• Title/Summary/Keyword: Fe content

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The Effect of Carbon on the Hot Corrosion of lron by Sulfur Containing Environment. (철의 고온 황화부식에 미치는 탄소의 영향)

  • 최성필;강성군;백영남
    • Journal of the Korean institute of surface engineering
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    • v.21 no.2
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    • pp.53-67
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    • 1988
  • The high temperature corrosion of Fe-C alloys were studied at I atm SO gas in the temperature range 500~80$0^{\circ}C$ by means of a thermogravimetric analysis. The Na2SO4 induced high tempwrature corrosion rate was also measured at atm O2 gas under above the temperature renge. The reaction products were identified with the aid of X-ray diffraction technique, and micostruction of the alloy/scale interface was observed with a optical microscope and SEM. The experimental results were disussed by the themodeynamic calcutions. Under above the experimental condition. the reaction rates decrbon with increasing carbon content. The transfer of Fe ion was limited by a residue of carbon precipitated at alloy scale interface due to the oxidation of Fe-C alloys at alloy surface. The effect of cold working on reaction rate was different between the Fe containing low carbon and Fe-C Alloy containing carbon above 0,73 wt%. In a cold worked iron containing low carbon content, the crystallization of metal surface leads to the poor adherence between the alloy and the cavity formed between the alloy and scale. The outward diffusion of ion through the scale is estimated to be hindered by the cavity formed between the scale, consequently decreasing reaction rate. In the case Fe-C containing carbon above 0.73 Wt% alloy, the reaction rate was little affected by cold working, because the effect of content on reaction rats is greater than the effect of cold working.

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Synthetic Properties of Fe/MgO Catalyst on Characteristics of Carbon Nanotubes Prepared by Catalytic Chemical Vapor Deposition

  • Jung, Sung-Sil;Lee, Dae-Yeol;Chung, Won-Sub;Park, Ik-Min
    • Carbon letters
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    • v.5 no.3
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    • pp.133-141
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    • 2004
  • The synthetic behaviors of carbon nanotubes (CNTs) by Fe/MgO catalysts were investigated in 0~90 wt.% range of MgO mixture ratios by catalytic chemical vapor deposition (CCVD) process. The CNTs were synthesized with 40 minutes of synthetic time, and 923 K of synthetic temperature using 0.1 L/min of ethylene gas and 1.0 L/min of hydrogen gas as synthetic and carrier gas, respectively. As the increase of synthetic temperatures and times, the diameters of CNTs become thicker. The carbon yield showed in a parabolic curve as MgO content increased and the maximum carbon yield was obtained at 30 wt.% of MgO. There were no obvious changes in the diameters of CNTs respect to the change of MgO content. Fe/MgO CNTs showed good crystalinity by High Resolution Transmission Electron microscope (HR-TEM) analysis. The behaviors of Fe/MgO CNTs have a tendency of depending on synthetic time and temperature rather than MgO content.

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Standard of Hwangtoh Pack Product (황토팩 제품의 규격)

  • Sohn, Young-Taek
    • Journal of Pharmaceutical Investigation
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    • v.35 no.6
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    • pp.467-469
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    • 2005
  • The purpose of this study was to investigate main ingredients of Hwangtoh (Korean yellow ochre), especially ferric oxide $(Fe_{2}O_{3})$ content. In this study, X-ray fluorescence spectrophotometry was employed to analyze the ingredients of Hwangtoh. The ferric oxide $(Fe_{2}O_{3})$ contents of Hwangtoh from Hwa Sun, Ham An, Chil Gok, Sun Chun, Ha Dong, San Chung, Go Chang, Kim Che and Jeong Eup were 1.5, 5.66, 11.76, 6.63, 2.74, 11.4, 4.84, 7.21 and 6.23%, respectively. Based on the above results, any Hwangtoh sample didn't meet the ferric oxide $(Fe_{2}O_{3})$ content criterion.

A Study on the Content of Cu, Fe, Zn, Mn, Pb, Cd in Market Milk (市乳中의 Cu, Fe, Zn, Mn, Pb, Cd, 함량에 관한 연구)

  • 김대선
    • Journal of Environmental Health Sciences
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    • v.12 no.1
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    • pp.69-78
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    • 1986
  • In order to determine the content levels of trace metals in cow's milk, 79 market milk samples were collected from markets in major cities of Korea from July to August, 1985 and analyzed for content levels of Cu, Fe, Zn, Mn, Pb, Cd. The Results were as follows Cu, average 43.5 $\mu$g/l range 14 ~ 172.7 $\mu$g/l Fe, average 398.4 $\mu$g/l range 35 ~ 1,873 $\mu$g/l Zn, average 2.917 mg/l range 1.233 ~ 7.46 mg/l Mn, average 26.74 $\mu$g/l range 7.6 ~ 102 $\mu$g/l Pb, average 33.9 $\mu$g/l range N.D. ~ 105 $\mu$g/l Cd, average 1.73 $\mu$g/l range N.D. ~ 5.4 $\mu$g/l

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INFLUENCE OF CARBON CONTENT ON AUSTENITE STABILITY AND STRAIN-INDUCED TRANSFORMATION OF NANOCRYSTALLINE FeNiC ALLOY BY SPARK PLASMA SINTERING

  • SEUNG-JIN OH;BYOUNG-CHEOL KIM;MAN-CHUL SUH;IN-JIN SHON;SEOK-JAE LEE
    • Archives of Metallurgy and Materials
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    • v.64 no.3
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    • pp.863-867
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    • 2019
  • The effects of carbon content on the austenite stability and strain-induced transformation of nanocrystalline Fe-11% Ni alloys were investigated using X-ray analysis and mechanical tests. The nanocrystalline FeNiC alloy samples were rapidly fabricated using spark plasma sintering because of the extremely short densification time, which not only helped attain the theoretical density value but also prevented grain growth. The increased austenite stability resulted from nanosized crystallites in the sintered alloys. Increasing compressive deformation increased the volume fraction of strain-induced martensite from austenite decomposition. The kinetics of the strain-induced martensite formation were evaluated using an empirical equation considering the austenite stability factor. As the carbon content increased, the austenite stability was enhanced, contributing to not only a higher volume fraction of austenite after sintering, but also to the suppression of its strain-induced martensite transformation.

Effect of Fe content on the contact resistance of electroplated Au-Fe alloy layers (Au-Fe합금 도금층의 접촉저항에 미치는 Fe함량의 영향)

  • Park, Hyeon-Sun;Son, In-Jun
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2015.11a
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    • pp.350-350
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    • 2015
  • 본 연구는 Fe함량에 따른 Au-Fe합금 도금층의 접촉저항을 알아보는 것이 목적이다. 이를 위해 Fe함량을 다르게 하여 Au-Fe합금 도금층을 가진 시편을 제작하고 열처리를 실시한 후 접촉저항을 비교하였다. 그 결과 Fe함량이 증가할수록 접촉저항이 증가하는 것을 알 수 있었다.

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Synthesis and Characterization of Polyphase Waste Form to Immobilize High Level Radioactive Wastes (고준위 방사성 폐기물의 고정화를 위한 다상 고화체 합성)

  • Chae Soo-Chun;Jang Young-Nam;Bae In-Kook;Ryu Kyung-Won
    • Economic and Environmental Geology
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    • v.39 no.2 s.177
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    • pp.173-180
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    • 2006
  • The synthesis of polyphase waste form, which is an immobilization matrix fur the high level radioactive wastes, was performed with the mixed composition of garnet and spinel $(Gd_3Fe_5O_{12}+(Ni_xMn_{1-x})(Fe_yCr_{1-y})_2O_4)$ in the range of 1200 to $1400^{\circ}C$. The phases synthesized from all stoichiometric compositions were garnet, perovskite, and spinel. Especially, garnet was synthesized only in the composition of the highest content of Fe(y=0.9), whereas it was not synthesized in other compositions. This result indicated that the content of Fe was closely related to the formation of garnet. The composition of garnet revealed that the content of Gd was exceeded and that of Fe was depleted. Preferential distribution of elements in the phases can be attributed to the nonstoichiometric composition of garnet.

The Effects of Si or Sn on the Sintered Properties of Fe-(Mo,Mn)-P Lean alloy (Fe-(Mo,Mn)-P계 Lean alloy의 소결특성에 미치는 Si와 Sn의 영향)

  • Jung, Woo-Young;Ok, Jin-Uk;Park, Dong-Kyu;Ahn, In-Shup
    • Journal of Powder Materials
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    • v.25 no.4
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    • pp.302-308
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    • 2018
  • A lean alloy is defined as a low alloy steel that minimizes the content of the alloying elements, while maintaining the characteristics of the sintered alloy. The purpose of this study is to determine the change in microstructure and mechanical properties due to the addition of silicon or tin in Fe-Mo-P, Fe-Mn-P, and Fe-Mo-Mn-P alloys. Silicon- or tin-added F-Mo-P, Fe-Mn-P, and Fe-Mo-Mn-P master alloys were compacted at 700 MPa and subsequently sintered under a $H_2-N_2$ atmosphere at $1120^{\circ}C$. The sintered density of three alloy systems decreases under the same compacting pressure due to dimensional expansion with increasing Si content. As the diffusion rate in the Fe-P-Mo system is higher than that in the Fe-P-Mn system, the decrease in the sintered density is the largest in the Fe-P-Mn system. The sintered density of Sn added alloys does not change with the increasing Sn content due to the effect of non-dimensional changes. However, the effect of Si addition on the transverse rupture strengthening enhancement is stronger than that of Sn addition in these lean alloys.

Development of New Titanium Alloys for Castings (주조용 티타늄 신합금 개발)

  • Kim, Seung-Eon;Jeong, Hui-Won;Hyeon, Yong-Taek;Kim, Seong-Jun;Lee, Yong-Tae
    • 연구논문집
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    • s.29
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    • pp.163-171
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    • 1999
  • A new titanium alloy system. Ti-xFe-ySi (x,y=0-4 wt%). was designed and characterized with the point at low cost and high strength for casting applications. Fe improved room and elevated temperature mechanical properties owing to solid solution hardening and beta phase stabilization. Si yielded titanium silicides and Si addition over 1 wt% resulted in poor ductility due to coarse silicide chains at prior beta boundaries. The optimum composition was found to be Ti-4Fe-(0.5-1)Si in the viewpoint of tensile strength and ductility which are comparable to the Ti-6Al-4V. The metal-mould reaction was also examined for Ti-xFe and Ti-xSi binary alloy system. The thickness of surface reaction layer w as not affected significantly with Fe content, while it was decreased with Si content. In the Ti-4Si alloy, no reaction layer was found. The depth of surface hardening layer was about $200\mum$ regardless of the mould materials.

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Electronic Behaviors of Passive Films Formed on Fe-Cr and Fe-Cr-Mo Ferritic Stainless Steels Studied by Mott-Schottky and Cyclic Voltammetry Techniques

  • Kim, Suk-Won;Yoon, Sang-In;Lee, Jae-Bong
    • Corrosion Science and Technology
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    • v.2 no.1
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    • pp.12-17
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    • 2003
  • The effects of Cr content and film formation potential on electronic behaviors of the passive film on Fe-Cr alloys were investigated in borate buffer solution. Influence of pH on passive films of both Fe-Cr and Fe-Cr-Mo alloys was also investigated. Mott-Schottky and cyclic voltammetry techniques were used to elucidate electronic behaviors of passive films and their electrochemical characteristics. AES analysis of passive films was carried out. Results showed that doping density decreased as Cr content and film formation potentials increased. The addition of Mo to Fe-Cr alloy had little influence on donor densities in pH 9.2 solution but some effects on the decrease in donor densities in pH 1.6 acidic solution.