• Resources Recycling
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• v.9 no.1
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• pp.36-43
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• 2000

This study was carried out for treatment and reuse of inorganic sludge from Fenton process at B dyeing wastewater treatment plant. The parameters for pilot-scale treatment system were derived from the results of this study. It was found that $COD_{cl}$ of the treated effluent became lower than 100 mg/l approximately on the optimal reaction condition. 2nd sludge which was generated after redissolving sludge was analyzed, and it showed that reduction ratio of ash in 2nd sludge and total dry sludge weight in comparison with current sludge were 85% and 65%. Also Fe salt in sludge was redissolved about 90~95% of initial Fe by weight. It was estimated almost ￦350,000,000 for sludge reuse process. It was estimated saving of about ￦1,300,000 per day (￦420,000,000 per year) in operating cost based on 30,000 $m^3$/d treatment, which these were about ￦430,000 per day in chemical, ￦1,100,000 per day in sludge transportation and ￦200,000 per day in equipment maintenance. Payback period with interest charge for investment cost was estimated about 10.5 months. Also, net present value (NPV) was ￦792,000,000 and internal rat of return (IRR) was about 110%.

• Clean Technology
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• v.5 no.1
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• pp.20-29
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• 1999

In the treatment of Cu - and CN - contained wastewater by using Fenton oxidation-flocculation-precipitation, the optimal removal efficiencies of the cyanide and copper were investigated according to pH, reaction time, the molar ratio of cyanide and hydrogen peroxide and the mass ratio of ferrous sulfate and hydrogen peroxide for Fenton oxidation, and pH for hydroxide precipitation, respectively. As a result, the $CN^-$ removal efficiency in our experimental wastewater by the Fenton oxidation was 81.2%~99% at its optimal conditions of pH ranging from 3 to 5 and reaction time of 30 minutes. And the optimal dosage of hydrogen peroxide and ferrous sulfate was 214, $428mg/{\ell}$, 107, $161mg/{\ell}$, 214, $214mg/{\ell}$ and 520, $500mg/{\ell}$, respectively when the molar ratio of $Cu^{2+}$:CN is 2:1, 1:1, 1:2, 1:10, and was 900, $1050mg/{\ell}$ when the molar ratio of $Cu^+$: CN is 1:10. When the copper was precipitated by sodium hydroxide after Fenton oxidation, the copper removal efficiency in the wastewater at pH 7 was 98.92%, 98.52%, 92.46%, 90.6% and 95%, respectively.

• Journal of Korean Society of Environmental Engineers
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• v.31 no.1
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• pp.9-14
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• 2009

In this research, a polyester manufacturing company (i.e. K Co.) in Gumi, South Korea was investigated regarding the release of high concentrations of 1,4-dioxane(about 600 mg/L) and whether treatment prior to release should occur to meet with the level of the regulation standard (e.g., 5 mg/L in 2011). The pilot-scale (reactor volume, 10 $m^3$) treatment system using Photo-Fenton Oxidation was able to remove approximately 90% of 1,4-dioxane under the conditions that concentrations of 2,800 ppm $H_2O_2$ and 1,400 ppm $FeSO_4$ were maintained along with 10 UV-C lamps (240 ${\mu}W/cm^2$) illuminated during aeration. However, the effluent concentration of 1,4-dioxane was still high at about 60 mg/L. Thus, further investigation is needed to see whether the bench scale (reactor volume, 8.9 L) of activated sludge could facilitate the decomposition of 1,4-dioxane. As a result, 1,4-dioxane in the effluent has been decreased as low as about 2~3 mg/L. Consequently, Photo-Fenton Oxidation coupled with activated sludge process can make it possible to efficiently decompose 1,4-dioxane to keep up with that of the regulation standard.

• Journal of Soil and Groundwater Environment
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• v.10 no.4
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• pp.18-25
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• 2005

Characteristics of phenanthrene removal in an electrokinetic (EK)-Fenton process were investigated in a viewpoint of concentration and ionic strength of electrolytes. When three kinds of electrolytes (NaCl, $KH_2PO_4,\;and\;MgSO_4$) were used, the increase in electrolyte concentration caused the decrease of electrical potential gradient. The increase of electrical conductivity was due to the increase of ionic concentration in soil. The decrease of accumulated electroosmotic flow (EOF) with increase in electrolyte concentration was due to the decrease of zeta potential. The removal efficiency was in proportion to accumulated EOF which depended on ionic strength. Total energy expenditure without electrolyte was 10-30 times higher than its with 0.5 M electrolyte. The lower removal efficiency was caused by the lower energy expenditure with 0.5 M one. An effective EK-Fenton process was determined from considering the removal efficiency and the energy expenditure, simultaneously.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2000.05a
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• pp.145-148
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• 2000

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2007.05a
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• pp.34-34
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• 2007

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2019.05a
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• pp.301-302
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• 2019

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2018.11a
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• pp.404-405
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• 2018

• Environmental Engineering Research
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• v.12 no.5
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• pp.238-243
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• 2007

The Fenton reaction, which refers to the reaction between ferrous ions and hydrogen peroxide to produce the OH radical, has not been widely applied to the disinfection of microorganisms despite being economic and environmentally friendly. Cho et al. have previously proposed the neutral photo ferrioxalate system as a solution to the problems posed by the Fenton reaction in acidic conditions, but this system still requires an external hydrogen peroxide supply. In the present study, we developed a simple disinfection technology using the photo or solar ferrioxalate reaction without the need for an external hydrogen peroxide supply. E. coli was employed as the indicating microorganism. The study results demonstrated the effectiveness of the photo ferrioxalate system in inactivating E. coli without any external hydrogen peroxide supply, as long as dissolved oxygen is supplied. Furthermore, the solar ferrioxalate system achieved faster inactivation of E. coli than an artificial light source at similar irradiance.

• Journal of Dairy Science and Biotechnology
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• v.38 no.3
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• pp.134-141
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• 2020

Oxidative stress is a cascade reaction characterized by a significant increase in the amount of oxidized components. Free radicals produced by oxidative stress are one of the common features in several experimental models of disease, and contribute to wide range of neurodegenerative diseases, including Alzheimer's disease. Iron (II) species can participate in the Fenton, and Fenton-like reactions, to react with hydrogen peroxide and generate hydroxyl radical. As iron accumulation and oxidative stress are associated with the pathological progression of neurodegenerative diseases, iron chelation and antioxidant therapies have become strategies to combat these diseases. Due to the complexity of the redox system in vivo, a multifaceted approach may be an attractive therapeutic strategy. Further investigations are highly expected for the prevention and treatment of neurodegenerative diseases in future.