• Journal of the Korean Magnetics Society
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• v.5 no.5
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• pp.778-781
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• 1995

The mixed ferrite $Ni_{x}Co_{1-x}Fe_{2}O_{4}$ have been investigated by X-ray and $M\"{o}ssbauer$ spectoscpy. From the results of X-ray diffraction measurement the structure for this system is spinel, and the lattice constant is in accord with Vegard's law. $M\"{o}ssbauer$ spectra of $Ni_{x}Co_{1-x}Fe_{2}O_{4}$ have been taken at various temperature ranging from 13 to 800 K. The isomer shifts indicate that the valence states of the irons at both A(tetrahedral) and B(octahedral) sithe are found to be in ferric high-spin states. The variation of magnetic hyperfine fields at the A and B sites are explained on the basis on A-B and B-B supertransferred hyperfine interactions. It is found that Debye temperatures for the A and B sites of $CoFe_{2}O_{4}$ and $NiFe_{2}O_{4}$ are found to be ${\theta}_{A}=734{\pm}5K,\;{\theta}_{B}=248{\pm}5K,\;and\;{\theta}_{A}=378{\pm}5K,\;{\theta}_{B}=357{\pm}5K$, respectively. Atomic migration of $Ni_{0.3}Co_{0.7}Fe_{2}O_{4}$ starts near 450 K and increases rapidly with increasing temperature to such a degree that 61 % of the ferric ions at the A site have moved over to the B site by 700 K.

• Journal of the Korean Magnetics Society
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• v.6 no.2
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• pp.67-72
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• 1996

The crystallographic and magnetic properties of the ferrimagnetic $CoFe_2O_4$ have been studied by X-ray and Mossbauer measurements. The crystal structure is found to be cubic spinel structure with the lattice constant $a_{0}=8.381{\pm}0.005{\AA}\;and\;a_{0}=8.391{\pm}0.005{\AA}$ for slow-cooled and quenched CoFeZ04' respectively. Mossbauer spectra of $CoFe_2O_4$ have been taken at various temperatures ranging from 13 to 780 K. The isorrer shifts indicate that the valence states of the Fe ions for tetrahedral(A) and octahedral(B) sites have ferric character. Debye temperatures for the A and B sites are found to be ${\theta}_A=734{\pm}5K\;and\;{\theta}_B=248{\pm}5K$ for slow-cooled and ${\theta}_A=531{\pm}5K\;and\;{\theta}_B=197{\pm}5K$ for quenched, respectively. Atomic migration from the A to the B sites starts near 400 K and 350 K for slow-cooled and quenched $CoFe_2O_4$, respectively, am increases rapidly with increasing temperature to such a degree that about 69 % for slow-cooled and 91 % for quenched of the ferric ions on the A sites have rmved over to the B sites at 700 K.

• Journal of Powder Materials
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• v.19 no.2
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• pp.105-109
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• 2012

Magnetic properties and the microstructures of magnets prepared by spark plasma sintering were investigated in order to enhance magnetic properties by grain size control. Nd-Fe-B magnets were fabricated by the spark plasma sintering under 30 MPa at various temperatures. The grain size was effectively controlled by the spark plasma sintering and it was possible to make Nd-Fe-B magnets with grain size of 5.9 ${\mu}m$.

• Journal of the Korean Magnetics Society
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• v.21 no.1
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• pp.10-14
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• 2011

We have measured the ferromagnetic resonance (FMR) signal in as deposited and $400^{\circ}C$ annealed CoFeB/MgO thin film to investigate the annealing effect on magnetic anisotropies and FMR linewidth (${\Delta}H_{PP}$). The uniaxial anisotropy field ($H_{K1}$) was only observed in the as deposited sample. Whereas, in the $400^{\circ}C$ annealed sample, the biaxial anisotropy field ($H_{K2}$) was additionally observed in accompany with uniaxial anisotropy field ($H_{K1}$). The appearance of biaxial anisotropy fields was originated from the crystalline growth of bcc CoFeB(001) from the MgO(001) interface and by the B diffusion during thermal annealing. Also, the ${\Delta}H_{PP}$ of $400^{\circ}C$ annealed sample was increased compared with that of as deposited sample, which was due to the broad distribution of the magnetization axis by the biaxial anisotropy.

• Journal of Magnetics
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• v.9 no.4
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• pp.105-108
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• 2004

The attempt for the addition of double-phase nanocomposite $Nd_2Fe_{14}BFe_3B$ powders, respectively, into several $RE_2Fe_{14}B$(RE=Pr, Nd) powders with high magnetic properties was carried out. The powders were compounded and compressed to take shape bonded magnets. By means of investigating the variation of compound magnet $B_r$, the interaction between magnetic powders was revealed. The result shows that not chemical just but physical interaction exists between elements. The compound effect of $Nd_2Fe_{14}BFe_3B$-ferrite bonded magnets was detailed studied. The functional relation was revealed between magnetic properties and ferrite content. That is $Y = 5.42 x^2 -11.34x + 6.62$. The variation of $_iH_c$ temperature coefficient ${\beta}_{iHc}$ with ferrite content was investigated. Following the ferrite content increased, ${\beta}_{iHc}$ and $h_{irr}$ were obviously decreased, compression-resistant strength was enhanced.

• Journal of Magnetics
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• v.3 no.1
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• pp.4-8
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• 1998

Two different compositions of melt spun magnetic alloys, $ Nd_4Fe_{80}B_{16} and Nd_4Fe_{76}Co}\_3Hf_{0.5}Ga_{0.5}B_{16},$ were characterized in terms of magnetic properties and thermal behaviors. It was found that the addition of Hf and Ga effectively slow down the crystallization rate of the nanocomposite $ Nd_2Fe_{14}B/Fe_3B$ magnet. Coercivity(iHc) changes only slightly with varying the post annealing conditions confirming that iHc is not a sensitive magnetic quantity as a function of grain size and exchange coupled interaction. The experimentally observed behaviors of Mr and Hc do not vary monotonously with in-creasing grain size which is not in agreement with the numerically calculated result near the critical grain size (dc). The plot of the grain size dependence for the remanence and coercivity in isotrop!c nanocomposite magnets has been revised in this study. The maxium energy product, $(B, H)_{max}$ =15.34 MGOe, and a reduced remanence, Mr/Ms=0.84 were obtained, respectively.

• Journal of Magnetics
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• v.7 no.4
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• pp.127-131
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• 2002

HDDR characteristics and magnetic properties of $Nd_{15}{(Fe_{1-x}Co_{x})}_{77}B_{8}$(x=0-0.6) alloys were investigated. The effect of applying magnetic field during the recombination step on the anisotropic nature of the HDDR-treated material was also examined. The $Nd_{15}{(Fe_{1-x}Co_{x})}_{77}B_{8}$ phase in the Nd-Fe-B alloys with high Co-substitution alloy had remarkably enhanced phase stability. The $Nd_{15}{(Fe_{1-x}Co_{x})}_{77}B_{8}$(x=0-0.6) alloys with high Co-substitution could be HDDR-treated successfully by only using high pressure hydrogen. However, these alloys had no appreciable coercivity. The poor coercivity of the HDDR-treated $Nd_{15}{(Fe_{1-x}Co_{x})}_{77}B_{8}$(x=0-0.6) alloys with high Co-substitution was attributed to the $Nd{(Fe,Co)}_2$ phase in the alloys. The magnetic filed applied during the recombination step had little effect on the anisotropic nature of the HDDR-treated powder.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1988.10a
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• pp.5-7
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• 1988

Effect of isothermal aging on the crystallization of $Fe_{78}B_{13}Si_{9}$ metallic glass has been investigated by electrical resistivity, X-ray measurements, bending test, thermal analysis and transmission electron microscopy. Amorphous $Fe_{78}B_{13}Si_{9}$ alloy was annealed isothermally for 5 to 1200 mon. between 300 C and 540 C. It has been found that close relation between relative resistivity and X-ray diffraction pattern showed. The crystalline peak of $\alpha$-(Fe, Si) and Fe$_2$B are detected by X-ray experiment. The crystalline phases observed by TEM show $\alpha$-(Fe, Si) and Fe$_3$B with dendritic and cylindrical morphology, respectively. It has been also found that the embrittleness of aged samples rapidly increased with the crystallization and was shown before the crystallization.th the crystallization and was shown before the crystallization.

• Journal of the Korean Magnetics Society
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• v.5 no.1
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• pp.1-7
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• 1995

${(Fe_{0.85}Co_{0.15})}_{75}Al_{7}B_{18-x}Nb_{x}(x=2,\;4\;and\;6\;at%)\;and\;{(Fe_{0.85}Co_{0.15})}_{75}Al_{y}B_{21-y}Nb_{4}(y=3,\;5,\;7,\;9\;at%)$ alloys were prepared by a single-roll quenching method. Microstructure and magnetic properties of the alloys such as saturation magnetization, initial permeability, coercive force and power loss have been investigated as functions of composition and armea1ing temperature. Nanocrystallines are obtained by armealing of as-prepared amorphous alloys in all compositions except the alloy of 9 at% AI. Saturation magnetization increases after armea1ing and, decreases with Nb content. However, AI and B affects the saturation magnetization insignificantly. Initial perrreability of nanocrystallized alloy at 50 kHz is improved roore than twice compared to that of the as-prepared alloy. Coercive force and core loss reach less than half after armea1ing.

• Journal of the Korean Magnetics Society
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• v.1 no.2
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• pp.42-48
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• 1991

The basic soft magnetic characteristics of a typical Fe based amorphous $Fe_{80}B_{15}Si_{5}$ alloy were measured with pulse metheod. Quantitative relations between magnetostriction, anisotropy energy, reluctivity were investigated. The relative contribution factor of magnetostrictive and uniaxial anisotropy energy to the reluctivity were calculated. The internal stress and induced anisotropy were estimated. A tension applied to the long axis of the sample greatly enhanced induced anisotropy.