능 항공소재로 활발히 연구개발되고 있는 Carbon fiber reinforced Polyetherketoneketone(CF/PEKK) 복합재에 적합한 핫프레스 성형공정의 최적화된 공정조건을 확립하기 위하여 근적외선 고속가열을 적용하였을 때, CF/PEKK 복합재에서 발생할 수 있는 열화 메커니즘과 그 특성을 형태학적, 열적 특성 및 기계적 성능 시험을 통해 평가하였다. 열화 반응에 따른 메커니즘 규명은 광학현미경을 활용하여 PEKK의 결정구조의 형태학적 조사를 기반으로 분석하였다. 그 결과, 열화가 진행됨에 따라 구결정의 크기가 감소하며 최종적으로 완전 열화 시 구결정이 소멸되는 것을 확인하였다. 열적 특성은 용융온도, 결정화온도, 발열량이 열화가 진행됨에 따라 감소하는 경향이 관찰되며, 460℃ 장시간 노출에서 결정구조가 소멸된 것을 확인하였다. 랩전단강도(Lap shear strength)시험 결과, 열화된 표면에서는 낮은 접합강도가 관찰되며, 접합면 분석에서 특정 면에서는 열에 의한 용융 특성이 나타나지 않았다. 결론적으로 CF/PEKK 복합재의 근적외선 고속가열 적용에 있어 특정 온도에서 열화 진행되며, 이에 구결정의 형태학적 변화와 열가소성 소재의 재용융 특성의 저하를 확인하였다.

Epoxidized Polybutadiene as a Thermal Stabilizer for Poly(3-hydroxybutyrate). II. Thermal Stabilization of Poly(3-hydroxybutyrate) by Epoxidized Polybutadiene

  • Choi, Ju-Yol;Lee, Jong-Keun;You, Young;Park, Won-Ho
    • Fibers and Polymers
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    • 제4권4호
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    • pp.195-198
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    • 2003
  • Epoxidized polybutadiene (EPB) was prepared by polybutadiene (PB) with m-chloroperbenzoic acid (MCPBA) in homogeneous solution. EPB was blended with poly(3-hydroxybutyrate) (PHB) up to 30 wt% by solution-precipitation procedure. The thermal decomposition of PHB/EPB blends was studied by thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) and differential thermal analysis (DTA). The thermograms of PHB/EPB blends contained a two-step degradation process, while that of pure PHB sample exhibited only one-step degradation process. This degradation behavior of PHB/EPB blends, which have a higher thermal stability as measured by maximum decomposition temperature and residual weight, is probably due to crosslinking reactions of the epoxide groups in the EPB component with the carboxyl chain ends of PHB fragments during the degradation process, and the occurrence of such reactions can be assigned to the exothermic peaks in their DTA thermograms.

Faraday Rotator Glass 광섬유 전류센서 (Fiber-Optic Current Sensor Using a Faraday Rotator Glass Fiber Sensor Coil)

  • 김기혁;송민호
    • 조명전기설비학회논문지
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    • 제18권4호
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    • pp.28-33
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    • 2004
  • 전력계통 시스템의 대전류 측정용으로 편광 분석형 광섬유 전류센서를 제작하였다. 선형복굴절에 의한 출력의 왜곡을 최소화하기 위하여 FRG 광섬유를 센서코일로 사용하였으며, 다양한 광원을 이용하여 광원에 따른 출력 노이즈 비교분석을 수행하였다. FRG광섬유 센서코일에 기계적 변형을 인가한 경우 $\pm$0.4(%) 이내의 출력안정도를 얻었으며, ASE 광폭 광원을 사용할 경우 단일모드 레이저에 비해 23(㏈) 정도의 노이즈 감쇄 효과를 얻을 수 있음을 확인하였다.