• Economic and Environmental Geology
• /
• v.34 no.4
• /
• pp.319-328
• /
• 2001

The Fe-REE deposit of the Hongcheon-Jaeun district occurs in Precambrian gneiss, and is classified into two ore bodies: the Jaeun ore body (northern ore body) and the Hongcheon ore body (southern ore body). Ecomonically important minerals consist of magnetite, monazite, strontianite and barite. Based on mineral assemblages and textures, the mineralization can be classified into two stages (Na-carbonatite stage and Fe-carbonatite stage). Main REE minerals were precipitated during the Fe-carbonatite stage. Some evidences of the carbonatite origin include: 1) strontianite-monazite exolution texture, 2) strontianite-barite exolution texture, 3) the occurrence of acmite of igneous origin at the area with abundant rare earth minerals, 4) the occurrence of the mineral assemblage consisting of carbonate minerals + magnetite + REE minerals. Therefore, we suggest that Fe-REE mineralization in the study area was related to carbonatite of igneous origin.

• Journal of the Mineralogical Society of Korea
• /
• v.26 no.4
• /
• pp.299-312
• /
• 2013

Magnetite, a major constituent mineral of the Hongcheon carbonatite-phoscorite complex, was produced over three stages in each rock type and decreased in quantity toward the late stage. Electron microprobe analyses for magnetite revealed that Ti and V were detected in traces, but showed increasing tendency from early to late stage. On the contrary, Mg and Mn decreased distinctly, and it is the general differentiation trend of carbonatitic magma. Al also showed decreasing tendency in carbonatite and phoscorite, and Cr was mostly below detection limit except late phoscorite. In early stage, $Fe^{2+}$ was largely replaced by $Mg{2+}$ and $Mn^{2+}$, and $Fe^{3+}$ by $Al^{3+}$ in magnetite, but it has nearly pure composition in late stage. Tendency of increase in V and decrease in Mn toward late stage represents that magma differentiation progressed under the condition of decreasing oxygen fugacity. Low concentrations of Mg, Al, Cr and Ti, as well as the absence of olivine and phlogopite, suggest that the Hongcheon carbonatite-phoscorite complex was generated from depleted magma. Especially, lower concentrations of Mg in magnetite compared to other typical carbonatite-phoscorite complex, and abundant occurrence of Fe-carbonate minerals and quartz in late stage, suggest that magma differentiation of the Hongcheon carbonatite-phoscorite proceeded to the latest stage.

• The Journal of the Petrological Society of Korea
• /
• v.11 no.2
• /
• pp.90-102
• /
• 2002

The studied Fe-REE ore consists of magnetite, ankerite, siderite, magnesite and strontianite as the major constituent, and monazite, columbite, fergusonite, apatite, aegirine-augite, Na-amphibole, pyrite, chalcopyrite, sphalerite, molybdenite and barite as accessaries. Wall rock of ore deposits is replaced to fenite due to Na-metasomatism and mainly consists of sugary albite and Na-amphibole. Monazite $Ce_{0.49}La_{0.31}Pr_{0.14}Nd_{0.03}Gd_{0.03})PO_4$ is the main mineral for REE deposit and shows myrmekitic intergrowth with strontianite $Ca_{0.02-0.16}Sr_{0.84-0.98}CO_3$ and is corroded by carbonate minerals. Mineral forming sequence can be divided into early and late periods by the development of microfractures. The early period minerals such as magnetite, ankerite, magnesite, monazite and apatite show well developed networks of microfractures due to cataclastic deformation caused by enriched $CO_2$ gas in melts during emplacement. The late minerals of columbite, fergusonite, siderite molybdenite, chalcopyrite and sphalerite formed after the brecciation event and have little micro-fractures. Ankerite, magnesite, monazite, strontianite, barite and pyrite seem to be formed continuously from the ealy to the late period since they show textures both with well developed fractures and also with little fractures. Mineral chemistry, mineral assemblages such as various carbonate minerals, magnetite, REE minerals of monazite and fergusonite, Sr mineral of strontianite, and Nb minerals of columbite, myrmekitic texture of monazite and ankerite, and well developed fenite along ore deposits observed from this studied area strongly indicate that this Hongcheon Fe-REE ore deposits are formed from carbonatitic melt and its rock type is late differentiated Fe-carbonatite or ankerite-carbonatite.

• Proceedings of the Mineralogical Society of Korea Conference
• /
• 2003.05a
• /
• pp.67-67
• /
• 2003

The chemical compositions and textural relationships of the Nb-Zr oxide minerals including pyrochlore [ideally (Ca,Na)$_2$Nb$_2$O$\sub$6/(OH,F), with up to 24% UO$_2$ and 16% Ta$_2$O$\sub$5/] and baddeleyite [ideally ZrO$_2$, with up to 6% Nb$_2$O$\sub$5/] in the Sokli carbonatite complex, Kola Peninsula, Arctic are described. These two minerals in carbonatites are the major hosts for the HFSEs such as U, Th, Ta, Nb, Zr and Hf and thus are interest both economically and petrologically. The Sokli carbonatite complex (360-370 Ma) in Northern Finland, which forms a part of the Paleozoic Kola Alkaline Province (KAP), is mainly composed of multi-stages of carbonatite and phoscorite associations (P1-C1 P2-C2, P3-C3, D4 and D5) surrounded by altered ultramafic rocks (olivinite and pyroxenite) and cut by numerous small dikes of ultramafic lamprophyre. The Sokli complex contains the highest concentration in niobium and probably in tantalum, which are economically very important to modern steel technology, among the ultramafic-alkaline complexes of the KAP. Pyrochlore and baddeleyite mostly concentrate in the phoscorites. Pyrochlores in the Sokli complex are generally rounded octahedra and cubes in shape, red brown to grey yellow in color, and 0.2 to 5 mm in size. They are found in all calcite carbonatites, phoscorites and dolomite carbonatites, except P1-C1 rocks. These pyrochlores display remarkable zonations which depend on host rock compositions, and have significant compositional variations with evolution of the Sokli complex. The common variation scheme is that (1) early pyrochlore is highly enriched in U and Ta; (2) these elements decrease abruptly in the intermediate stage, while Th and Ce increase, and (3) late stage pyrochlore is low in U, Ta, Th, and Ce, and correspondingly high in Nb. Baddeleyites in the Sokli complex occur in the early P1-C1 and P2-C2 rocks and rarely in P3. They crystallized earlier than pyrochlores, and occasionally show post-magmatic corrosion and replacement. The FeO and TiO$_2$ contents of baddeleyites are much lower than those of the other terrestrial and lunar baddeleyites, whereas Nb$_2$O$\sub$5/ and Ta$_2$O$\sub$5/ contents are the highest among the reported compositions. Ta/Nb and Zr/Nb ratios of pyrochlores and baddeleyites decrease towards later stage facies, which is in accordance with the whole rock compositions. The variation of Ta/Nb and Zr/Nb ratios of pyrochlores and baddeleyites is considered to be a good indicator to trace an evolution of the carbonatite complexes.

• The Journal of the Petrological Society of Korea
• /
• v.12 no.3
• /
• pp.135-153
• /
• 2003

In order to understand its origin and petrogenesis, petrochemical studies of major, trace elements, REE, and stable isotopes of oxygen and carbon from the Hongcheon Fe-REE deposits have been investigated. The Hongcheon Fe-REE deposit intruding into Precambrian metasedimentary rocks consists of magnetite, various carbonates such as ankerite, siderite, magnesite and strontianite, monazite, aegirine-augite, Na-amphibole, and sulfides. Compared with major elements abundances of typical ferro-carbonatites, the Hongcheon Fe-REE deposit is enriched in FeO and depleted in CaO with increasing of $SiO_2$, where $TiO_2$and $A1_2O_3$increased and CaO, FeO, MgO and $P_2O_5$ are slightly decreased, but those are rather scattered and their trends are somewhat ambiguous. V Ni, U and Rb slightly increasing with of $SiO_2$increase and scattering or no trends of other detected elements. Nb, Zr and Zn are depleted then the abundances of typical ferro-carbonatites (Woolley and Kempe, 1989). In rare earth elements a large enrichment of total REE (maximum 14.8 wt%) and LREE relative to chondrites and HREE depleted more then the values of ferro-carbontites therefore La/Lu ratios shows large abundances (max. 16,197). The results of stable isotopes of O and C from minerals of ankerite and strontianite and whole rocks represent studied rocks are from igneous carbonatitic melts. Although petrochemical characteristics of the Hongcheon Fe-REE deposits are somewhat different from normal ferro-carbonatites from the world, this discrepancy suggests another conclusion that petrochemical characteristic of the studied Fe-REE mineralized rocks are similar to those of phoscorites from Kovdor, Russia and Sokli, Finland showing the same petrochemical compositions described above.

• Journal of the Mineralogical Society of Korea
• /
• v.19 no.4 s.50
• /
• pp.325-336
• /
• 2006

Domestic serpentinite is one of the important industrial minerals utilizing in the iron manufacturing company such as POSCO in Korea. Serpentinite is distributed in the Ulsan Fe deposit, Andong, Hongseong-Cheongyang, and Gapyeong areas. This study tries to interpret the relationship among the formation of carbonate rocks, iron mineralization, and serpentinite alteration throughout the study of field occurrence, mineralogy, and chemical compositions. Serpentine is formed by the break-down of olivine and pyroxene of parent peridotite. The serpentinization is inferred to be formed by the hydrothermal fluid derived from intruded Cretaceous granite and the addition of meteoric water. Variation of major oxides such as $SiO_2,\;Fe_2O_3$, and MgO in serpentinized rocks are controlled by the degree of serpentinization and Fe mineralization. Variation of $Al_2O_3$ and CaO contents of altered rocks is dependent on the amount of the residual minerals such as calcite and homblende, and on the degree of chloritization. The presence of carbonate rocks reported in the sedimentary origin or igneous origin (carbonatite) provided a geological environment to form skarn type Fe deposit regardless of its origin. The geological processes of Ulsan Fe deposits are inferred to be formed as the order of the formation of carbonate rocks ${\to}$ the intrusion of Cretaceous granite ${\to}$ serpentinization ${\to}$ Fe mineralization by the interprelation of field occurrence and mineralogical characteristics.