• Title/Summary/Keyword: Fe-As-S 계

Search Result 144, Processing Time 0.031 seconds

Effect of Sealing Process on the Tribological Behavior of the Plasma Spray Zirconia Based Coatings (지르코니아 충전이 지르코니아계 용사코팅층의 마모마찰에 미치는 영향)

  • 신종한;임대순;안효석
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
    • /
    • 1998.10a
    • /
    • pp.265-271
    • /
    • 1998
  • High temperature wear behavior of plasma sprayed zirconia based coating sealing with zirconia sol were investigated for high temperature wear resistance application. The zirconia powders containing 2.5, 5.0, 7.5, 10.0 mol% of MoS$_2$, $Fe_2O_3$ for plasma spray were made by spray drying method. As-sprayed coating was sealed by zirconia-sol to fill up the pore and crack in coating. wear test were performed at temperature ranges from room temperature to 600$\circ$C. The microstructural changes of before and after sealing process were examined by SEM, XRD and EPMA. After sealing process, the porosity was decreased and micro-hardness was increased. The wear properties of coating after sealing process were improved by sealing of pores and cracks. The behavior of wear amount and coefficient of friction were same tendency to before sealing process.

  • PDF

Mean Field Analysis of Exchange Coupling in Amorphous RE$Fe_2$-B (RE=Dy, Sm) Alloy Ribbons (비정질 RE$Fe_2$-B (RE=Dy, Sm) 합금 리본에서 평균장 이론에 의한 교환상호작용 계산)

  • Lee, J. M.;J. K. Jung;S.H. Lim
    • Journal of the Korean Magnetics Society
    • /
    • v.11 no.3
    • /
    • pp.85-96
    • /
    • 2001
  • Experimental magnetization-temperature curves for melt-spun ribbons of amorphous alloys (Dy$\_$0.33/Fe$\_$0.67/)$\_$1-x/B$\_$x/(x=0 ,0.05, 0.1, and 0.15) and (Sm$\_$0.33/Fe$\_$0.67/)$\_$1-x/B$\_$x/(x=0, 0.01, 0.02, and 0.03) (in atomic fraction) are fitted with theoretical equations based on the mean field theory in order to calculate exchange couplings between constituent elements as a function of the B content. In the case of the DyFe$_2$-B system, the sign of the exchange coupling between Dy and Fe is negative, indicating that the magnetization direction of Dy is antiparallel to that of Fe. The sign of the other two couplings are positive indicating a parallel alignment. The exchange coupling between Fe ions are greatest, while that between Dy ions is negligible. In the case of the SmFe$_2$B alloys, the sign of all the couplings are positive, indicating ferromagnetic coupling between the spins. The exchange couplings between Fe ions, and Fe and Sm are comparable to each other, but they are much greater than that between Sm ions. The high exchange coupling between Fe and Sm, which is considered to occur indirectly, is rather unexpected, but it is considered to be unique characteristics of amorphous Sm-Fe alloys. In both alloy systems, the exchange coupling between Fe ions increases with increasing B content. and this may be explained by the increase of the Fe-Fe separation with increasing B content. The exchange coupling between Fe and RE also increases with increasing B content. As the B content increases, the magnetization decreases over the whole temperature range, and the Curie temperature also decreases.

  • PDF

Effect of Fe2O3 Concentration in Coal Slag on the Formation of (Fe,Cr)3O4 in Chromia Refractory (크롬계 내화물에서 슬래그의 산화철 농도가 (Fe,Cr)3O4 형성에 미치는 영향)

  • Park, Woo Sung;Oh, Myongsook S.
    • Applied Chemistry for Engineering
    • /
    • v.18 no.5
    • /
    • pp.495-500
    • /
    • 2007
  • The inside wall of a coal gasifier is lined with refractory, and the corrosion of the refractory is an important factor affecting the refractory lifetime and the replacement period. This paper examines the changes in microstructure of a chromia refractory due to chemical reactions with slag having varying amounts of $Fe_2O_3$. Slag samples were prepared by adding $Fe_2O_3$ to KIDECO slag, and static corrosion experiments were carried out at $1550^{\circ}C$. The layer of $(Fe,Cr)_3O_4$ formation and the depth of Fe depletion in the infiltrating slag were determined. In addition, FactSage equilibrium calculations were carried out in order to determine the conditions of formation, and to compare with the experimental observations. In the sample exposed to KIDECO slag, which has about 10 wt% $Fe_2O_3$, the formation of $(Fe,Cr)_3O_4$ was not observed. As the $Fe_2O_3$ concentration in slag increased, $(Fe,Cr)_3O_4$ formation and Fe depletion depth increased. Increasing $Fe_2O_3$ concentration also made the slag/refractory interface indistinguishable. Equilibrium calculations predicted that higher $Fe_2O_3$ concentrations favor chromite formation at gasification temperatures. The chromite formation was most favorable when the amount of $Cr_2O_3$ was limited, as in the case of dissolved $Cr_2O_3$ in slag. When the concentration of $Fe_2O_3$ in slag was less than 20%, the formation of chromite was least favorable in the system with equal amounts of slag and refractory.

Study on Physical and Chemical Properties of CaO-Al2O3 System Melting Compound (CaO-Al2O3계 용융화합물의 물리·화학적 특성에 관한 연구)

  • Lee, Keun-Jae;Koo, Ja-Sul;Kim, Jin-Man;Oh, Sang-Yoon
    • Journal of the Korea Concrete Institute
    • /
    • v.25 no.2
    • /
    • pp.209-215
    • /
    • 2013
  • This study is aimed to identify the method to use the CaO-$Al_2O_3$ system of rapidly cooled steel making slag (RCSS) as the environment-friendly inorganic accelerating agent by analyzing its physical and chemical properties. The fraction of rapidly cooled steel making slag is distinguished from its fibrous, and the contents of CaO and $Fe_2O_3$ are inversely proportional across different fractions. In addition, as the content of CaO decreased and the content of $Fe_2O_3$ increased, the loss ignition tended to become negative (-) and the density increased. The pore distribution by mercury intrusion porosimetry is very low as compared to the slowly cooled steel-making slag, which indicates that the internal defect and the microspore rate are remarkably lowered by the rapid cooling. To analyze the major minerals the rapidly cooled steel-making slag, XRD, f-CaO quantification and SEM-EDAX analysis have been performed. The results shows that f-CaO does not exist, and the components are mainly consisted of $C_{12}A_7$ and reactive ${\beta}-C_2S$.

Antioxidative Activity of Ulmi cortex Extract (유백피(Ulmi cortex) 추출물의 항산화 활성)

  • 이경행;전은경;유시영;오만진
    • Food Science and Preservation
    • /
    • v.7 no.4
    • /
    • pp.373-379
    • /
    • 2000
  • The Ulmi corex extract was prepared using various solvents to investigate the availability as a natural antioxidant. The extracts were added to lard emulsion and the antioxidant activities were compared. The extract that had a greater antioxidant activity was fractionized. Then the antioxidant activity and substrate specificity of the fraction were examined and optimum concentration of addition was determined. To observe the antioxidative effect of the fraction in vivo, an inhibition rate of lipid peroxidation from which might be derived was measured using a microsome in rat's liver. Among the extracts of Ulmi cortex, the extract from water had the best antioxidant activity, and the addition of 0.05% (w/w) of ethyl acetate fraction showed similar antioxidant activity to a synthetic antioxidant, butylated hydroxyanisole(BHA). Ethyl acetate fraction (0.05%, w/w) also presented the antioxidative effect in lard, soybean oil, palm oil, and com oil. The inhibition of lipid peroxidation in liver microsome showed feater in the ethyl acetate fraction than caffeic acid in both nonenzymatic peroxidation (Fe$\^$++/ascorbate system) and enzymatic peroxidation (Fe$\^$++/-ADP/NaDPH system).

  • PDF

Influence of pH on Leaching Behavior of Phosphorous from Steelmaking Slag (제강슬래그에서 인의 침출 거동에 대한 pH의 영향)

  • Kim, Jeong-In;Kim, Sun-Joong
    • Resources Recycling
    • /
    • v.25 no.6
    • /
    • pp.23-28
    • /
    • 2016
  • In this study, leaching process to extract phosphorus from the steelmaking slag was investigated for using the fertilizer resources of agriculture. In general, the phosphorus of steelmaking slag is formed as $C_2S-C_3P$ solid solution, and also, this solid solution is soluble in water more than the other phase in slag, and less than free CaO phase. In the present experiment, the influence of pH on the leaching behavior of various elements from the steelmaking slag was investigated by using multi-component steelmaking slag. When the pH was decreased, the concentration of Ca, Si, P and Fe in solution from the steelmaking slag was increased. Furthermore, at a pH of 3, the concentration of P ion in solution was decreased as leaching time increased. It is considered that the decrement of P was caused from the precipitation reaction between P ion and Fe ion in solution.

Effect of Microstructure on the Damping Capacity and Tensile Properties of Fe-Al-Mn Alloys (Fe-Al-Mn 합금의 진동감쇠능 및 인장성질에 미치는 미세조직의 영향)

  • Son, D.U.;Kim, J.H.;Lee, J.M.;Kim, I.S.;Kim, H.C.;Kang, C.Y.
    • Journal of Power System Engineering
    • /
    • v.8 no.4
    • /
    • pp.31-37
    • /
    • 2004
  • The damping capacity and strength of Fe-2Al-26Mn alloys have been studied for the development of new materials with high strength and damping capacity. Particularly, the effect of ${\alpha}'\;and\;{\varepsilon}$ martensite phase, which constitutes the microstructure of cold rolled Fe-Al-Mn alloys, has been investigated in terms of the strength and damping capacity of the alloys. The damping capacity rises with increasing the degree of cold rolling and reveals the maximum value at 25% reduction. The damping capacity is strongly affected by the volume fraction of ${\varepsilon}$ martensite, while the other phases, such as ${\alpha}'$ martensite and austenite phase, actually exhibit little effect on damping capacity. Considering that tensile strength increases and elongation decreases with increasing the volume fraction of ${\alpha}'$ martensite, it is proved that tensile strength is mainly affected by the amount of ${\alpha}'$ martensite.

  • PDF

In-Plane Vibration Analysis of General Plates (일반 평판의 면내 진동 해석)

  • Choi, M.S.;Yeo, D.J.;Byun, J.H.;Suh, J.J.;Yang, J.K.
    • Journal of Power System Engineering
    • /
    • v.11 no.4
    • /
    • pp.78-85
    • /
    • 2007
  • In order to analyze accurately the vibration of a structure by using the finite element method (FEM), we have to model a analytical structure as a numerical model with many degrees-of-freedom. However, in this case, the FEM needs much computation time and storage. The authors developed the finite element-transfer stiffness coefficient method (FE-TSCM) for overcoming the drawback of the FEM. In this paper, the authors apply the FE-TSCM to the in-plane vibration analysis of general plates with various shapes. Two numerical examples, a rectangular plate and a triangular plate, are used to compare the results of the FE-TSCM and the FEM. Through the numerical calculation, we confirm that the FE-TSCM can be applied to the in-plane free or forced vibration analysis of the general plates with various shapes and is effective to in-plane vibration analysis of general plates.

  • PDF

A Study on the Dyeing Properties of Yellow and Red Natural Dyes(1) (황색 및 적색계 천연염료의 염색성에 관한 연구(1))

  • Shin, Young-Joon
    • Journal of the Korea Fashion and Costume Design Association
    • /
    • v.17 no.2
    • /
    • pp.45-61
    • /
    • 2015
  • In order to analysis on color difference of natural dyes, I have dyed Hanji, cotton, silk fabric and exposed them to carbon arc light. The results of experiment have been analysed by wavelength of maximum absorption, amounts of dye uptake, color difference, Hunter's value and Munsell's value. Gardenia Jasminoides is monogenetic dye, but it gained darker color by pre-mordanting method used Al mordant agent and greenish yellow color by Fe mordant agent. whereas Curcuma, an Amur cork, and bud of pagoda tree are shown as greenish yellow color, and A barberry root, Betel nut, and Rhubarb are shown as reddish yellow color. these gained khaki colored dyed fabric by Fe mordanting. In addition, Sappan wood showed great result in pre-mordanting. Especially, it gained dark red color by Al pre-mordanting. The pink color was shown by post-mordanting. and Logwood showed great dyeing result in Hanji and cotton better than silk. Specially pre-mordanting was effective. Hanji and cotton showed greenish blue color by Al pre-mordanting, and silk showed brown color.

  • PDF

DETERMINATION OF WIND PARAMETERS BY THE METHOD OF DIFFERENTIAL CORRECTIONS (차등보정법에 의한 항성풍인자의 결정)

  • 김유경;강영운
    • Journal of Astronomy and Space Sciences
    • /
    • v.11 no.1
    • /
    • pp.107-114
    • /
    • 1994
  • This paper describes a method for the determination of wind parameters as mass-loss rate, wind velocity, stochastic velocity in Zeta Aurigae type binaries. We have modified the Baade's (1989) computer code to analyze the wind parameters of Zeta Aurigae type binaries according to the least squares criterion. The modified program adjusts the wind parameters by the method of differential corrections. We have appled this method to the IUE observations of 32 Cygni. We have fitted a theoretical line profile to the IUE observations of Fe II resonance line at various phases. The mass-loss rate, wind velocity and stochastic velocity of 32 Cygni obtained in this paper are $2.18{\times}10^{-8}M_{\odot}/yr$, 132.14km/s, 39.82km/s, respectively.

  • PDF