• 한국신재생에너지학회:학술대회논문집
• /
• 2010.11a
• /
• pp.115.2-115.2
• /
• 2010

Autothermal reforming(ATR) processes of hydrocarbon liquids such as diesel fuels are spotlighted as methods to produce hydrogen for Fuel cell. However, the use of heavy hydrocarbons as feedstocks for hydrogen production causes some problems which increase the catalyst deactivation by the carbon deposition. Coking can be inhibited by increasing the water dissociation on the catalyst surface. This results in catastrophic failure of whole system. Performance degradation of diesel autothermal reforming leads to increase of undesirable hydrocarbons at reformed gases and subsequently decrease the performance. In this study, perovskite-based catalysts were investigated as alternatives to substitute the noble metal catalyst for the ATR of diesel. The investigated perovskite structure was based on LaCrO3. and metals were added at the A-site to enhance oxygen ion mobility, transition metals were doped on the B-site to enhance the reformation. Substituted Lanthanum chromium perovskite were made by aqueous combustion synthesis, which can produce high surface area. And for the homogeneous fuel supply, we made ultrasonic injection system for reforming. We compared durability of evaporation system and ultrasonic system for fuel injection.

• 한국생물공학회:학술대회논문집
• /
• 2001.11a
• /
• pp.249-252
• /
• 2001

The green algae, Botryococcus braunii, has an unusually high hydrocarbon content, ranging from 15 to 75% of dry weight, as a long-chain unsaturated hydrocarbon. It has a potential as a renewable source of chemical feedstocks or fuels. The commercial production of hydrocarbon by B. braunii has not been achieved mainly due to their economic and several technical barriers. The B. braunii cultivation with piggery wastewater could alleviate to economic problems by the reduction of inorganic nutrients, mainly nitrogen and phosphorus from wastewater. We have been studying cultivation of B. braunii in the pretreated piggery wastewater by a MBR(membrane bioreactod, containing about 3000 mg $NO^3$ /L, 15 mg $NH_4\;^+/L$, 3 mg P/L, and others. The purpose of this study was to develop a continuous culture system in piggery wastewater and nitrogen-limited chemostat.

• Journal of Energy Engineering
• /
• v.11 no.1
• /
• pp.34-46
• /
• 2002

Carbon accounting is a key issue in the discussions on global warming/CO$_2$mitigation. This paper applies both the IPCC Approach and the NEAT (Non-Energy use Emission Accounting Tables) model, a bottom-up approach, to estimate the potential CO$_2$ emissions (carbon storage) originating from the non-energy use as to assess the actual CO$_2$ emissions (carbon release) from the use of fossil fuels in Korea. The current Korean carbon accounting seems to overestimate the potential CO$_2$ emissions and with it to underestimate the actual CO$_2$ emissions. The estimation shows that the potential CO$_2$ emissions calculated according to the IPCC Approach are lower than those calculated using the NEAT model. This is because the IPCC default storage fraction for naphtha seems to be low for the Korean petrochemical production structure, on the one hand and because the IPCC Approach does not consider the trade with short life petrochemical products, on the other hand. This paper shows that a bottom-up approach like the NEAT model can contribute to overcome some of limitations of the IPCC guidelines, especially by considering the international trade with short life petrochemical products and by estimating the storage fractions of fossil fuels used as feedstocks for the country in consideration. This paper emphasizes the importance of accurate energy statistics for carbon accounting.

• Journal of Microbiology and Biotechnology
• /
• v.27 no.1
• /
• pp.77-83
• /
• 2017

Lignocellulosic biomass represents a potentially large resource to supply the world's fuel and chemical feedstocks. Enzymatic bioconversion of this substrate offers a reliable strategy for accessing this material under mild reaction conditions. Owing to the complex nature of lignocellulose, many different enzymatic activities are required to function in concert to perform efficient transformation. In nature, large multienzyme complexes are known to effectively hydrolyze lignocellulose into constituent monomeric sugars. We created artificial complexes of enzymes, called rosettazymes, in order to hydrolyze glucuronoxylan, a common lignocellulose component, into its cognate sugar ${\small{D}}$-xylose and then further convert the ${\small{D}}$-xylose into ${\small{D}}$-xylonic acid, a Department of Energy top-30 platform chemical. Four different types of enzymes (endoxylanase, ${\alpha}$-glucuronidase, ${\beta}$-xylosidase, and xylose dehydrogenase) were incorporated into the artificial complexes. We demonstrated that tethering our enzymes in a complex resulted in significantly more activity (up to 71%) than the same amount of enzymes free in solution. We also determined that varying the enzyme composition affected the level of complex-related activity enhancement as well as overall yield.

• Journal of Microbiology and Biotechnology
• /
• v.19 no.2
• /
• pp.161-166
• /
• 2009

Certain microalgae have been known to use light and various carbon sources to produce carbohydrates, mainly in the form of starch. This is one of the pertinent feedstocks replacing agricultural products for the production of bioethanol by yeast. This study focuses upon dilute acid hydrothermal pretreatments at low cost and high efficiency to compete with current methods, and employs Chlamydomonas reinhardtii UTEX 90 as the feedstock. With dry cells of 5%(w/v), the algal biomass was pretreated with sulfuric acid(1-5%) under temperatures from 100 to $120^{\circ}C$, from 15 to 120 min. As a result, the glucose release from the biomass was maximum at 58%(w/w) after pretreatment with 3% sulfuric acid at $110^{\circ}C$ for 30 min. This method enabled not only starch, but also the hydrolysis of other oligosaccharides in the algal cell in high efficiency. Arrhenius-type of model equation enabled extrapolation of some yields of glucose beyond this range. The pretreated slurry was fermented by yeast, Saccharomyces cerevisiae S288C, resulting in an ethanol yield of 29.2% from algal biomass. This study suggests that the pretreated algal biomass is a suitable feedstock for ethanol production and can have a positive impact on large-scale applied systems.

• Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
• /
• 2011.04a
• /
• pp.171-178
• /
• 2011

During the last decades, global warming from the increased amount of greenhouse gases, mainly carbon dioxide has become a major political and scientific issue. Burning fossil fuels (natural gas, coal and oil) releases $CO_2$, which is also a major cause of global warming. Among the clean environment, wood pellets are considered as promising renewable fossil fuels because of clean burning characteristics, reduction of particulate and NOx emission from combustion. In Korea, more than 50% pellets have to be imported every year because of shortage of feedstocks. On the other hand, about 80% of wood pulps are greatly dependent upon overseas products due to limited forest resources. Under this situation, this study explored how efficiently we have to use forest biomass instead of total dependence on wood as raw materials for pellets.

• Journal of the Korean Ceramic Society
• /
• v.55 no.2
• /
• pp.178-184
• /
• 2018

In the present study, $TiB_2-Co$ composite coatings were thermally sprayed onto the surface of a 304 stainless steel substrate using an atmospheric plasma spray (APS). The phase analysis of the powders and plasma-sprayed coatings was performed using X-ray diffractometry analysis. The microstructures of the coatings were studied by a scanning electron microscope (SEM). The average particle size and flowability of the feedstocks were also measured. Both $TiB_2-32Co$ and $TiB_2-45Co$ (wt.%) coatings possessed typical dense lamellar structures and high-quality adhesion to the substrate. The oxidation behaviors of the coatings were studied at $900^{\circ}C$ in an atmospheric environment. In addition, the cross-sectional images of the oxidized coatings were analyzed by SEM. A thin and well-adhered layer was formed on the surface of both $TiB_2-Co$ coatings, confirming satisfactory high-temperature oxidation resistance. The kinetic curves corresponding to the isothermal oxidation of the coatings illustrated a short transient stage from rapid to slow oxidation during the early portion of the oxidation experiment.

• Applied Chemistry for Engineering
• /
• v.29 no.1
• /
• pp.1-9
• /
• 2018

Microalgae is considered as one of environmentally sustainable and potential feedstocks to produce biodiesels. However, recent studies on life cycle assessments (LCA) of microalgal buidiesels have shown that energy requirement is not small to produce biodiesel from microalgae, especially during cultivation stage. The costs for carbon sources, nutrients like nitrogen or phosphorous, and water for cultivation can contribute up to 80% of the total medium costs. In the present article, recent trends on the utilization of several promising nutrient sources such as municipal wastewaters, organic fertilizers, combustion exhaust emissions and organic solid wastes were reviewed, and the potential strategies to be used as substitutes of artificial culture media, especially for the biodiesel production, were discussed.

• 한국신재생에너지학회:학술대회논문집
• /
• 2007.11a
• /
• pp.437-440
• /
• 2007

Gasification converts coal and other feedstocks into a very clean and usable gas, called syngas, that can be used to produce a wide variety products such as electricity, chemicals, transports fuels, hydrogen production, etc. This paper was studied the gasification performance effects with the variation of the gasification operating parameters such as the feeding amounts of oxygen, steam and coal. When $O_2/coal$ ratio was below 0.8, $H_2$ mole % was increased as increasing $O_2/coal$ ratio. CO mole % was increased when $O_2/coal$ ratio was below 1.2 as increasing the $O_2/coal$ ratio. As increasing steam/coal ratio, $H_2$ mole %was increased and CO mole % was decreased. The $O_2/coal$ and steam/coal ratio was $0.8{\sim}0.9$ and $0.0{\sim}0.4$, respectively, to keep the proper gasification condition that the gasifier temperature was $1300^{\circ}C{\sim}1450^{\circ}C$ and the cold gas efficiency was over 76%.

• Applied Chemistry for Engineering
• /
• v.3 no.2
• /
• pp.201-206
• /
• 1992

Annual amount of plastics waste including rubber and leather waste, generated in 1990 was about 2,600,000 tons. Amount of generation of plastics waste has rapidly increased, but fractions of recycling and incineration have gradually decreased. Recently, two-stage incinerator, consisting of gasifier and gas combustor, draws much attention in Korea. Plastics are gasified in the starved air condition in the gasifier and produced gas is fired in the combustor. Combustion of produced gas is much easier than that of solid plastics, and produces a little pollutants. Standardzation of technology and process automation are still needed, but this incineration technology is in the commercial stage. Next topic concerned with this two-stage incineration will be how to treat complex plastics waste including toxic substances generated from automobiles and household appliances. Pyrolysis, realized by indirect heating in inert atmosphere, can provide high-quality products with minimum emissions. Many plastics are easily decomposed into oil in pyrolysis conditions, which can be utilized as chemical feedstocks, or gasoline or kerosene depending on feed materials and operating conditions. This has been demonstrated in several pilot-scale tests performed in Japan, Germany, etc. Easy removal of HCl from PVC is one of the most decisive merits of pyrolysis process. But in general, further efforts should be made for the process to obtain marketability. The future of pyrolysis process depends on public concern about environmental problems and oil prices.