• 한국재료학회지
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• 제7권3호
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• pp.203-212
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• 1997

This paper evaluated the feasibility of laser consolidation for improving the properties of the plasma coated layer, Further, the mechanim of the degradation sequence of the chrome carbide layer applied on the turbine blades was postualted. The laser consolidation could be successfully applied for improcing the surface properties of the plasma coated blade, if a proper condition was carefully chosen. The consolidated layer had erosion & corrosion resistance and vond strength superiro to those of the as-plasma coated layer. The properties of the consolidated layer were strongly dependent upon the degree of dilution, especially on the Fe pickup from the substrate. The degradation of the plasma coating layer was thought to be a reault of the repeating action of the solid particle erosion, corrosion penetration through the pores and oxide films formed along the interlayer surface and impact spalling.

• 한국표면공학회지
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• 제53권2호
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• pp.72-79
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• 2020

Two Fe-Cr steels of T22 steel and STS430 steel were corroded at 650 and 750℃ for 100hr in sewage sludge-(0.3% SO₂-6% O₂-10% H₂O-balance CO₂) mixed gas environment. T22 steel corroded faster than STS430, indicating that the Cr content significantly influence the corrosion rates. T22 formed thick and non-protective Fe₂O₃ as the major oxide and Fe₃O₄ as the minor one. With an increase in corrosion temperature, their corrosion rates increased, being accompanied with formation of pores and cracks in the thickened oxide scales that were non-adherent. STS430 steel formed Fe₂O₃, Fe₃O₄ as the outer scale and (Fe, Cr)-O as the inner layer by which its corrosion rate is greatly reduced. Both the T22 and STS430 steel samples formed multi-layered scales by outward diffusion of Fe ions and inward diffusion of oxygen and sulfur ions at high-temperature more than 650℃.

• 한국자기학회지
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• 제2권1호
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• pp.8-14
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• 1992

${\gamma}-Fe_{2}O_{3}$ 입자의 보자력 특성을 향상시키기 위해 ${\gamma}-Fe_{2}O_{3}$ 입자표면상에 코발트 훼라이트를 결정화시켜 코발트 에피탁시얼 ${\gamma}-Fe_{2}O_{3}$ 입자를 제조하 였다. 피착층인 $Co_{x}Fe_{3-x}O_{4}$의 보자력은 x=1인 조성에서 가장 우수한 특성을 나타내었다. 반응 분위기를 초기 비산화성에서 산화성 분위기로 제어하여 제조한 시료의 자기 특성이 가장 우수하였으며 반응온도 $90^{\circ}C$에서 30분간 반응하면 ${\gamma}-Fe_{2}O_{3}$ 입자표면상에서의 코발트 훼라이트 피착 반응이 완료되었다.

• Corrosion Science and Technology
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• 제10권1호
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• pp.6-12
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• 2011

The selective surface oxidation of a transformation-induced-plasticity (TRIP) steel containing 1.6 wt.% Mn and 1.5 wt.% Si during annealing at $800^{\circ}C$ was investigated for its influence on the formation of an inhibition layer during hot-dip galvanizing. The selective oxidation of the alloying elements and the oxide morphology were significantly influenced by the annealing atmosphere. The pure $N_{2}$ atmosphere with a dew point $-40^{\circ}C$ promoted the selective oxidation of Mn as a crystalline $Mn_{2}SiO_{4}$ phase, whereas the $N_{2}$ + 10% $H_{2}$ atmosphere with the same dew point $-40^{\circ}C$ promoted the selective oxidation of Si as an amorphous Si-rich oxide phase. During hot-dip galvanizing, the $Mn_{2}SiO_{4}$ phase was reduced more readily by Al in the Zn bath than the Si-rich oxide phase. Consequently, the pure $N_{2}$ atmosphere resulted in a higher formation rate of $Fe_{2}Al_{5}$ particles at the Zn/steel interface and better galvanizability than the $N_{2}$ + 10% $H_{2}$ atmosphere.

• 한국세라믹학회지
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• 제54권2호
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• pp.137-140
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• 2017

A $TiO_2$ nanofilm was deposited on ${\alpha}-Fe_2O_3$ nanopowders using the atomic layer deposition method. The $TiO_2$ film was prepared at $300^{\circ}C$ using $Ti(N(CH_3)_2)_4$ and $H_2O$ as the precursor and reactant gas, respectively. The thickness and composition of the $TiO_2$ surface were characterized by TEM and EDS measurements. The TEM results showed that the growth rate of the film was about $0.12{\AA}/cycle$. The EDS and SAED analyses showed the presence of titanium oxide on the surface of the ${\alpha}-Fe_2O_3$ nanopowders, confirming the deposition of the $TiO_2$ nanofilm. The Zeta potential and sedimentation test results showed that the dispersibility of the coated nanopowders was higher than that of the uncoated nanopowders. This is attributed to the electrostatic repulsion between the $TiO_2$-coated layers on the surface of the ${\alpha}-Fe_2O_3$ nanopowders. The results revealed that the $TiO_2$-coated layers modified the surface characteristics of the ${\alpha}-Fe_2O_3$ nanopowders and improved their dispersibility.

• 전기화학회지
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• 제4권4호
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• pp.139-145
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• 2001

본 연구에서는 리튬전지내 양극 재료로서 리튬철계 산화물을 제조하여 전극재료의 다양한 조성에 따른 전기화학적 특성을 고찰하고자 하였다 출발 물질인 $FeCl_3-6H_2O,\; NaOH,\;LiOH$를 혼합하여 저온으로 가열하여 층상의 $LiFeO_2$를 합성하였으며 출발 물질의 조성비를 바꾸어 그 영향을 조사하였다. 그 결과 NaOH의 첨가량이 증가할수록 전극의 용량은 감소하나 효율 및 용량의 감소율은 작아짐을 알 수 있었다. $NaOH/FeCl_3/LiOH$의 중량비를 2/1/7로 조성하여 합성하였을 때 가장 큰 용량을 보였으나 효율은 30회 순환 후 급격히 감소하였다. 층상의 $LiFeO_2$ 양극을 사용한 리튬 전지의 충방전 실험을 수행한 결과 이 셀은 1.5-4.5V의 범위에서 가역적임을 알 수 있었다 CPR방법을 사용하여 1M $LiPF_6/EC/DEC$ 전해질에서 확산계수를 측정하였다. 확산계수는 0.5$10^{-11}cm^2/s$임을 알 수 있었다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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• pp.387.1-387.1
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• 2014

A new class of temperature-sensing materials is demonstrated along with their integration into transparent and flexible field-effect transistor (FET) temperature sensors with high thermal responsivity, stability, and reproducibility. The novelty of this particular type of temperature sensor is the incorporation of an R-GO/P(VDF-TrFE) nanocomposite channel as a sensing layer that is highly responsive to temperature, and is optically transparent and mechanically flexible. Furthermore, the nanocomposite sensing layer is easily coated onto flexible substrates for the fabrication of transparent and flexible FETs using a simple spin-coating method. The transparent and flexible nanocomposite FETs are capable of detecting an extremely small temperature change as small as $0.1^{\circ}C$ and are highly responsive to human body temperature. Temperature responsivity and optical transmittance of transparent nanocomposite FETs were adjustable and tuneable by changing the thickness and R-GO concentration of the nanocomposite.

• 한국자기학회지
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• 제12권3호
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• pp.103-108
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• 2002

나노옥사이드(nato-oxide layer, NOL) 층이 고정층에 첨가된 스펙큘라 스핀밸브(specular spin valve)와 NOL이 없는 기본 스핀 밸브를 UHV 스퍼터 시스템에서 FeMn 반강자성층을 사용하여 탑 및 바텀 형 스핀밸브를 제조하였으며, 제조한 시료의 열처리 온도에 따른 자기저항 특성 및 교환바이어스 특성을 비교 분석하였다. 탑 형 스핀밸브에서는 NOL이 있는 경우 25$0^{\circ}C$ 열처리에서 9.2%의 자기저항비를 얻을 수 있었으며, 바텀 형 스핀밸브에서는 25$0^{\circ}C$ 열처리에서 10.1%의 자기저항비를 얻을 수 있었다. 따라서 바텀 형 스핀밸브가 탑 형 스핀밸브보다 고정층에 첨가된 NOL의 스펙큘라 반사 효과가 높아 자기저항비가 증가함을 확인하였다. 또한 바텀 형 스핀밸브에서 25$0^{\circ}C$ 이상의 열처리시 NOL이 있는 경우가 NOL이 없는 경우보다 28 % 이상의 교환바이어스 증가를 보였다. 이와 같은 원인은 NOL이 첨가된 고정층의 자기모멘트의 감소와 X-선 회절 분석 결과로부터 NOL의 첨가에 따른 강화된 (111) FeMn집합조직 때문이라고 판단된다.

• 한국재료학회지
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• 제15권4호
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• pp.224-232
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• 2005

Dry sliding wear behavior of electro-pressure sintered Fe-Ni and Co-Fe-Ni compacts was investigated. Pin-on-disk wear tests were performed on the sintered Fe-Ni, Co-Fe-Ni disk specimens against alumina $(Al_2O_3)$ and silica $(SiO_2)$ ball counterparts at various loads ranging from 3N to 12N. A constant sliding speed of 0.1m/sec was employed. Wear rate was calculated by dividing the weight loss measured after the test by specific gravity and sliding distance. Worn surfaces and cross sections of them were examined by a scanning electron microscopy, and wear mechanism of the compacts was investigated. Wear characteristics of the compacts were discussed as a function of composition of the compacts. Relationship between the wear rate and mechancial properties of the compact was explored, and effects of the oxide layer that was formed on wearing surface of the compacts on the wear were also studied.

• 열처리공학회지
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• 제37권5호
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• pp.207-214
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• 2024

This study examines the effects of post-oxidation treatment on the microstructure and corrosion resistance of GC250 cast iron. The nitriding process was conducted at 570℃ for 180 minutes with a fixed nitriding potential (Kn) of 1.5, followed by post-oxidation at 450℃, 500℃, and 550℃ for 120 minutes. The post-oxidized specimens showed increased surface hardness and case depth compared to the nitrided specimens, with a maximum surface hardness of approximately 890 HV0.1. The oxidation process increased the thickness of the nitrided layer by more than 3 ㎛, with the oxide layer thickness reaching up to 2.5㎛ as the oxidation temperature increased. XRD analysis identified the presence of ε-phase, γ'-phase, and Fe₃O⁴ phase on the surface. Polarization tests revealed that the specimen treated at the highest oxidation temperature had a corrosion current density of 20.26 ㎂/cm² and a corrosion potential of -0.22V, indicating enhanced corrosion resistance compared to the nitrided specimen. This improvement is attributed to the formation and increased thickness of the oxide layer, which enhances corrosion resistance. In conclusion, the oxide layer formed through post-oxidation treatment significantly improves the corrosion resistance of GC250 cast iron, with the effect becoming more pronounced at higher oxidation temperatures.