• Title/Summary/Keyword: Fe contamination

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Assessment of Leachate from Solid Waste Landfills in Daechong Lake Upper Drainage Basin (대청호 상류유역 매립지의 침출수 분석 및 평가)

  • Hong, Sang-Pyo
    • Journal of Environmental Impact Assessment
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    • v.12 no.3
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    • pp.161-170
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    • 2003
  • To investigate the characteristics of 17 solid waste landfills in the upper drainage basin of Lake Daechong, the landfill sites were surveyed, the leachate of these landfills were analyzed, and the analysis results were assessed from standpoint of water contamination. Sanitary landfills which are now being operated are relatively well equipped with facilities such as leachate collection, daily soil cover and landfill gas treatment devices. But a few of open-dumping landfills were leaking leachate apparently and were supervised improperly and neglectfully by local governments. Some of sanitary landfills exceeded the COD permission criteria of leachate effluent, and some of open-dumping landfills exceeded SS, T-P, Pb, As, Fe, Mn permission criteria of leachate effluent. To improve the water quality of Lake Daechong which is utilized for supplying drinking water, agricultural water, and industrial water to the great part of Chungchong area, the adequate and prompt measures for preventing Daechong Lake water contamination from landfills leachate is necessary.

Removal of Cu and Fe Impurities on Silicon Wafers from Cleaning Solutions (세정액에 따른 실리콘 웨이퍼의 Cu 및 Fe 불순물 제거)

  • Kim, In-Jung;Bae, So-Ik
    • Korean Journal of Materials Research
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    • v.16 no.2
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    • pp.80-84
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    • 2006
  • The removal efficiency of Cu and Fe contaminants on the silicon wafer surface was examined to investigate the effect of cleaning solutions on the behavior of metallic impurities. Silicon wafers were intentionally contaminated with Cu and Fe solutions by spin coating and cleaned in different types of cleaning solutions based on $NH_4OH/H_2O_2/H_2O\;(SC1),\;H_2O_2/HCl/H_2O$ (SC2), and/or HCl/$H_2O$ (m-SC2) mixtures. The concentration of metallic contaminants on the silicon wafer surface before and after cleaning was analyzed by vapor phase decomposition/inductively coupled plasma-mass spectrometry (VPD/ICP-MS). Cu ions were effectively removed both in alkali (SC1) and in acid (SC2) based solutions. When $H_2O_2$ was not added to SC2 solution like m-SC2, the removal efficiency of Cu impurities was decreased drastically. The efficiency of Cu ions in SC1 was not changed by increasing cleaning temperature. Fe ions were soluble only in acid solution like SC2 or m-SC2 solution. The removal efficiencies of Fe ions in acid solutions were enhanced by increasing cleaning temperature. It is found that the behavior of metallic contaminants as Cu and Fe from silicon surfaces in cleaning solutions could be explained in terms of Pourbaix diagram.

Influence of Metallic Contamination on Photovoltaic Characteristics of n-type Silicon Solar-cells (중금속 오염이 n형 실리콘 태양전지의 전기적 특성에 미치는 영향에 대한 연구)

  • Kim, Il-Hwan;Park, Jun-Seong;Park, Jea-Gun
    • Current Photovoltaic Research
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    • v.6 no.1
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    • pp.17-20
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    • 2018
  • The dependency of the photovoltaic performance of p-/n-type silicon solar-cells on the metallic contaminant type (Fe, Cu, and Ni) and concentration was investigated. The minority-carrier recombination lifetime was degraded with increasing metallic contaminant concentration, however, the degradation sensitivity of recombination lifetime was lower at n-type than p-type silicon wafer, which means n-type silicon wafer have an immunity to the effect of metallic contamination. This is because heavy metal ions with positive charge have a much larger capture cross section of electron than hole, so that reaction with electrons occurs much more easily. The power conversion efficiency of n-type solar-cells was degraded by 9.73% when metallic impurities were introduced in the silicon bulk, which is lower degradation compared to p-type solar-cells (15.61% of efficiency degradation). Therefore, n-type silicon solar-cells have a potential to achieve high efficiency of the solar-cell in the future with a merit of immunity against metal contamination.

Heavy Metal Concentrations in Soils of the Daegu and Ulsan Area (대구·울산지역의 토양 중금속 오염도 평가)

  • Lee Tae-Gwan
    • Journal of Environmental Science International
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    • v.14 no.6
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    • pp.605-611
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    • 2005
  • The aim of this study was to analyze the local distribution of the heavy metal concentration in Daegu and Ulsan which were divided into the residual areas, the traffic dense areas and the industrial areas. The Inductively Coupled Plasma(ICP) was used to analyze heavy metals, such as As, Cr, Hg, Zn, Cd, Pb, Cu and minor metals, such as Fe, Si, Mg, Ca, AI, Na, K. The results of this analysis showed that the content of heavy metals which was classified by districts in Daegu and Ulsan was the highest in the industrial areas followed by the traffic dense areas and the residual areas. Compared to the level of heavy metals of national and local soil survey network in 2003, contamination of heavy metals in Daegu was lower than national average. However, the content of Cd, As, Zn in Ulsan was respectively 13.38 times, 472 times and 2.65 times higher than national average contamination. In addition, compared to the soil pollution level of the environmental protection law, contamination of all areas in Daegu was lower. But the content of As at the industrial areas in Ulsan was 10.71 times higher than standard of soil pollution and 4.28 times higher than standard of measures against soil contamination.

Characteristics of Groundwater Pollution and Contaminant Attenuation at Waste Disposal Sites (폐기물 매립지 주변의 지하수 오염과 오염물질의 지연 특성)

  • 오석영;전효택
    • Journal of the Korean Society of Groundwater Environment
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    • v.3 no.1
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    • pp.37-49
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    • 1996
  • The objectives of this study are to investigate the groundwater and surface water contamination, to interpret the attenuation mechanism of contaminant transport, and to find the appropriate contamination indicator. at the two big landfill sites : Nanjido Landfill and Hwasung Landfill. Leachate from the Nanjido, th, Hwasung and the Kimpo waste disposal sites is characterized by high temperature (31.7-40.1$^{\circ}C$), high electric conductivity (14,650-32,800 ${\mu}$S/cm), somewhat higher pH(7.58-8.45) and low Eh (-119.4-20.4 mV), and is enriched in both major (Na$^{+}$, K$^{+}$, Ca$^{2+}$, Mg$^{2+}$, HC $O_3$$^{-}$, Cl$^{-}$) and minor (Mn, Sr$^{2+}$, Ba$^{2+}$, Li$^{+}$, F$^{-}$, Br$^{-}$) ions. Municipal solid waste leachate and industrial waste leachate are effectively discriminated by the content of S $O_4$$^{2-}$, Fe, and heavy metals. The attenuation mechanism of each component was assessed using the chemical analysis. Cl-normalizing process, WATEQ4F simulation, and preceding flownet analysis. Based on the calculation of Contamination Factor, K, Na, Ca, Mg, B, Zn, HC $O_3$, Cl, F, Br and TOC are effective contamination indicators in the Nanjido landfill site, and K, Na, Ca, Mg, B, S $O_4$, HC $O_3$, Cl, F, Br and TOC in the Habsburg landfill site Particularly, TOC is the best contamination indicator in landfill sites influenced by sea water.

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A Study on the Functionality of the Fabrics Dyed with Pine Needles Extract (1) (솔잎 추출물을 이용한 염색직물의 기능성에 관한 연구[1])

  • Park Young-Hee
    • Journal of the Korean Society of Costume
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    • v.56 no.2 s.101
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    • pp.147-154
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    • 2006
  • In this study 1, the dyeability and sun protection characteristic of the fabrics dyed with pine needles extract was investigated. In the test of color difference, the surface color of all the dyed fabric of both cotton and silk came to light as greenish yellow. In the test of dyeing colorfastness, the colorfastness to sunlight of dyed cotton fabric was below 2nd grade and the one of dyed silk fabric was below 3rd grade. The colorfastness to laundry for the degree of discoloration showed a difference as to mordants, but the colorfastness to laundry for the degree of contamination was excellent as all the dyed fabrics were 4th-5th grade. The colorfastness to perspiration was excellent as the degree of discoloration was more than 3rd grade and the degree of contamination was more than 4th-5th grade. The colorfastness to rubbing showed the excellent result as all the dyed fabrics were 4th-5th grade. In the test of sun protection factor(SPF), the cotton and silk fabrics dyed with $FeSO_4{\cdot}7H_{2}O$ mordant showed very high sun protection characteristic as the SPF was each 36.1 and 42.5. In the test of sun protection rate for UV-A and UV-B, the cotton and silk fabrics dyed with $FeSO_4{\cdot}7H_{2}O$ mordant showed the very high sun protection rate of more than $90\%$.

Heavy metal assessment of marine sediment in selected coastal districts of the Western Region, Ghana

  • Kuranchie-Mensah, Harriet;Osei, Juliet;Atiemo, Sampson M.;Nyarko, Benjamin J.B.;Osae, Shiloh K.;Laar, Cynthia;Ackah, Michael;Buah-Kwofie, Archibold;Blankson-Arthur, Sara;Adeti, Prince J.
    • Advances in environmental research
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    • v.2 no.2
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    • pp.155-166
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    • 2013
  • A preliminary investigation to establish the status of contamination of trace metals in the Western coast of Ghana was conducted prior to the commercial production of crude oil in the area. The study revealed the presence of heavy metals such as Pb (4.00-79.64 mg/kg), As (8.81-236 mg/kg), Cu (12.86-108.06 mg/kg), V (28.07-953.32 mg/kg), Zn (7.08-264.25 mg/kg), Cr (101.69-1366.62 mg/kg), Ni (42.41-451.43 mg/kg), Mn (16.77-1890.45mg/kg), Br (7.66-142.78 mg/kg), Ti (542.03-19960 mg/kg) and Fe (7472.88-97120 mg/kg) at six sites sampled along the coast. With the exception of Ti and Fe which showed no variation in metal concentration, the rest of the metals varied significantly among the sampled locations. Potential ecological risk of metals particularly of Co, As and Br which exhibited extreme enrichment of the sediments indicates considerable metal pollution in the studied areas. The degree of contamination is of particular concern especially to benthic biota that inhabit this environment for survival.

Groundwater Quality and Contamination in the 'A' section of Seoul Metropolitan Subway (서울특별시 지하철 A설계구간에서의 지하수 수질 및 오염특성)

  • 이병선;우남칠
    • The Journal of Engineering Geology
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    • v.12 no.4
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    • pp.379-394
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    • 2002
  • This study was initiated to identify groundwater quality and contamination at present in the 'A' section of Seoul Metropolitan Subway. Groundwater samples were collected at 21 boreholes along the 'A' section and appeared to show mainly $Ca-HCO_3$ type. In 20 samples, concentration of $SO_4$, Cd, Pb, Fe, Mn, Al, F and $NO_3-N$ were higher than those of Korean drinking water quality standards. From chemical data and saturation Indices, contaminant sources of individual chemical elements were inferred to be buried wastes and surface sediments over the study area. The result of factor analysis suggested that the pollution factor should account for about 47% of data variation.

Predicting As Contamination Risk in Red River Delta using Machine Learning Algorithms

  • Ottong, Zheina J.;Puspasari, Reta L.;Yoon, Daeung;Kim, Kyoung-Woong
    • Economic and Environmental Geology
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    • v.55 no.2
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    • pp.127-135
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    • 2022
  • Excessive presence of As level in groundwater is a major health problem worldwide. In the Red River Delta in Vietnam, several million residents possess a high risk of chronic As poisoning. The As releases into groundwater caused by natural process through microbially-driven reductive dissolution of Fe (III) oxides. It has been extracted by Red River residents using private tube wells for drinking and daily purposes because of their unawareness of the contamination. This long-term consumption of As-contaminated groundwater could lead to various health problems. Therefore, a predictive model would be useful to expose contamination risks of the wells in the Red River Delta Vietnam area. This study used four machine learning algorithms to predict the As probability of study sites in Red River Delta, Vietnam. The GBM was the best performing model with the accuracy, precision, sensitivity, and specificity of 98.7%, 100%, 95.2%, and 100%, respectively. In addition, it resulted the highest AUC of 92% and 96% for the PRC and ROC curves, with Eh and Fe as the most important variables. The partial dependence plot of As concentration on the model parameters showed that the probability of high level of As is related to the low number of wells' depth, Eh, and SO4, along with high PO43- and NH4+. This condition triggers the reductive dissolution of iron phases, thus releasing As into groundwater.