• Title/Summary/Keyword: Feedstock

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Dynamic thermal Design of a 1-ton Class Bio-Hydrogen Production System Simulator Using Industrial Waste Heat and by-Products (산업배열 및 부산물을 활용한 1톤급 바이오수소 생산 시뮬레이터 동적 열설계)

  • Kim, Hyejun;Kim, Seokyeon;Ahn, Joon
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.29 no.5
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    • pp.259-268
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    • 2017
  • This paper proposes a hydrogen-based social economy derived from fuel cells capable of replacing fossil fuels and resolving global warming, It thus provides an entry for developing economically feasible social configurations to make use of bio-hydrogen production systems. Bio-hydrogen production works from the principle that microorganisms decompose water in the process of converting CO to $CO_2$, thereby producing hydrogen. This study parts from an analysis of an existing 157-ton class NA1 bio-hydrogen reactor that identifies the state of feedstock and reactor conditions. Based on this analysis, we designed a 1-ton class bio-hydrogen reactor process simulator. We carried out thermal analyses of biological heat reactions, sensible heat, and heat radiation in order to calculate the thermal load of each system element. The reactor temperature changes were determined by modeling the feed mixing tank capacity, heat exchange, and heat storage tank. An analysis was carried out to confirm the condition of the feed mixing tank, heat exchanger, heat storage tank capacity as well as the operating conditions of the system so as to maintain the target reactor temperature.

Renewable and Sustainable Resource Derived Carbon Neutral Adhesive Materials (재생 및 지속사용 가능 자원 유래 탄소 중립형 접착소재)

  • Kim, Baekjin;Kim, Sangyong;Cho, Jin Ku;Lee, Sang-Hyeup;Kim, Hyun-Joong
    • Journal of Adhesion and Interface
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    • v.11 no.2
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    • pp.76-83
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    • 2010
  • The extensive use of fossil resources over the past century resulted in dwindling supply and surging price of oil and it is strongly suspected that irreversible global climate change might be due to carbon dioxide emitted from combustion of fossil carbons. With this regard, much attention is recently paid to renewable and sustainable resources as alternatives to petroleum. In this review, we considered a range of efforts to replace petroleum-derived chemicals, particularly adhesive materials with renewable and sustainable plant-based biomass feedstock.

A Study on CNN based Production Yield Prediction Algorithm for Increasing Process Efficiency of Biogas Plant

  • Shin, Jaekwon;Kim, Jintae;Lee, Beomhee;Lee, Junghoon;Lee, Jisung;Jeong, Seongyeob;Chang, Soonwoong
    • International journal of advanced smart convergence
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    • v.7 no.1
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    • pp.42-47
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    • 2018
  • Recently, as the demand for limited resources continues to rise and problems of resource depletion rise worldwide, the importance of renewable energy is gradually increasing. In order to solve these problems, various methods such as energy conservation and alternative energy development have been suggested, and biogas, which can utilize the gas produced from biomass as fuel, is also receiving attention as the next generation of innovative renewable energy. New and renewable energy using biogas is an energy production method that is expected to be possible in large scale because it can supply energy with high efficiency in compliance with energy supply method of recycling conventional resources. In order to more efficiently produce and manage these biogas, a biogas plant has emerged. In recent years, a large number of biogas plants have been installed and operated in various locations. Organic wastes corresponding to biogas production resources in a biogas plant exist in a wide variety of types, and each of the incoming raw materials is processed in different processes. Because such a process is required, the case where the biogas plant process is inefficiently operated is continuously occurring, and the economic cost consumed for the operation of the biogas production relative to the generated biogas production is further increased. In order to solve such problems, various attempts such as process analysis and feedback based on the feedstock have been continued but it is a passive method and very limited to operate a medium/large scale biogas plant. In this paper, we propose "CNN-based production yield prediction algorithm for increasing process efficiency of biogas plant" for efficient operation of biogas plant process. Based on CNN-based production yield forecasting, which is one of the deep-leaning technologies, it enables mechanical analysis of the process operation process and provides a solution for optimal process operation due to process-related accumulated data analyzed by the automated process.

Deposition Behavior and Microstructure of Fe-based Amorphous Alloy Fabricated by Vacuum Kinetic Spraying Process (진공 저온 분사 공정을 통해 형성된 Fe계 비정질 재료의 적층거동 및 미세구조 변화 관찰)

  • Kwon, Juhyuk;Park, Hyungkwon;Lee, Illjoo;Lee, Changhee
    • Korean Journal of Materials Research
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    • v.24 no.1
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    • pp.60-65
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    • 2014
  • Fe-based amorphous coatings were fabricated on a soda-lime glass substrate by the vacuum kinetic spray method. The effect of the gas flow rate, which determines particle velocity, on the deposition behavior of the particle and microstructure of the resultant films was investigated. The as-fabricated microstructure of the film was studied by field emission scanning electron microscopy (FE-SEM) and high resolution transmission electron microscopy (HR-TEM). Although the activation energy for transformation from the amorphous phase to crystalline phase was lowered by severe plastic deformation and particle fracturing under a high strain rate, the crystalline phases could not be found in the coating layer. Incompletely fractured and small fragments 100~300 nm in size, which are smaller than initial feedstock material, were found on the coating surface and inside of the coating. Also, some pores and voids occurred between particle-particle interfaces. In the case of brittle Fe-based amorphous alloy, particles fail in fragmentation fracture mode through initiation and propagation of the numerous small cracks rather than shear fracture mode under compressive stress. It could be deduced that amorphous alloy underwent particle fracturing in a vacuum kinetic spray process. Also, it is considered that surface energy caused by the formation of new surfaces and friction energy contributed to the bonding of fragments.

Screening of Freshwater Microalgae for Resistance to Ultraviolet Radiation (자외선 차단능을 보유한 미세조류의 스크리닝)

  • Han, Mi-Ae;Han, Hye Jin;Jung, Moon Hee;Yoo, Rim Hwan;Hwang, Chae Eun;Myung, Su Hyun;Son, Yun Jin;Yoon, Young-Sil;Lee, Choul-Gyun
    • Journal of Marine Bioscience and Biotechnology
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    • v.6 no.2
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    • pp.131-137
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    • 2014
  • Ultraviolet-B radiation (UV-B) in sunlight causes biological damages such as erythema and blister on skin. Microalgae have been in the limelight as an attractive feedstock for manufacturing functional materials. This study focused on screening microalga with protection ability against UV-B. The microalgae were isolated from local areas on April to June 2013 as well as June 2014. The cells were grown under continuous illumination from fluorescent lamps at $136.3{\pm}2.2{\mu}E/m^2/s$ in BG-11 medium at $15^{\circ}C$ for 12-14 days. The selected cells were spread on BG-11 agar and were exposed to UV-B (312 nm) for 20 and 25 minutes. The 13 strains among selected algae were classified. Among these, 9 strains were Scenedesmus sp. and the remains were Chlorella sp. Based on this study, it seems that Scenedesmus sp. and Chlorella sp. have resistibility against ultraviolet. These results will help to study on UV protection using microalgae.

Effects of nitrogen and organic carbon sources on growth and lipid production of Chlorella sp. KR-1 in flask cultures (플라스크 배양에서 Chlorella sp. KR-1의 균체 성장 및 지질 생산에 대한 질소원 및 유기탄소원의 영향)

  • Lee, Ja-Youn;Seo, Kyoung Ae;Oh, You-Kwan
    • Journal of Marine Bioscience and Biotechnology
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    • v.6 no.2
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    • pp.110-117
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    • 2014
  • Recently microalgae have been proposed as a promising biodiesel feedstock, owing to their higher lipid productivity and non-arable land based cultivation system. Biomass and lipid productivities of microalgae are largely affected by various environmental and nutritional factors. In this study, the effects of nitrogen (nitrate and ammonium) and organic carbon (glucose and glycerol) sources on the cell growth and lipid production of Chlorella sp. KR-1 were examined in flask cultures. Under autotrophic culture conditions for 15 days, overall cell growth and lipid (fatty acid methyl ester, FAME) production with nitrate were better than those of ammonium, resulting in 1.06 g cell/L and 333 mg FAME/L, respectively. Maximal intracellular lipid contents (348 - 352 mg FAME/g cell) were observed at low concentrations of 1 mM for both nitrate and ammonium. In the supply of light, addition of glucose in the range of 1 - 20 g/L showed higher cell densities than the autotrophic cell growth condition. Higher lipid accumulation of 375 mg FAME/g cell could achieved at 5 g glucose/L albeit of relatively short incubation of 7 days. With glycerol, intracellular lipid contents were ~1.9 times lower than glucose cases although similar cell growths were observed for both carbon sources.

A Effect of Reaction Conditions on Syngas Yield for the Preparation of Syngas from Landfill Gas (매립지가스(LFG)로부터 합성가스 제조시 반응조건에 따른 수율에 미치는 연구)

  • CHO, WOOKSANG;CHOI, KEONGDON;BAEK, YOUNGSOON
    • Transactions of the Korean hydrogen and new energy society
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    • v.26 no.5
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    • pp.477-483
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    • 2015
  • LFG (Land-Fill Gas) includes components of $CH_4$, $CO_2$, $O_2$, $N_2$, and water. The preparation of synthesis gas from LFG as a DME (Dimethyl Ether) feedstock was studied by methane reforming of $CO_2$, $O_2$ and steam over $NiO-MgO-CeO_2/Al_2O_3$ catalyst. Our experiments were performed to investigate the effects of methane conversion and syngas yield on the amount of LFG components over $NiO-MgO-CeO_2/Al_2O_3$ catalyst. Results were obtained through the methan reforming experiments at the temperature of $900^{\circ}C$ and GHSV of 8,800. The results were as following; it has generally shown that syngas yield increase with the increase of oxygen and steam amounts and then decrease. Highly methane conversion of above 98% and syngas yield of approximately 60% were obtained in the feed of gas composition flow-rate of 243ml/min of $CH_4$, 241ml/min of $CO_2$, 195ml/min of $O_2$, 48ml/min of $N_2$, and 450ml/min of steam, respectively, under reactor pressure of 1 bar for 200 hrs of reaction time. Also, it was shown that catalyst deactivation by coke formation was reduced by excessively adding oxygen and steam as an oxidizer of the methane reforming.

Production of Biodiesel from High Acid Value Oils using Amberlyst-15 (Amberlyst-15를 이용한 산가가 높은 유지로부터 바이오디젤의 생산)

  • Sim, Yeon-Ju;Kim, Eui-Yong
    • KSBB Journal
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    • v.25 no.5
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    • pp.483-489
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    • 2010
  • Biodiesel has attracted great attention as an alternative renewable energy source for the replacement of petroleumbased diesel fuel, yet its high production cost due to expensive oil feedstock remainsas the major economical obstacle. In this study, we investigated catalysts and reaction conditions for the acid catalyzed pre-conversion of free fatty acid (FFA) to fatty acid methyl ester (FAME) in cheap low-grade oils of high acid value. The NaOH base catalyzed reaction of vegetable oil of the initial acid value of 2 mg KOH/g led to a high FAME conversion above 95.4%, but the conversion abruptly decreased at higher initial acid values. This base catalyzed reaction was practically ineffective displaying the FAME conversion below 15% even at the initial acid value of 10 mg KOH/g by the severe saponification side reaction. Among the various catalysts studied for the pre-conversion of FFA to FAME, Amberlyst-15 was the most effective in reducing the acid value, and the optimum reaction condition identified was $65^{\circ}C$ with oil to methanol ratio of 1:3 and catalyst concentration of 15% (w/w). As the results, great enhancements in the overall biodiesel conversion were achievable via a consecutive reaction of the acid catalyzed FFA pre-conversion to FAME under the optimal condition obtained with Amberlyst-15 followed by the NaOH base catalyzed reaction, far above the extent which was obtainable by the single NaOH catalyzed reaction.

Fabrication, Microstructure and Adhesive Properties of BCuP-5 Filler Metal/Ag Plate Composite by using Plasma Spray Process (Plasma spray 공정을 이용한 BCuP-5 filler 금속/Ag 기판 복합 소재의 제조, 미세조직 및 접합 특성)

  • Youn, Seong-June;Kim, Young-Kyun;Park, Jae-Sung;Park, Joo-Hyun;Lee, Kee-Ahn
    • Journal of Powder Materials
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    • v.27 no.4
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    • pp.333-338
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    • 2020
  • In this study, we fabricate a thin- and dense-BCuP-5 coating layer, one of the switching device multilayers, through a plasma spray process. In addition, the microstructure and macroscopic properties of the coating layer, such as hardness and bond strength, are investigated. Both the initial powder feedstock and plasma-sprayed BCuP-5 coating layer show the main Cu phase, Cu-Ag-Cu3P ternary phases, and Ag phase. This means that microstructural degradation does not occur during plasma spraying. The Vickers hardness of the coating layer was measured as 117.0 HV, indicating that the fine distribution of the three phases enables the excellent mechanical properties of the plasma-sprayed BCuP-5 coating layer. The pull-off strength of the plasma-sprayed BCuP-5 coating layer is measured as 16.5 kg/㎠. Based on the above findings, the applicability of plasma spray for the fabrication process of low-cost multi-layered electronic contact materials is discussed and suggested.

Dunaliella salina as a Microalgal Biomass for Biogas Production (바이오 가스 생산을 위한 미세조류 바이오매스로서의 Dunaliella salina)

  • Jeon, Nayeong;Kim, Daehee;An, Junyeong;Kim, Taeyoung;Gim, Geun Ho;Kang, Chang Min;Kim, Duk Jin;Kim, Si Wouk;Chang, In Seop
    • Microbiology and Biotechnology Letters
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    • v.40 no.3
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    • pp.282-285
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    • 2012
  • In this study, the ability of Chlorella vulgaris and Dunaliella salina to use biomass resources for anaerobic digestive biogas production was examined. The differences in cell wall structure pretreatments affecting the yield of soluble products showed that D. salina is a better candidate for biogas production than C. vulgaris. There was no significant difference between pretreated and non-pretreated D. salina in terms of methane production yield by inocula obtained from anaerobic digestion systems. Therefore, D. salina is a suitable algal biomass for biogas production due to its high biomass productivity, simple pretreatment needs, and easy conversion to biogas.