• Bulletin of the Korean Chemical Society
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• 제33권8호
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• pp.2567-2573
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• 2012

We successfully synthesized $Fe_3O_4@SiO_2$ nanoparticles with ultrathin silica layer of $1.0{\pm}0.5$ nm that polyethyleneimine (PEI) with low molecular weight of 2.0-4.0 kDa was covalently conjugated with the resulting $Fe_3O_4@SiO_2$ nanoparticles by silane coupling reaction. The PEI-$Fe_3O_4@SiO_2$ nanoparticles were further used as gene delivery vector for a human fibroblast cell (IMR-90) line. Gene transfection efficiency of the PEI-$Fe_3O_4@SiO_2$ complexes did not increase remarkably after magnetofection; however, the addition of Lipofectamine 2000 significantly increased the transfection efficiency of the PEI-$Fe_3O_4@SiO_2$ complexes. We believe that the present approach could be utilized for magnetofection as alternative to $Fe_3O_4$ nanoparticles conjugated with the PEI of high molecular weight thanks to its relatively low cytotoxicity and high transfection efficiency.

• 대한전자공학회논문지
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• 제17권1호
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• pp.36-39
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• 1980

5Fe₂O₃-5Bi₂O₃소결체에서 V-I특성의 규격화, theramal current runaway의 인가 step 전압의 존성, current channel의 분석등을 연구하였다. 5Fe₂O₃-5Bi₂O₃소결체의 switching 특성의 측정으로부터 전기적 switching기구는 thermal ionic breakdown으로 설명된다.

• Bulletin of the Korean Chemical Society
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• 제28권8호
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• pp.1273-1279
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• 2007

The NiSO4 supported on Fe2O3 catalysts were prepared by the impregnation method. No diffraction line of nickel sulfate was observed up to 30 wt %, indicating good dispersion of nickel sulfate on the surface of Fe2O3. The addition of nickel sulfate to Fe2O3 shifted the phase transition of Fe2O3 (from amorphous to hematite) to higher temperatures because of the interaction between nickel sulfate and Fe2O3. 20-NiSO4/Fe2O3 containing 20 wt % of NiSO4 and calcined at 500 oC exhibited a maximum catalytic activity for ethylene dimerization. The initial product of ethylene dimerization was found to be 1-butene and the initially produced 1-butene was also isomerized to 2-butene during the reaction. The catalytic activities were correlated with the acidity of catalysts measured by the ammonia chemisorption method.

• 한국재료학회지
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• 제23권4호
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• pp.219-226
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• 2013

Activated magnetite ($Fe_3O_{4-{\delta}}$) has the capability of decomposing $CO_2$ proportional to the ${\delta}$-value at comparatively low temperature of $300^{\circ}C$. To enhance the $CO_2$ decomposition capability of $Fe_3O_{4-{\delta}}$, $(Fe_{1-x}Co_x)_3O_{4-{\delta}}$ and $(Fe_{1-x}Mn_x)_3O_{4-{\delta}}$ were synthesized and then reacted with $CO_2$. $Fe_{1-x}Co_xC_2O_4{\cdot}2H_2O$ powders having Fe to Co mixing ratios of 9:1, 8:2, 7:3, 6:4, and 5:5 were synthesized by co-precipitation of $FeSO_4{\cdot}7H_2O$ and $CoSO_4{\cdot}7H_2O$ solutions with a $(NH_4)_2C_2O_4{\cdot}H_2O$ solution. The same method was used to synthesize $Fe_{1-x}Mn_xC_2O_4{\cdot}2H_2O$ powders having Fe to Mn mixing ratios of 9:1, 8:2, 7:3, 6:4, 5:5 with a $MnSO_4{\cdot}4H_2O$ solution. The thermal decomposition of synthesized $Fe_{1-x}Co_xC_2O_4{\cdot}2H_2O$ and $Fe_{1-x}Mn_xC_2O_4{\cdot}2H_2O$ was analyzed in an Ar atmosphere with TG/DTA. The synthesized powders were heat-treated for 3 hours in an Ar atmosphere at $450^{\circ}C$ to produce activated powders of $(Fe_{1-x}Co_x)_3O_{4-{\delta}}$ and $(Fe_{1-x}Mn_x)_3O_{4-{\delta}}$. The activated powders were reacted with a mixed gas (Ar : 85 %, $CO_2$ : 15 %) at $300^{\circ}C$ for 12 hours. The exhaust gas was analyzed for $CO_2$ with a $CO_2$ gas analyzer. The decomposition of $CO_2$ was estimated by measuring $CO_2$ content in the exhaust gas after the reaction with $CO_2$. For $(Fe_{1-x}Mn_x)_3O_{4-{\delta}}$, the amount of $Mn^{2+}$ oxidized to $Mn^{3+}$ increased as x increased. The ${\delta}$ value and $CO_2$ decomposition efficiency decreased as x increased. When the ${\delta}$ value was below 0.641, $CO_2$ was not decomposed. For $(Fe_{1-x}Co_x)_3O_{4-{\delta}}$, the ${\delta}$ value and $CO_2$ decomposition efficiency increased as x increased. At a ${\delta}$ value of 0.857, an active state was maintained even after 12 hours of reaction and the amount of decomposed $CO_2$ was $52.844cm^3$ per 1 g of $(Fe_{0.5}Co_{0.5})_3O_{4-{\delta}}$.

• 한국결정성장학회지
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• 제28권2호
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• pp.69-73
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• 2018

$100^{\circ}C$에서 0.03 M $FeCl_3$ 용액을 이용하여 수열법으로 제조한 80~90 nm의 ${\alpha}-Fe_2O_3$ 나노크기 입자의 결정 성장이 유연 frit 및 무연 frit에서 조사되었다. 두 종류의 frit 내에 있는 나노사이즈 ${\alpha}-Fe_2O_3$ 입자를 $800^{\circ}C$로 가열하였고 frit 내의 ${\alpha}-Fe_2O_3$ 입자의 평균 입경이 각각 200~210 nm과 150~160로 증가했다. 또한 ${\alpha}-Fe_2O_3$의 응집과 소결로 인해 결정 성장이 촉진된다는 사실도 확인되었다. 직경이 100 nm를 초과하는 큰 입자의 형성 비는 무연 frit에서 54 %, Pb가 함유된 유연 frit에서는 85 %였다. $800^{\circ}C$에서 frits 내에 있는 ${\alpha}-Fe_2O_3$ 입자를 가열함으로써, 평균 직경 7~9 nm의 기공이 ${\alpha}-Fe_2O_3$ 입자 내에 형성되었다. 이들 기공은 원래의 ${\alpha}-Fe_2O_3$ 입자 내의 한층 더 미세한 기공들로 구성된 다공성 구조에서 유래되었고, 소결 중 이들 미세 기공들은 입자에 갇혀있는 상태에서 서로 결합하여 7~9 nm의 기공 크기로 성장하였다.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2000년도 추계학술대회 논문집 학회본부 C
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• pp.506-508
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• 2000

Oxide of the form $Mn_{3}O_{4}-NiO-Fe_{2}O_{3}$ present properties that make them useful as multilayer chip NTC thermistor for mobile phone NTC thermistor electric properties of $Mn_{3}O_{4}-NiO-Fe_{2}O_{3}$ system has been measured as a function of temperature and composition. In $Mn_{3}O_{4}-NiO-Fe_{2}O_{3}$ composition, it can be seen that resistivity and B-constant were increased as the ratio of $Mn_{3}O_{4}/F_{2}O_{3}$ and $Mn_{3}O_{4}$/NiO was increased. In particular, resistance change ratio (${\Delta}R$), the important factor for reliability varied within ${\pm}1%$, indicating the compositions of these products could be available for mobile phone.

• 한국전기전자재료학회논문지
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• 제30권12호
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• pp.812-816
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• 2017

$Fe_3O_4$ was prepared on the $TiO_2-coated$ natural mica substrate. The natural mica has an average particle size of $22{\mu}m$. The substrate was coated on $TiO_2$ thin films using hydrothermal synthesis at pH 1.5-2.5 at $75^{\circ}C$. The Fe precursor solution was prepared by mixing $FeSO_4$ (for $Fe^{2+}$ ion) and $FeCl_3$ (for $Fe^{3+}$ ions) with different molar ratios such as 1/2, 1/1, 2/1, 3/0, and $Fe_3O_4$ only. X-ray diffraction analysis shows that the crystal structure depends on the $FeCl_3-to-FeSO_4$ molar ratio. $Fe_3O_4$ crystal phase could be obtained at higher $FeSO_4$ contents.

• 한국세라믹학회지
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• 제22권3호
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• pp.35-40
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• 1985

The composition of the base glass was determined to be $Na_2O$ 15, $Fe_2O_3$ 35, $B_2O_3$ 0~20, $P_2O_5$ 30~50 by mole percent. The heating temperature for nucleation was determined by means of thermal expansion curve. Crystalline phases were investigated by X-ray diffraction method and I.R Spectra. Electrical conductivities of glass spec-imens were observed in the temperature range 25~20$0^{\circ}C$ The activation energies of these specimens were caculated. The results obtained were as follows : 1) The limit composition of the melts 15mol% $Na_2O$ 35mole% $Fe_2O_5$ 20mole% $B_2O_3$ 30mole% $P_2O_5$ was able to be formed into desired shapes during cooling, . 2) In the measurement of d. c conductivity($\delta$) on the glasses in the system $15Na_2O-35Fe_2O_3$-$B_2O_3$-(50-x) $P_2O_5$ the values decreased by replacing 5 mole% $P_2O_5$ with $B_2O_3$ 3) The d. c conducties of heat treated samples were increased by replacing $P_2O_5$ with $B_2O_3$ 4) $B_2O_3$ contributed to precipitate crystals such as${\gamma}$-$Fe_2O_3$ $Fe_3O_4$ which had the advantage of electronic conduction in heat treated samples. 5) The slope plotted Log($\delta$) versus 1/T in this glass system was linear in the measured temperature range.

• Bulletin of the Korean Chemical Society
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• 제26권2호
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• pp.281-284
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• 2005

The Fe/MgO catalysts with different Fe loadings (1, 4, 6, 15 and 30 wt% Fe) were prepared by a wet impregnation with iron nitrate as precursor. All of the catalysts were characterized by BET surface analyzer, X-ray diffraction (XRD), temperature-programmed reduction (TPR), and X-ray photoelectron spectroscopy (XPS). The maximum removal capacity of $H_2S$ was obtained with 15 wt% Fe/MgO catalyst which had the highest BET surface area among the measured catalysts. XRD of Fe/MgO catalysts showed that well dispersed Fe particles could be present on Fe/MgO with Fe loadings below 15 wt%. The crystallites of bulk $\alpha$-$Fe_2O_3$ became evident on 30 wt% Fe/MgO, which were confirmed by XRD. TPR profiles showed that the reducibility of Fe/MgO was strongly related to the loaded amounts of Fe on MgO support. Therefore, the highest removal efficiency of $H_2S$ in wet oxidation could be ascribed to a good dispersion and high reducibility of Fe/MgO catalyst. XPS studies indicated that the $H_2S$ oxidation with Fe/MgO could proceed via the redox mechanism ($Fe^{3+}\;{\leftrightarrow}\;Fe^{2+}$).

• Elastomers and Composites
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• 제44권4호
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• pp.408-415
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• 2009

졸-겔 방법을 사용하여 Fe-ACF/$TiO_2$ 복합체 광촉매를 제조하였다. 여러 가지 철 전구체를 사용하여 세가지 Fe-ACF/$TiO_2$ 복합체를 제조하고 BET, SEM, XRD 및 EDX를 사용하여 특성화 하였다. UV 조사에서 Rh.B 용액의 분해에 의거하여 Fe-ACF/$TiO_2$ 복합체의 광촉매 특성을 파악 하였다. 실험 결과로부터, Fe-ACF/$TiO_2$ 복합체는 ACF/$TiO_2$ 복합체 보다 Rh.B의 제거 효과가 더 우수함을 나타내었다. 또한 여러 가지 Fe 전구체 사용으로 인한 Fe 원소의 포토-펜톤 효과는 다르게 나타났다. $FeCl_3$을 사용하여 제조된 Fe-ACF/$TiO_2$ 복합체는 가장 우수한 포토-펜톤 효과를 나타내었고, pH 변화에 의존하여 Rh.B 용액 분해에 대하여 영향을 주었다.