• Title/Summary/Keyword: Fe-containing

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Synthesis and Characterization of Fe-containing AC/TiO2 Composites and Their Photodegradation Effect for the Piggery Waste

  • Oh, Won-Chun
    • Environmental Engineering Research
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    • v.13 no.2
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    • pp.85-92
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    • 2008
  • In this present study, we have synthesized Fe-containing AC(activated carbon)/$TiO_2$ composites with titanium (VI) n-butoxide (TNB) as a titanium source to Fe treated AC through an impregnation method. The result of the textural surface properties demonstrates that there is a slight decrease in the BET surface area of composite samples with an increase of the amount of Fe treated. The surface properties of scanning electron microscope (SEM) presented a characterization of a porous texture on the Fe-containing AC/$TiO_2$ composites and homogenous compositions for Fe and titanium dioxide distributed on the sample surfaces. Fe compound peaks and a titanium dioxide structure were observed in the X-ray diffraction patterns for the Fe-containing AC/$TiO_2$ composites. The results of chemical elemental composition for the Fe-containing AC/$TiO_2$ composites showed that most of the spectra for these samples gave stronger peaks for C, O, treated Fe components and Ti metal than that of any other elements. From the photo degradation results for the piggery waste, the Fe-containing AC/$TiO_2$ composites showed an excellent degradation activity for the chemical oxygen demand (COD) due to a photocatalysis of the supported $TiO_2$, radical reaction by Fe species and the adsorptivity and absorptivity of porous carbon.

Oxidation Behavior of $Ni_xFe_{1-x}(OH)_2$ in $C\Gamma$-containing Solutions

  • Chung, Kyeong Woo;Kim, Kwang Bum
    • Corrosion Science and Technology
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    • v.2 no.3
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    • pp.148-154
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    • 2003
  • The addition of Ni leads to the formation of protective rust layer on steel and subsequently high corrosion resistance of steel in $Cl^-$-containing environment. $\alpha$-FeOOH, $\beta$-FeOOH, $\gamma$-FeOOH and $Fe_3O_4$ are formed mainly on steels exposed to $Cl^-$-containing environment. As the first work of this kind, this study reports the influence of Ni on the oxidation behavior of $Ni_xFe_{1-x}(OH)_2$ in $Cl^-$-containing solution at two different pH regions(condition I under which the solution pH is allowed to decrease and condition I under which solution pH is maintained at 8) where $\gamma$-FeOOH and $Fe_3O_4$ are predominantly formed, respectively, upon oxidation of $Fe(OH)_2$, In the presence of Ni(II) in the starting solution, the formation of $\beta$-FeOOH was facilitated and the formation of $\gamma$-FeOOH was suppressed with increasing Ni(II) content and with increasing oxidation rate of Fe(II). Ni(II) was found to have $Fe_3O_4$-suppressing effect under condition II.

Influence of basal medium formulations and silver nanoparticles on in vitro plant growth in gerbera

  • Hyun Hee Kang;Aung Htay Naing;Junping Xu;Mi Young Chung;Su Young Lee;Jeung-Sul Han;Chang Kil Kim
    • Journal of Plant Biotechnology
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    • v.50
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    • pp.183-189
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    • 2023
  • This study investigated the impact of two distinct MS basal media: one containing FeNaEDTA and the other FeEDDHA, on the growth of five unique gerbera cultivars (Shy Pink, Pink Holic, Breeze, Harmony, Snow Dream). Notably, the response to these media types varied significantly among the cultivars, particularly concerning leaf yellowing and plant growth. 'Shiny Pink' and 'Pink Holic' exhibited leaf yellowing on the FeNaEDTA-containing medium but displayed leaf greening on the FeEDDHA-containing medium. In contrast, 'Snow Dream,' 'Harmony,' and 'Breeze' remained unaffected on both medium types. However, the FeNaEDTA-containing medium promoted higher plant height and petiole length in 'Breeze,' 'Harmony,' and 'Snow Dream' than the FeNaEDTA-containing medium did. A promotive effect of silver nanoparticles (AgNPs) on plant growth and leaf greening was observed in 'Pink Holic,' particularly on the FeNaEDTA-containing medium, while the addition of AgNPs to the FeEDDHA-containing medium negatively affected plant growth. These results highlight the substantial influence of medium type, specifically the presence of FeNaEDTA or FeEDDHA, on gerbera growth responses, emphasizing the critical role of medium selection in gerbera propagation. Additionally, when contemplating the addition of AgNPs for in vitro gerbera propagation, it is crucial to consider the medium type.

The Effect of Carbon on the Hot Corrosion of lron by Sulfur Containing Environment. (철의 고온 황화부식에 미치는 탄소의 영향)

  • 최성필;강성군;백영남
    • Journal of the Korean institute of surface engineering
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    • v.21 no.2
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    • pp.53-67
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    • 1988
  • The high temperature corrosion of Fe-C alloys were studied at I atm SO gas in the temperature range 500~80$0^{\circ}C$ by means of a thermogravimetric analysis. The Na2SO4 induced high tempwrature corrosion rate was also measured at atm O2 gas under above the temperature renge. The reaction products were identified with the aid of X-ray diffraction technique, and micostruction of the alloy/scale interface was observed with a optical microscope and SEM. The experimental results were disussed by the themodeynamic calcutions. Under above the experimental condition. the reaction rates decrbon with increasing carbon content. The transfer of Fe ion was limited by a residue of carbon precipitated at alloy scale interface due to the oxidation of Fe-C alloys at alloy surface. The effect of cold working on reaction rate was different between the Fe containing low carbon and Fe-C Alloy containing carbon above 0,73 wt%. In a cold worked iron containing low carbon content, the crystallization of metal surface leads to the poor adherence between the alloy and the cavity formed between the alloy and scale. The outward diffusion of ion through the scale is estimated to be hindered by the cavity formed between the scale, consequently decreasing reaction rate. In the case Fe-C containing carbon above 0.73 Wt% alloy, the reaction rate was little affected by cold working, because the effect of content on reaction rats is greater than the effect of cold working.

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Effect of Heat-treatment in Low Thermal Expansion Coefficient Fe-Ni-Co alloy for Core Material of Increased Capacity Transmission Line (증용량 송전선 강심용 저열팽창 Fe-Ni-Co 합금에 있어서 용체화처리 영향)

  • 김봉서;유경재;김병걸;이희웅
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.950-952
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    • 2000
  • Considering the effective distribution coefficient of Ni in Fe-Ni-Co invar alloy containing a little amount of carbon, we investigated on the thermal expansion coefficient(${\alpha}$). Fe-Ni-Co invar alloy had a large thermal expansion coefficient in as-casted compared with solution treated. The thermal expansion coefficient of Fe-Ni-Co alloy increased with the carbon content in both state of as-casted and solution treated. The effective distribution coefficient(Ke$\^$Ni/) of Ni was smaller than unity in alloy of not containing carbon, but is way larger than unity in alloy of containing carbon. It was considered that the homogeneity of Ni in primary austenite affected thermal expansion coefficient.

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Effects of Dietary Chelated Fe and Yeast Fe on Growth Performance and Body Composition in Broiler Chicks (유기태 철과 효모철의 첨가급여가 육계의 성장 및 체조성에 미치는 영향)

  • Na S.J.;Oh J.I.;Uuganbayar D.;Jung D.K.;Kim H.Y.;Moon S.T.;Yang C.J.
    • Korean Journal of Poultry Science
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    • v.33 no.2
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    • pp.113-119
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    • 2006
  • This study was carried out to investigate the effects of dietary Saccharomyces cerevisiae (wild yeast mutant) and Saccharomyces cerevisiae hFeHLC (ferritin containing yeast) and chelated Fe on growth performance and body composition of broiler chicks. A total of 252 (1-day old) 'Ross' broiler chicks were allotted to seven dietary treatments: I) control without iron supplementation, 2) 0.1% wild yeast mutant (YM03), 3) 1.0% wild yeast mutant, 4) 0.1% ferritin containing yeast (YF04), 5) 1.0% ferritin containing yeast, 6) 0.01% chelated Fe and 7) 0.1% chelated Fe. The highest weight gain obtained from broilers fed 0.01% chelated Fe was 2,121g, the lowest weight gain obtained from broilers fed control diet was 2.087g. The growth performance results were not significantly different in weight gain, feed intake and feed conversion ratio of broilers diets containing wild yeast, ferritin containing yeast and chelated Fe supplementation and control diets (P>0.05). The lowest iron content in meat was for control 30.51 mg/dL and the highest Fe content was for 0.1% ferritin containing yeast 41.58 mg/dL, but these were not significantly different (P>0.05).

Cloning, DNA Sequence Determination, and Analysis of Growth-Associated Expression of the sodF Gene Coding for Fe- and Zn-Containing Superoxide Dismutase of Streptomyces griseus

  • Kim, Ju-Sim;Lee, Jeong-Kug
    • Journal of Microbiology and Biotechnology
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    • v.10 no.5
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    • pp.700-706
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    • 2000
  • Iron- and zinc-containing superoxide dismutase (FeZnSOD) and nickel-containing superoxide dismutase (NiSOD) are cytoplamic enzymes in Streptomyces griseus. The sodF gene coding for FeZnSOD was cloned from genomic Southern hybridization analysis with a 0.5-kb DNA probe, which was PCR-amplified with facing primers corresponding to the N-terminal amino acid of the purified FeZnSOD of S. griseus and a C-terminal region which is conserved among bacterial FeSODs and MnSODs. The sodF open reading frame (ORF) was comprised of 213 amino acid (22,430 Da), and the deduced sequence of the protein was highly homologous (86% identity) to that of FeZnSOD of Streptomyces coelicolor. The FeZnSOD expression of exponentially growing S. griseus cell was approximately doubled as the cell growth reached the early stationary phase. The growth-associated expression of FeZnSOD was mainly controlled at the transcriptional level, and the regulation was exerted through the 110 bp regulatory DNA upstream from the ATG initiation codon of the sodF gene.

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HYDROGEN DECREPITATION AND MAGNETIC PROPERTIES OF $Sm_{2}Fe_{17}-TYPE$ ALLOY MODIFIED WITH A SMALL ADDITION OF Nb

  • Kwon, H.W.;Harris, I.R.
    • Journal of the Korean Magnetics Society
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    • v.5 no.5
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    • pp.432-436
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    • 1995
  • The hydrogen decrepitation behaviour of the $Sm_{2}Fe_{17} alloy containing 4at%Nb was examined by means of DTA and SEM metallography, and the magnetic properties of the alloy were studied by means of VSM or TMA. It has been found that a simple hydrogenation and degassing treatment for the alloy caused a poor hydrogen decrepitation. The cycle treatment consisting of repeated hydrogenation and degassing, however, caused a severe hydrogen decrepitation with a combination of intergranular and transgranular failure. The disproportionation temperature of the hydrogenated $Sm_{2}Fe_{17}-type alloy was enhanced significantly by small addition of Nb. It has also been found that the Curie temperature of $Sm_{2}Fe_{17} matrix phase in the Nb-containing alloy has been enhanced by the hydrogenation, and this was attributed to the increase in interatomic distance between the neighbouring iron atoms caused by the interstitial occupancy of the hydrogen atom into the $Sm_{2}Fe_{17}-type lattice. The magnetisation of the $Sm_{2}Fe_{17} alloy containing Nbwas found to be lower than that of the Nb-free alloy, and this was explained by the dilution effect due to the presence of the paramagnetic $Sm_{2}Fe_{17} phase.

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A Study on the V22Ti16Zr16Ni39X7(X=Cr, Co, Fe, Mn, Al) Metal Hydride Electrodes (V22Ti16Zr16Ni39X7(X=Cr, Co, Fe, Mn, Al) 금속수소화물전극에 관한 연구)

  • Kim, Jeong-Seon;Cho, Won-Il;Cho, Byung-Won;Yun, Kyung-Suk;Kim, Sang-Joo
    • Transactions of the Korean hydrogen and new energy society
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    • v.5 no.1
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    • pp.1-8
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    • 1994
  • Lattice structure, hydrogen absorption characteristics, discharge capacity and cycle life of $V_{22}Ti_{16}Zr_{16}Ni_{39}X_7$(X= Cr, Co, Fe, Mn, Al) alloys were investigated. The matrix phases of these alloys were the C14 Laves phase. Chromium-containing alloy had a vanadium-rich phase in addition to the Laves phase. The chromium, maganese, or aluminum-containing alloys had lower hydrogen equilibrium pressure and larger hydrogen absorption content than the cobalt or iron-containing alloys. The discharge capacities of these alloys were 270~330mAh/g. The discharge capacity according to the alloying element X decreased in the order of Mn>Cr>Co, Al)Fe. The charge/discharge cycle lives of the chromium, cobalt or iron-containing alloys were longer than those of maganese or aluminum-containing alloys due to the lower vanadium dissolution rate.

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Effect of Fe Content on Mechanical and Electrochemical Properties of Ti-Mo-Fe Alloys (Ti-Mo-Fe 합금의 Fe 함량에 따른 기계적 특성과 전기화학적 특성 비교·분석)

  • Ji-Won Kim;Jeong-Yeon Park;Min Gang;Ji-Hwan Park;Dong-Geun Lee
    • Journal of the Korean Society for Heat Treatment
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    • v.36 no.3
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    • pp.145-152
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    • 2023
  • β titanium alloys containing β stabilizing elements such as V, Nb, Ta, Mo and Fe are widely used etc, due to their excellent specific strength, corrosion resistance, fatigue strength and easy formability. New metastable β titanium alloys are developed containing low-cost elements (Mo and Fe) in this study. Fe element is a strong β-stabilizer which can affect the mechanical and electrochemical properties of Ti-5Mo-xFe (x = 1, 4 wt%) alloys. These properties were analyzed in connection with microstructure and phase distribution. Ti-5Mo-4Fe alloy showed higher compression yield stress and maximum stress than Ti-5Mo-1Fe alloy due to solid-solution hardening and grain refinement hardening effect. As Fe element increased, Fe oxide formation and reduction of ${\bar{Bo}}$ (bond order) value affect the decrease of corrosion resistance. Ti-5Mo-xFe alloys were more excellent than Ti-6Al-4V ELI alloy.