• Title/Summary/Keyword: Fe/Zn

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Some Trace Metals and their Ratios in Aloe (Aloe vera L.), Cucumber (Cucumis sativus L. var. tuberculatus Gabaj.) and Sponge-gourd (Luffa cylindrica L.) in Korea

  • Lee, Chang-Jun;Park, Jung-Sang;Jang, Gi-Chul;Kim, Sang-Deog A.
    • Korean Journal of Plant Resources
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    • v.22 no.6
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    • pp.540-545
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    • 2009
  • Aloe (Aloe vera L.), cucumber (Cucumis sativus L. var. tuberculatus Gabaj.) and sponge.gourd (Luffa cylindrica L.) are well utilized in Asian countries as traditional medicines and cosmetics, or foods. And we carried out an experiment to see if there are some specific ratios among trace metals on the plants. Though the metal concentrations varied significantly depending on the sampling periods, aloe gel is high in iron (Fe) and calcium (Ca). Cucumber fruit juice is also high in iron (Fe) and potassium (K). Sponge.gourd sap contains a high amount of zinc (Zn) and calcium (Ca). The uses of the previous 3 plant parts are considered to have some relations to their different ratios and of their trace metals.

A Study on Electromagnetic Wave Absorbing Properties of Complex Isotropic Ferrite-Rubber Composite (복합형 등방성 Ferrite-Rubber Composite의 전자파 흡수특성에 관한 연구)

  • 김동일;박연준;김하근;사공건
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.3 no.1
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    • pp.35-42
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    • 1999
  • This paper describes the characteristics of the complex isotropic ferrite-rubber composite for a super wideband electromagnetic absorber in RP-A-PF type, which can be used for an anechoic chamber, wall material to prevent TV ghost, etc. The $Ni_x-A_{0.1}-ZN_{(1-x0.1)}$. $Fe{_2}O_4$ ferrite powder has been fabricated. Using this, then, [$Ni_x-A_{0.1}-ZN_{(1-x0.1)}$. $Fe{_2}O_4$]-Rubber composite for RF-layer in the RF-A-PF type absorber has been fabricated and it's characteristics has been analyzed. As a result, it has been shown that the [$Ni_x-A_{0.1}-ZN_{(1-x0.1)}$. $Fe{_2}O_4$].Rubber composite has excellent electromagnetic wave absorbing properties.

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A study on the contol mechaanism of Fe deposition in gavannealed steel sheet (용융아연 합금도금강판의 Fe석출량 제어기구에 관한 연구)

  • 서정현
    • Journal of the Korean institute of surface engineering
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    • v.31 no.5
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    • pp.286-296
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    • 1998
  • Galvannealing is becomming the main stream of the coating technology applied to automobile outer and inner panels due to its low cost and easy application applied to automobile outer and inner panels due to its low cost and easy application in thick Zn coating, compared to electro galvanizing. Despite of filed up data with an experience in this field, galvannealing in thick Zn coating is getting more difficult because of the absence of Fe deposition in Zn coating. As a result, it exhibits, with different steel sheet and grain size there is a proper temperature range which is good for the tarket coating thickness of galvannealing. In case of 1,200mm wide and 0.77 mm thick extra low carbon steel with 20$mu extrm{m}$ grain size, its proper temperature range for galvannealing of one side 60g/$\textrm{m}^2$ is 470-$480^{\circ}C$.

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A Study on Coating Adhesion of Hot Rolled Galvanized Iron Manufactured without pickling process (산세생략형 열연 용융아연도금강판의 특성)

  • 최진원;전선호
    • Journal of the Korean institute of surface engineering
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    • v.32 no.1
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    • pp.21-30
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    • 1999
  • Coating adherance behavior of low carbon steels, produced by POSCO, Korea, was studied in order to study the characteristics of hot rolled galvanized iron(HGI) manufactured without pickling line and the development of its process. Galvanizing experiments were carried out in zinc pot with 0.2wt% Al after hot rolled plates with scale were reduced at $550~750^{\circ}C$ in 10~30% hydrogen gas atmosphere during 60~400seconds. The reduced plates and coated products were examined by SST, XRD, SEM and EPMA on their surfaces and cross sections. Coating layer of HGI manufactured with pickling line was composed of retained scale, Fe-Zn-Al compound, Fe-Zn compound ($\delta_1\;and\;\zeta$ Phase) and pure zinc. It was superior to HGI in coating adhesion. It seems to be due to forming of Fe-Zn-Al compound in interface of matrix and retained porous scale.

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A Study on Mechanical Properties of Galvanized Steel Plate (용융아연도금한 강판의 기술적 성질에 관한 연구)

  • 정동원;곽창섭;최종술
    • Journal of the Korean institute of surface engineering
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    • v.16 no.4
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    • pp.153-159
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    • 1983
  • The growth rate equation of Fe-Zn alloy layer was represented by x = Kt, and hence the growth of alloy layer was considered to be controlled by diffusion process. The constituent of alloy layer formed on the steel surface was identified to be intermetallic compound of Fe3Zn10 and FeZn10. The ultimate tensile strength and elongation of galvanized steel showed a nearly constant value at the thickness below about 30$\mu\textrm{m}$, and both properties decreased with increasing thickness above about 30$\mu\textrm{m}$. In the case of galvanied steel with a great thickness of alloy layer, crack was formed below yield point of base metal, which is considered to be attributed to the alloy layer failure.

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Establishment of the Spectral Correction Matrix and Simultaneous Determination of Ion and Zic with 1-(6-Benzothiazolylazo)-2-Naphthol as Chromogenic Agent.

  • Geo, Hong Wen.;Li, Cheng Yu.;Ye, Qing Song.
    • Bulletin of the Korean Chemical Society
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    • v.22 no.6
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    • pp.565-569
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    • 2001
  • The spectral correction matrix has been established to study the simultaneous complextions between metals and a ligand, and it eliminated the mutual influence among the complexes. The two sensitive reations between iron(Ⅱ) and 1-(6-bromo-2-benzothiazolylazo)-2-naphthol(BBTAN) and zinc (Ⅱ) and BBTAN have been investigated and applied to the simultaneous determination of Zn and Fe at pH 8.5 in the presence of triton x-100. This method gave the simples determination of the characteristic constants of the complexes. For the analysis of natural water, foods and other samoles, the recoveries of Fe and Zn were between 92 and 109% and between 91 and 104%, and their relative standard deviations were less than 5.5 and 11%, respectively.

Mechanical Aalloying Behavior of $Al_3$Hf 및 $Al_3$Ta Intermetallic Compounds by SPEX Mill and the Effect of Ternary Additions on the Formation of $Ll_2$ Phase (SPEX mill을 이용한 $Al_3$Hf 및 $Al_3$Ta 금속간화합물의 기계적합금화 거동과 $Ll_2$상형성에 미치는 제 3 원소 첨가의 영향)

  • Lee, Seong-Hun;Choe, Jong-Hyeon;Kim, Jun-Gi;Kim, Seon-Jin
    • Korean Journal of Materials Research
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    • v.10 no.8
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    • pp.569-574
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    • 2000
  • To improve the ductility of $Al_3Hf$ and $Al_3Ta$ intermetallic compounds, which are the potential temperature structural materials, the mechanical alloying behaviour and the effect of ternary additions on the $Ll_2$ phase formation were investigated. During the mechanical alloying by the SPEX mill, the $Ll_2$ $Al_3Hf$ intermetallic compound was formed after 6 hours of milling in AL-25%Hf system. In AL-25%Ta system, however, only the $D0_{22}$ $Al_3Ta$ intermetallic compound was formed until 30 hours of milling and the $Ll_2$ phase was not observed. In AL-12.5%M-25%Ta(M=Cu, Zn, Mn, Fe, Ni) systems, the additions of Cu and Zn had no effect on the $D0_{22}$ structure of the binary $Al_3Hf$ and the additions of Mn, Fe and Ni produced the amorphous phase. Therefore it was considered that these ternary additions could not overcome the energy difference between $Ll_2$ and $D0_{22}$ structures in the $Al_3Hf$ intermetallic compound. In AL-12.5%M-25%Hf(M=Cu, Zn, Mn, Fe, Ni)systems, the additions of Cu and Zn did not affect the $Ll_2$ structure of the binary $Al_3Hf$ but the additions of oMn, Fe and Ni produced the amorphous phase as they did in AL-12.5%M-25%Ta systems. Therefore, it was considered that the Ni, Mn and Fe additions promote the formation of amorphous phase in $Al_3X$ intermetallic compounds.

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A Geochemical Study on Trace Elements in the Granitic Rocks in relation to Mineralization in the Limestone Area of the Taebaegsan Basin (화강암류중 미량원소와 태백산분지내 석회암지역 광화작용과의 지구화학적 관계)

  • Lee, Jae Yeong
    • Economic and Environmental Geology
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    • v.20 no.3
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    • pp.179-196
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    • 1987
  • Various skarn ore deposits of Pb-Zn, Fe-Cu, W-Mo and others are widely distributed in the study area which consists mainly of Cambro Ordovician calcareous rocks. The ore deposits are all in close association with specific types of granitic rocks of mid-late Cretaceous age according to the kinds of ores: Fe-Cu deposit with granodiorite-quartz monzodiorite, Pb-Zn deposit with granite-granodiorite, W-Mo deposit with granite, and Mn deposit with quartz porphyry. The granitic rock of Fe-Cu deposit has lower content in K and higher in Ca than those of Pb-Zn deposits. On the contrary, the granitic rock of W-Mo deposit has much higher content in K and lower in Ca in comparison to those of Pb-Zn deposits. However, the granitic rock of Mn deposit shows similar variation to those of Pb-Zn deposits. Lithophile trace elements of Sr and Rb tend to vary in close relation with major elements of K and Ca, respectively. In good contrast, chalcophile elements of Cu, Pb, Zn, Wand Mo are enriched in the granitic rocks of their ore deposits, and other trace elements of Ni and Co show a trend to vary in relation with Mg, Fe and Cu, which have the same replacement index (0.14) as Ni and Co. Average K/Rb and Ca/Sr ratios of the granitic rocks range nearly within 300~150 and 150~40, respectively, and the distribution pattern of the ratios is different according to the kind of ore deposits: Fe-Cu deposit is plotted toward K-Rb poor region whereas Pb-Zn and W-Mo deposits toward K-Rb rich region. In contrast, Fe-Cu and Fe deposits are plotted toward Ca-Sr rich region whereas Pb-Zn deposit toward Ca-Sr poor region. The variation trend of chemical elements of the mid-late Cretaceous granitic rocks in the study area is similar to that of the Cretaceous granitic rocks in the Gyeongsang Basin. Therefore, this geochemical result may be applicable to determining what kinds of ore deposits a Cretaceous granitic rock is favourable for, and whether it is productive or non-productive for systematic geochemical exploration works.

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Growth of ZnO Thin films Depending on the Substrates by RF Sputtering and Analysis of Their Microstructures (기판의 결정구조에 따른 RF 스퍼터링 ZnO 박막의 성장과 미세구조 분석)

  • Yoo In-Sung;So Soon-Jin;Park Choon-Bae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.5
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    • pp.461-466
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    • 2006
  • To investigate the ZnO thin films which are interested in the next generation of short wavelength LEDs and Lasers, the ZnO thin films were deposited by RF sputtering system. At sputtering process of ZnO thin films, substrate temperature, work pressure respectively is $100^{\circ}C$ and 15 mTorr, and the purity of target is ZnO 5 N. The ZnO thin films were in-situ annealed at $600^{\circ}C$ in $O_2$ atmosphere. The thickness of ZnO thin films has implemented about $1.6{\mu}m$ at SEM analysis after in-situ annealing process. We have investigated the crystal structure of substrates, and so structural properties of ZnO thin films has estimate by using XRD, FWHM, FE-SEM and AFM. XRD and FE-SEM showed that ZnO thin films grown on substrates had a c-axis preferential orientation in the [0001] crystal direction. XPS spectra showed that ZnO thin film was showed a peak positions corresponding to the O1s and the Zn2p. As form above XPS, we showed that the atom ratio of Zn:O related 1:1.1504 on ZnO thin film, so we could obtained useful information for p-type ZnO thin film.