• Korean Journal of Soil Science and Fertilizer
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• v.44 no.5
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• pp.767-772
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• 2011

The purpose of this study was to find out required time for recovery of nutritional disorder by Fe-DTPA treatment in induced Fe-deficient tomato cultivars and to select stable Fe-chelate in high pH of nutrient solution. The pH levels of nutrient solution were amended with 6.0, 7.0, and 8.0. Then Fe-EDTA (Ethylenediaminetetraacetic acid, ferric-sodium salt), Fe-DTPA (Sodium ferric diethylenetriamine pentaacetate), and Fe-EDDHA (Ethylenediamine-N,N-bis (2-hydroxyphenylacetic acid) ferric-sodium salt)) were treated as Fe $2.0mg\;L^{-1}$ concentration. The Fe-DTPA and Fe-EDDHA were stable in the nutrient solution of pH 6.0~8.0 but Fe-EDTA in nutrient solution of pH 8.0 was to become insoluble by 25%. The Fe $2.0mg\;L^{-1}$ as Fe-DTPA was treated for recovery of Fe deficient tomato seedlings. In case of Redyoyo and Supersunroad cultivars, total chlorophyll and Fe contents of leaves were recovered as much as those of normal leaves in 5 days. The Rafito cultivar for complete recovery was taken 7 days. When Fe $2.0mg\;L^{-1}$ as Fe-DTPA was supplied to Fe-deficient tomato seedlings, in geotype, heme oxigenase recovered as much as normal leaves in 24 hours in the Rafito and Redyoyo. However, it was not remarkable difference by elapsed time in the Supersunroad.

• Resources Recycling
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• v.20 no.5
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• pp.58-63
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• 2011

pH control-precipitation method is used for recovery of EDTA from waste fluid of archeological waterlogged wood conservation treatment. EDTA has been used for eliminating of blacken effect in archeological waterlogged wood which was buried in the ground for long period of time. The black substance is generated by Fe$^{3+}$ in the soil reacted with tannin in the archeological waterlogged wood. In order to remove the black substance in archeological waterlogged wood, EDTA was used. The black substance is eliminated from wood as Fe-EDTA complex are formed, and EDTA is separated and precipitated from Fe-EDTA complexes at pH 2.68 or less. The result of analysis of the precipitated products and the commercial EDTA by FT-IR and FE-SEM showed that precipitated product by pH adjusted was not a type of Fe-EDTA complex, but pure EDTA. In this study, Fe$^{3+}$ from waste fluid of EDTA can be separated by HCl added. EDTA can be recycled by using the method of precipitation of EDTA in a strong acid.

• Resources Recycling
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• v.26 no.4
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• pp.95-100
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• 2017

In this study, $Fe_2O_3$ was added as a flux to decrease melting temperature and refine during melting of Cu powder from scraped surface of the waste PCB (printed circuit board). The effect of $Fe_2O_3$ ratio to Cu powder and temperature on the recovery of Cu and content of impurities were investigated. It was found that the recovery of Cu was increased with increasing addition ratio of $Fe_2O_3$ and reaction temperature. The contents of O, Si and Fe in Cu phase were also decreased with increasing addition ratio of $Fe_2O_3$ and temperature. The formation of fayalite ($2FeO{\cdot}SiO_2$) and iron oxides phases in the slag was confirmed by XRD analysis after reaction with $Fe_2O_3$. Therefore, it was considered that the decrease of melting temperature and viscosity of slag by formation of fayalite slag contributed remarkably to the Cu recovery.

• Microbiology and Biotechnology Letters
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• v.26 no.3
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• pp.206-212
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• 1998

The effects of the pretreatment with coagulants on the recovery efficiency of poly (3-hydroxybutyrate, PHB) synthesized in Alcaligenes eutrophus were investigated. Al-base or Fe-base coagulants, and the dispersion method of 30% hypochlorite solution and chloroform were used as coagulants and PHB recovery method, respectively The recovery efficiency of PHB from the cells harvested with Al-base coagulants at the range from 0 to 1000 mg-Al/L was similar to that from cells harvested without the coagulants. At these conditions, the concentrations of residual aluminium in the purified PHB were below 250 mg-Al/kg-PHB, indicating the effect of residual aluminum on the characteristics of the purified PHB can be insignificant. When the dosage of coagulants was over 1000 mg-Al/L, the PHB recovery remarkably decreased with increasing the coagulant dosage. However, the PHB recovery could be enhanced by the use of 50% hypochlorite solution instead of 30% hypochlorite solution. Even though the reduction of PHB recovery efficiency was not found by using Fe-base coagulants, the purified PHB was stained pale red due to residual iron, These results suggest that the use of Al-base coagulants did not exert bad influence on neither PHB recovery efficiency and PHB purity.

• Archives of Metallurgy and Materials
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• v.66 no.4
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• pp.983-986
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• 2021

This study investigated the recovery behavior of valuable metals (Co, Ni, Cu and Mn) in spent lithium ion-batteries based on Al₂O₃-SiO₂-CaO-Fe₂O₃ slag system via DC submerged arc smelting process. The valuable metals were recovered by 93.9% at the 1250℃ for 30 min on the 20Al₂O₃-40SiO₂-20CaO-20Fe₂O₃ (mass%) slag system. From the analysis of the slag by Fourier-transform infrared spectroscopy, it was considered that Fe₂O₃ and Al₂O₃ acted as basic oxides to depolymerize SiO₄ and AlO₄ under the addition of critical 20 mass% Fe₂O₃ in 20Al₂O₃-40SiO₂-CaO-Fe₂O₃ (CaO + Fe₂O₃ = 40 mass%). In addition, it was observed that the addition of Fe₂O₃ ranging between 20 and 30 mass% lowers the melting point of the slag system.

• Resources Recycling
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• v.13 no.2
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• pp.3-8
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• 2004

A basic study on the recovery of heavy metals such as Zn, Ni, Cu and Fe ions from wastewater was carried out with the spent iron oxide catalyst, which was used in the Styrene Monomer(SM) production company. The heavy metals could be recovered more than 98％ with the spent iron oxide catalyst. The alkaline components of the spent catalyst could be precipitated the metal ions of the wastewater as metal hydroxides at the higher pH 10.6 in Ni, pH 8.0 in Cu, pH 6.5 in Fe, pH 8.5 in Zn. But the metal ions are adsorbed physically on the surface of the spent catalyst in the range of the pH of the metal hydroxides and pH 3.0, which is the isoelectric point of the iron oxide catalyst.

• Journal of the Korean Society for Precision Engineering
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• v.13 no.9
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• pp.165-173
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• 1996

The dimensional accuracy of a final product is mainly affected by elastic die deformation during the forging and elastic recovery after the ejection in cold forging process. The investigations on elastic recovery are not so much as those of elastic die deformation. The elastic recovery can be determined by using the elastic-plalstic finite element analysis, but, this method has some limits such as poor conver- gence and long computational time, etc. In this paper, a theoretical analysis for predicting the elastic recovery of a final product in axi-symmetric forging process by using the rigid-plastic finite element method is presented. The rigid-plastic finite element analysis of a cold forward extrusion process involving loading, ejecting process is accomplished by rigid-plastic FE code, DEFORM. The effect of elastic die deformation on the final product dimenmsion is also considered. The calculated elastic recovery is compared is compared with the analysis result of elastic-plastic FE code. ABAQUS.

• The Transactions of the Korea Information Processing Society
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• v.4 no.3
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• pp.649-658
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• 1997

Database management systems(DMBS)using bolatile memory shluld have a recovery function to protect data against system failutes.Recovery requires much overhead in transaction proessing and is one of the great factors that deteriorate the system performance.Recently, there have been a lot of studies on database systems with nonbolatile memory to enhance the performance.A nonbolatile memory called DFeRAM is one of the promising memory devices of the future technology, but this device does not support fine-franularity licking.In this paper, we present a dual plane FeRAM(DFeRAM)architecture to support the fine-granularity locking.We also propose a recovery algorithm for the database system with the DFeRAM based on a shadow paging methed.In order to analze the performance of the proposed algorithm, we present an analytical model and analyze the performance using the moedl.

• Korean Chemical Engineering Research
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• v.55 no.6
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• pp.785-790
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• 2017

To collect zinc, Fe and Zn in spent pickling solution were extracted by using TBP (tributyl phosphate), and Zn was recovered from extracted solution to zinc oxalate particles by oxalic acid solution. The reusability of TBP solvent was also tested. The distribution coefficient of Zn was not affected by the concentration of Fe in spent pickling solution, almost constant with the values of 7.12~9.31 when extracted by TBP solvent. It was found that the extraction capacity of TBP solvent for Zn is higher than that for Fe. The extraction efficiency of Zn was higher than 95%, while most of Fe was left in aqueous phase. After the recovery, the used TBP solvent could be repeatedly reused for the extraction of Zn up to eight times. XRD analysis showed that zinc oxalate ($ZnC_2O_4$ $2H_2O$) was formed from the reaction of Zn-TBP and oxalic acid. From the results of SEM analysis, the formation of zinc oxalate particle was strongly affected by the concentration of oxalic acid. In summary, Zn in spent pickling solution was successfully separated and recovered with TBP solvent and oxalic acid solution, respectively.

• Resources Recycling
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• v.30 no.4
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• pp.27-34
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• 2021

In this study, the leaching behavior of vanadium (V) was investigated through CaO roasting and sulfuric acid leaching from domestic V-bearing titanomagnetite (VTM). Changes in the phase according to the amount of CaO added and roasting temperature were analyzed. Regardless of the roasting conditions, perovskite (CaTiO₃) was preferred to form. When the CaO content was increased, the calcium ferrite (CaFeO_x) phase was formed; otherwise, ferrite (Fe₂O₃) was preferred. After CaO was roasted, leaching was performed for 6 h with 1M sulfuric acid at 50℃ and a 10% solid-liquid ratio. Results of leaching revealed that when the roasted product was sintered, V was not sufficiently oxidized, and the leaching efficiency decreased. In addition, when the roasting temperature was low, the leaching efficiency of V decreased due to the influence of unreacted excess CaO. To lower the leaching efficiency of iron and titanium in VTM concentrates, suppressing the formation of CaTiO₃ and CaFeO_x was necessary by minimizing the amount of CaO added. Consequently, a leaching efficiency of 86% V, 4.3% Fe, and 6.5% Ti was obtained when the roasted product of 1150℃ and 10 wt% CaO was leached.