• 센서학회지
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• 제11권1호
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• pp.18-27
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• 2002

스크린 프린팅법으로 $Al_2O_3$ 기판 위에 $LaFeO_3$를 기본물질로 하여 $Al_2O_3$를 각각 2Wt.%, 5wt.%, 10wt.%를 첨가한 후막을 제조하였다. 열처리 온도에 따른 후막의 구조적, 전기적 특성과 암모니아 가스에 대한 감지특성을 조사하였다. X선 회절에서, 첨가한 $Al_2O_3$는 $1200^{\circ}C$까지의 열처리에도 $LaFeO_3$와 반응하여 화합물을 형성하지 않음을 확인하였다. 전자현미경 사진에서 $Al_2O_3$의 첨가량에 따른 열처리에 대한 입자의 변화는 차이를 보이지 않았다. 후만의 전기적 특성에서 활성화 에너지가 높고 전기저항이 작은 시료에서 가스감도가 좋았다. $Al_2O_3$를 2wt.% 첨가하여 $1200^{\circ}C$에서 열처리한 후막은 100ppm $NH_3$ 가스에 대해 동작온도 $350^{\circ}C$에서 210%의 감도를 보였다. 이 후막은 $NH_3$ 가스에 대해 우수한 선택성을 보였다.

• 한국재료학회지
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• 제18권3호
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• pp.143-147
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• 2008

Fe compounds in scoria as distributed in the south-western area of Jeju Island were investigated using X-ray fluorescence spectroscopy, X-ray diffractometry, and $^{57}Fe$ $M{\ddot{o}}ssbauer$ spectroscopy. The samples were prepared from four parasite volcanoes. It was found that these samples are typical basalt comprised of $SiO_2$, $Al_2O_3$, Fe, and silicate minerals. The $M{\ddot{o}}ssbauer$ spectra showed doublets for olivine, pyroxene, and ilmenite as well as sextets for hematite and magnetite. The valence state of Fe is chiefly a 3+ charge state with a slight 2+ charge state. It is expected that these results will add to the body of information related to the formation mechanisms of Jeju Island.

• 한국주조공학회지
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• 제32권1호
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• pp.50-56
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• 2012

Fusion bonding of cast iron and Al alloy is an effective way to improve the properties such as low inertia, high efficiency and corrosion resistance in machinery parts. In case of fusion bonding, intermetallic compound layers are formed at the interface between cast iron and Al alloy interface. It is important to control the intermetallic compound layers for improving bonding strength. The formation behavior of intermetallic compound layer by heat treatment has been investigated. Heat treatment was performed at temperature from $600^{\circ}C$ to $800^{\circ}C$ with $100^{\circ}C$ interval for an hour to investigate the phase transformation during heat treatment. Heat treated specimens were analyzed by using FE-SEM, EPMA and EDS. The EPMA/WDS results revealed that various phases were formed at the interface, which exhibited 4 distinct intermetallic compound layers such as ${\tau}_6-Al_{4.5}FeSi$, ${\tau}_2-Al_3FeSi$, ${\tau}_{11}-Al_5Fe_2Si $and ${\eta}-Al_5Fe_2$. Also, fine precipitation of ${\tau}_1-Al_2Fe_3Si_3$ phase was formed between ${\tau}_{11}$ and ${\eta}$ layer. The phase fraction in intermetallic compound layer was changed by heat treatment temperature. At $600^{\circ}C$, intermetallic compound layer of ${\tau}_6$ phase was mainly formed with increasing heat treatment time. With increasing heat treatment temperature to $800^{\circ}C$, however, ${\tau}_2$ phase was mainly distributed in intermetallic compound layer. ${\tau}_1$ phase was remarkably decreased with increasing heat treatment time and temperature.

• 대한환경공학회지
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• 제35권5호
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• pp.312-320
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• 2013

상수도관망에서의 입자성 물질들은 대부분 금속관로의 내부부식 및 퇴적물에 의한 영향으로 이를 해결할 수 있는 방법은 제한적이라 할 수 있다. 수중의 입자성 물질들은 입자크기, 화합물 성분 및 성상들이 다르며, 이들 특성은 시설별 종류, 관 상태, 외부적 요인 및 공급과정 등에 의해서 차이가 발생하게 된다. 본 연구에서는 상수도관망의 수질조사를 수행하면서 수중의 입자성 물질들에 대한 조사를 실시하고자 하였으며, 정수를 공급하는 각 계통들의 배수지 및 관말지역을 대상으로 실시하였다. 각 조사지점에서 입자성 물질을 포집하기 위해 $47{\phi}$ 의 유리섬유여지(GF/C)를 이용하여 여과를 수행하였다. 수중의 탁도에 영향을 미치는 물질들이 입자성 부유물질과 무기물질들에 의한 것으로 관말지역으로 갈수록 입자성 물질이 증가하는 것으로 조사되었다. XRD를 이용한 입자성 물질의 화합물 성분분석결과 상수도관망의 관말지역에서 가장 많은 화합물은 Goethite (${\alpha}$-FeOOH), Magnetite ($Fe_3O_4$) 등이고 정수와 각 배수지 유출수에서는 Quartz ($SiO_2$)와 Yeelimite ($Ca_4Al_6O_{12}SO_4$) 등도 있는 것으로 조사되어 각 상수도 시설별 용출되거나 잔존하고 있는 화합물 성분이 다르며, 침적물들에도 차이가 있었다.

• 한국주조공학회지
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• 제13권3호
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• pp.276-284
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• 1993

The interfacial phenomena between intermetallic compounds and Al matrix have been studied at $680^{\circ}C$ for various holding time under argon atmosphere. Model experiments were performed using Fe, Ni and Ti wire to observe the interfacial phenomena. The interfacial phenomena between intermetallic compounds and Al matrix were analysed by optical microscope, SEM and EDX. The results of EDX and XRD showed that the interfacial zones of intermetallic compounds/Al matrix were composed of several intermetallic layers. The reaction layer was varied with holding time and heating temperature. The investigation of interfacial zones in the specimen as a function of heat treatment time at $680^{\circ}C$ indicated that the best heat treatment condition for squeeze casting was $680^{\circ}C$ for 5min.

• 한국재료학회지
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• 제5권5호
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• pp.575-582
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• 1995

Al 8090합금의 퇴화처리시에 나타나는 금속간화합물 변화과정과 PFZ 생성 및 입계석출물의 거동을 TEM을 사용하여 조사하였다. 기지에서는 $\delta$상, T$_{1}$ 상과 S'상이 모든 시편에서 관찰되었고, 입계어슨 PFZ이 형성되었다. 본 연구에 사용된 Al합금의 초기PFZ의 생성 기구는 입계의 임계공공 농도에 의한 것으로 나타났다. 2단계 열처리시 시간이 2분 이상이면 입계에 석축물이 형성되었다. 입계에는 중간단계로 5회전대칭축을 가지는 준안전상의 icosahedral상의 생성되었다. 평형 입계석출물은 사방정의 $Al_{13}$Fe$_{4}$였다.

• 대한금속재료학회지
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• 제48권2호
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• pp.141-147
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• 2010

An Ni-Al intermetallic coating has been produced by induction heating on mild steel. The effect of the induction heating conditions on the microstructure of the coating has been investigated. The reaction synthesis of the intermetallic compounds was promoted while increasing the heating rate and the holding time at reaction temperature. Especially, an NiAl phase corresponding to the initial composition of mixed powder was predominantly formed. However, the synthesis at low reaction temperatures occurred by solid state diffusion during the holding time and an Fe-Al reaction layer was formed at the interface with the substrate, regardless of the heating rate. The combustion synthesis of the intermetallic compound occurred at a temperature higher than 1023 K and resulted in an almost single phase NiAl structure.

• 한국주조공학회지
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• 제18권4호
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• pp.357-363
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• 1998

Microstructure of A356 aluminium alloys cast in a permanent mold was investigated by optical microscope and image analyzer, with particular respect to the shape and size distribution of iron intermetallics known as ${\beta}-phase$ ($Al_5FeSi$). Morphologies of the ${\beta}-phase$ was found to change gradually with the Be:Fe ratio like these. In Be-free alloys, ${\beta}-phase$ with needlelike morphology was well developed, but script phase was appeared when the Be:Fe ratio is above 0.2:1. With the Be:Fe ratios of 0.4:1-1:1, script phase as well as Be-rich phase was also observed. In case of higher Be addition, above 1:1, Be-rich phase was observed on all regions of the specimens, and increasing of the Be:Fe ratios gradually make the Be-rich phase coarse. It was also observed that the ${\beta}-phase$ with needlelike morphology was coarsened with increase of the Fe content in Be-free alloys. However, in Be-added alloys, length and number of these ${\beta}-phases$ were considerably decreased with the increased Be:Fe ratio. It was concluded that Fe impurity element to be crystallized into needlelike intermetallics was tied up by Be addition element, and new phases were crystallized into script or Be-rich intermetallics.

• 한국기계가공학회지
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• 제17권3호
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• pp.102-108
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• 2018

The objective of this study is to develop the mechanical properties of an AlSiCu aluminum alloy using the two-step solution heat treatment. The microstructure of the gravity casting specimen represents a typical dendrite structure with a secondary dendrite arm spacing (SDAS) of 40 um. In addition to the Al matrix, a large amount of coarsen eutectic Si phase, $Al_2Cu$ intermetallic phase, and Fe-rich phases is generated. The eutectic Si phases are fragmented and globularized with the solution heat treatment. The $Al_2Cu$ intermetallic phase is also resolutionized into the Al matrix. The $2^{nd}$ solution temperature at $525^{\circ}C$ may be an optimal condition to enhance the mechanical properties of the AlSiCu aluminum alloy.

• 한국재료학회지
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• 제33권1호
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• pp.8-14
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• 2023

In order to broaden the range of application of light weight aluminum alloys, it is necessary to enhance the mechanical properties of the alloys and combine them with other materials, such as cast iron. In this study, the effects of adding small amounts of Cu and Zr to the Al-Si-Mg based alloy on tensile properties and corrosion characteristics were investigated, and the effect of the addition on the interfacial compounds layer with the cast iron was also analyzed. Although the tensile strength of the Al-Si-Mg alloy was not significantly affected by the additions of Cu and Zr, the corrosion resistance in 3.5 %NaCl solution was found to be somewhat lowered in this research. The influence of Cu and Zr addition on the type and thickness of the interfacial compounds layer formed during compound casting with cast iron was not significant, and the main interfacial compounds were identified to be Al₅FeSi and Al₈Fe₂Si phases, as in the case of the Al-Si-Mg alloys.